Solvent mixtures for dissolving elemental sulfur, methods of utilizing the solvent mixtures, and methods of forming the solvent mixtures

Patent metadata

Field	Value
Publication number	US-11118098-B2
Application number	US-201916436432-A
Country	US
Kind code	B2
Filing date	Jun 10, 2019
Priority date	Jun 27, 2018
Publication date	Sep 14, 2021
Grant date	Sep 14, 2021

Abstract

Solvent mixtures for dissolving elemental sulfur, methods of utilizing the solvent mixtures, and methods of forming the solvent mixtures. The solvent mixtures include an elemental sulfur solvent fraction and an odorant fraction. The elemental sulfur solvent fraction includes an elemental sulfur solvent that has a solvent odor and a solvent sulfur solubility of at least 10 weight percent (wt %). The odorant fraction includes at least one odorant that has an odorant odor that differs from the solvent odor. The solvent mixture includes at least 20 wt % and at most 80 wt % of both the elemental sulfur solvent fraction and the odorant fraction. The presence of the odorant fraction, within the solvent mixture, decreases an intensity of the mixture odor relative to the solvent odor and/or decreases an offensiveness of the mixture odor relative to the solvent odor.

First claim

What is claimed is:

1. A solvent mixture for dissolving elemental sulfur, the solvent mixture having a mixture odor and comprising:
an elemental sulfur solvent fraction including an elemental sulfur solvent, wherein the elemental sulfur solvent has a solvent odor and has a solvent sulfur solubility of at least 10 weight percent (wt %) at standard temperature and pressure (STP); and
an odorant fraction including at least one odorant, wherein the at least one odorant has an odorant odor that differs from the solvent odor;
wherein the elemental sulfur solvent fraction includes dimethyl disulfide (DMDS) and forms at least 20 wt % and at most 80 wt % of the solvent mixture;
wherein the odorant fraction includes at least 5 wt % and at most 15 wt % acetone, at least 10 wt % and at most 30 wt % methyl ethyl ketone (MEK), and at least 20 wt % and at most 40 wt % ethyl lactate; and
wherein the presence of the odorant fraction, within the solvent mixture, does at least one of the following (i) and (ii):
(i) decreases an intensity of the mixture odor relative to the solvent odor; and
(ii) decreases an offensiveness of the mixture odor relative to the solvent odor.

2. The solvent mixture of claim 1 , wherein the DMDS comprises at least 20 wt % and at most 40 wt % of the solvent mixture.

3. The solvent mixture of claim 1 , wherein the odorant fraction includes:
(i) at least 8 wt % and at most 12 wt % acetone;
(ii) at least 18 wt % and at most 22 wt % methyl ethyl ketone (MEK); and
(iii) at least 28 wt % and at most 32 wt % ethyl lactate.

4. The solvent mixture of claim 3 , wherein the odorant fraction further includes at least 3 wt % and at most 22 wt % of an amine.

5. The solvent mixture of claim 4 , wherein the amine includes:
(i) at least 0.1 wt % and at most 0.4 wt % monoethanolamine (MEA); and
(ii) at least 0.1 wt % and at most 0.6 wt % diethanolamine (DEA).

6. The solvent mixture of claim 4 , wherein the amine includes triethanolamine (TEA).

7. The solvent mixture of claim 6 , wherein the odorant fraction includes at least 5 wt % and at most 10 wt % TEA.

8. The solvent mixture of claim 4 , wherein the amine includes methyldiethanolamine (MDEA).

9. The solvent mixture of claim 8 , wherein the odorant fraction includes at least 5 wt % and at most 10 wt % MDEA.

10. The solvent mixture of claim 1 , wherein the elemental sulfur solvent fraction includes at least 20 wt % and at most 40 wt % DMDS and further includes at least one of: (i) methanol; (ii) isopropanol; (iii) diethanolamine (DEA); (iv) acetone; (v) diaryl disulfide (DADS); (vi) carbon disulfide; (vii) toluene; and (viii) an organic elemental sulfur solvent fraction.

11. The solvent mixture of any of claim 1 , wherein the odorant fraction further includes at least one of: (i) a ketone; (ii) acetone; (iii) an amine; (iv) monoethanolamine (MEA); (v) diethanolamine (DEA); (vi) triethanolamine (TEA); (vii) methyldiethanolamine (MDEA); (viii) an ester; (ix) an aromatic compound; and (x) a sulfurous compound.

12. The solvent mixture of claim 1 , wherein a mixture sulfur solubility of elemental sulfur within the solvent mixture is at least 10% and at most 90% of the solvent sulfur solubility.

13. The solvent mixture of claim 1 , wherein the odorant fraction is selected such that the solvent mixture defines a target elemental sulfur solubility of at most 100 wt %.

14. The solvent mixture of claim 1 , wherein the presence of the odorant fraction both decreases the intensity of the mixture odor and decreases the offensiveness of the mixture odor.

15. The solvent mixture of claim 1 , wherein the presence of the odorant fraction decreases a perceived intensity of the mixture odor, relative to the solvent odor, by at least 1 on an Odor Intensity Referencing Scale.

16. The solvent mixture of claim 1 , wherein the presence of the odorant fraction decreases a perceived offensiveness of the mixture odor, relative to the solvent odor, by at least 1 on an Odor Offensiveness Referencing Scale.

17. A method of removing elemental sulfur from a hydrocarbon conveyance system, the method comprising:
providing the solvent mixture of claim 1 ; and
applying the solvent mixture to the elemental sulfur to dissolve the elemental sulfur within the solvent mixture.

18. A method of forming the solvent mixture of claim 1 , the method comprising:
providing the elemental sulfur solvent fraction;
providing the odorant fraction; and
combining the elemental sulfur solvent fraction and the odorant fraction to generate the solvent mixture.

19. The solvent mixture of claim 1 , wherein the mixture odor differs from both the solvent odor and the odorant odor.

20. The solvent mixture of claim 1 , wherein the elemental sulfur solvent fraction includes:
(i) at least 30 wt % and at most 60 wt % diethanolamine (DEA);
(ii) at least 30 wt % and at most 60 wt % methanol;
(iii) at least 5 wt % and at most 30 wt % acetone;
(iv) at least 5 wt % and at most 10 wt % isopropanol; and
(v) at least 20 wt % and at most 25 wt % DMDS.

Assignees

• Northrop P Scott
• Harnsberry Kevin A
• Exxonmobil Upstream Res Co

Inventors

• Northrop P Scott
• Harnsberry Kevin A

Classifications

• C09K8/532 Primary

  Sulfur · CPC title

• C09K2208/20

  Hydrogen sulfide elimination · CPC title