Pneumatic tire

Patent metadata

Field	Value
Publication number	US-11118036-B2
Application number	US-201615341061-A
Country	US
Kind code	B2
Filing date	Nov 2, 2016
Priority date	Nov 20, 2015
Publication date	Sep 14, 2021
Grant date	Sep 14, 2021

Abstract

The present invention is directed to a pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr),
(A) from about 40 to about 90 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from −40° C. to 0° C.; (B) from about 60 to about 10 phr of polybutadiene; and (C) from 5 to 50 phr of a hydrocarbon resin having a Tg ranging from −40° C. to 20° C.; (D) optionally, a rubber process oil (E) optionally, a hydrocarbon resin having a Tg ranging above 20° C.

wherein the total amount of hydrocarbon resins and oils is less than 65 phr, and the weight ratio of silica to the total of hydrocarbon resins and oils is greater than 2.
(F) from 70 to 130 phr of silica.

First claim

What is claimed:

1. A pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr),
(A) from about 40 to about 90 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from −40° C. to 0° C.;
(B) from about 60 to about 10 phr of polybutadiene; and
(C) from 25 to 50 phr of a hydrocarbon resin having a Tg ranging from −40° C. to −10° C.;
(D) optionally, a rubber process oil; and
(E) from 90 to 130 phr of silica;
wherein the weight ratio of silica to the total of hydrocarbon resins and oils is at least 3.6.

2. The pneumatic tire of claim 1 , wherein the solution polymerized styrene-butadiene rubber is functionalized with an alkoxysilane group and at least one functional group selected from the group consisting of primary amines and thiols.

3. The pneumatic tire of claim 1 , wherein the hydrocarbon resin having a Tg ranging from −40° C. to −10° C. is a coumarone-indene resin.

4. The pneumatic tire of claim 1 , wherein the hydrocarbon resin having a Tg ranging from −40° C. to −10° C. resin is derived from styrene and alphamethylstyrene.

5. The pneumatic tire of claim 1 , wherein the vulcanizable rubber composition further comprises a hydrocarbon resin having a Tg higher than 20° C. and is derived from styrene and alphamethylstyrene.

6. The pneumatic tire of claim 1 , wherein the oil is selected from the group consisting of aromatic, paraffinic, naphthenic, MES, TDAE, heavy naphthenic oils, and vegetable oils.

7. The pneumatic tire of claim 1 , wherein the hydrocarbon resin having a Tg ranging from −40° C. to −10° C. is a coumarone-indene resin comprising residues of coumarone, indene, and at least one residues selected from the group consisting of methyl coumarone, styrene, α-methylstyrene, methylindene, vinyltoluene, dicyclopentadiene, cycopentadiene, and diolefins such as isoprene and piperlyene.

8. The pneumatic tire of claim 1 , wherein the solution polymerized styrene-butadiene rubber functionalized with an alkoxysilane group and a primary amine group, and is represented by the formula (1) or (2)

wherein P is a (co)polymer chain of a conjugated diolefin or a conjugated diolefin and an aromatic vinyl compound, R 1 is an alkylene group having 1 to 12 carbon atoms, R 2 and R 3 are each independently an alkyl group having 1 to 20 carbon atoms, an allyl group or an aryl group, n is an integer of 1 or 2, m is an integer of 1 or 2, and k is an integer of 1 or 2, with the proviso that n+m+k is an integer of 3 or 4,

wherein P, R 1 , R 2 and R 3 have the same definitions as give for the above-mentioned formula (1), j is an integer of 1 to 3, and h is an integer of 1 to 3, with the provision that j+h is an integer of 2 to 4.

9. The pneumatic tire of claim 1 , wherein the solution polymerized styrene-butadiene rubber is functionalized with an alkoxysilane group and a primary amine group comprises the reaction product of a living polymer chain and a terminating agent of the formula
RN—(CH) X —Si—(OR′) 3 ,  I

wherein R in combination with the nitrogen (N) atom is a protected amine group which upon appropriate post-treatment yields a primary amine, R′ represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, or an aryl; and X is an integer from 1 to 20.

10. The pneumatic tire of claim 1 wherein the solution polymerized styrene-butadiene rubber is functionalized with an alkoxysilane group and a thiol, and comprises the reaction product of a living anionic polymer and a silane-sulfide modifier represented by the formula
(R 4 O) x R 4 y Si—R 5 —S—SiR 4 3

wherein Si is silicon; S is sulfur; O is oxygen; x is an integer selected from 1, 2 and 3; y is an integer selected from 0, 1, and 2; x+y=3; R 4 is the same or different and is (C 1 -C 16 ) alkyl; and R 5 is aryl, and alkyl aryl, or (C 1 -C 16 ) alkyl.

11. A pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr),
(A) from about 40 to about 90 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from −40° C. to 0° C.;
(B) from about 60 to about 10 phr of polybutadiene; and
(C) from 25 to 50 phr of a hydrocarbon resin having a Tg ranging from −40° C. to −10° C.;
(D) optionally, a rubber process oil
(E) optionally, a hydrocarbon resin having a Tg ranging above 20° C. wherein the total amount of hydrocarbon resins and oils is less than 65 phr, and the weight ratio of silica to the total of hydrocarbon resins and oils is greater than 2; and
(F) from 70 to 130 phr of silica;
wherein the weight ratio of silica to the total of hydrocarbon resins and oils is at least 3.6.

Assignees

• Goodyear Tire & Rubber

Inventors

• Isitman Nihat Ali
• Pompei Manuela
• Engeldinger Eric

Classifications

• Y02T10/86

  Optimisation of rolling resistance, e.g. weight reduction · CPC title

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08K3/36

  Silica · CPC title

• B60C1/00 Primary

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title