Reactor layout for methanol production from low quality synthesis gas

Patent metadata

Field	Value
Publication number	US-11117851-B2
Application number	US-201916727319-A
Country	US
Kind code	B2
Filing date	Dec 26, 2019
Priority date	Aug 12, 2015
Publication date	Sep 14, 2021
Grant date	Sep 14, 2021

Abstract

A reactor layout for a process of methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.

First claim

What is claimed is:

1. A reactor layout for carrying out a process for methanol production from synthesis gas, said reactor layout comprising:
one or more methanol pre-converters/guard reactors, in which the synthesis gas is partially converted to methanol over a heterogeneous catalyst to generate an effluent gas without impurities,
a feed-effluent heat exchanger for pre-heating the synthesis gas and for cooling the effluent gas from the one or more methanol pre-converters/guard reactors, and
a methanol synthesis loop comprising:
a main methanol converter for converting a mixture of recycle gas and the cooled effluent gas from the one or more methanol pre-converters/guard reactors,
a main feed-effluent heat exchanger,
a cooler or a series of coolers,
a high pressure gas-liquid separator, which splits the inlet flow into raw methanol and recycle gas,
a recycle compressor,
a loop purge, wherein the loop purge is drawn from the recycle gas before the recycle compressor, and
means for defining and controlling a maximum allowable outlet temperature using a cold recycle gas stream which is injected into the one or more methanol pre-converters/guard reactors via a control valve.

2. The reactor layout according to claim 1 , which has fresh feed gas splitting located on the cold side, before the feed-effluent heat exchanger.

3. The reactor layout according to claim 1 , which enables on-stream catalyst replacement in the one or more pre-converters/guard reactors.

Assignees

• Haldor Topsoe As

Inventors

• Modarresi Hassan

Classifications

• B01J2219/00213

  Fixed parameter value · CPC title

• B01J8/001 Primary

  Controlling catalytic processes (B01J8/1809 takes precedence) · CPC title

• B01J2208/00274

  involving reactant vapours · CPC title

• B01J2208/00716

  Means for reactor start-up · CPC title

• B01J8/0492

  Feeding reactive fluids (for solid material, see B01J8/0015) · CPC title