Three-dimensional printing system, three-dimensional printing method, molding device, fiber-containing object, and production method thereof
US-2017210074-A1 · Jul 27, 2017 · US
US11117312B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11117312-B2 |
| Application number | US-201716071308-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 16, 2017 |
| Priority date | Jan 22, 2016 |
| Publication date | Sep 14, 2021 |
| Grant date | Sep 14, 2021 |
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Provided is the method for manufacturing a three-dimensional structure with a less amount of internal voids or bubbles, and also to provide a 3D printer filament used for manufacturing such three-dimensional structure. The method for manufacturing a three-dimensional structure, the method comprises melting and depositing a filament using a 3D printer, the filament comprising a commingled yarn that contains a continuous reinforcing fiber (A) and a continuous thermoplastic resin fiber (B), with a dispersity of the continuous reinforcing fiber (A) in the commingled yarn of 60 to 100%.
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What is claimed is: 1. A method for manufacturing a three-dimensional structure, the method comprising melting and depositing a filament using a 3D printer, the filament comprising a commingled yarn that contains a continuous reinforcing fiber (A) and a continuous thermoplastic resin fiber (B), with a dispersity of the continuous reinforcing fiber (A) in the commingled yarn of 60 to 100%. 2. The method for manufacturing a three-dimensional structure of claim 1 , wherein the filament has an elastic modulus of 10 MPa or larger, where the elastic modulus is measured by embedding an end of a 15 mm-long filament up to 10 mm-depth by a resin to form a 25 mm-diameter cylinder shape; by inserting the cylindrical resin part directed downward into a 25 mm-diameter, 20 mm-high cylindrical hole of a jig; by fitting a 25 mm-diameter disk-like weight from above the cylindrical resin part into the jig; and thereby applying load at a testing speed of 0.2 mm/min. 3. The method for manufacturing a three-dimensional structure of claim 1 , wherein the filament contains a commingled yarn and a reinforcing member. 4. The method for manufacturing a three-dimensional structure of claim 3 , wherein the reinforcing member is a thermoplastic resin fiber (C). 5. The method for manufacturing a three-dimensional structure of claim 1 , wherein the continuous reinforcing fiber (A) is longer than 30 mm. 6. The method for manufacturing a three-dimensional structure of claim 1 , wherein the continuous thermoplastic resin fiber (B) contains thermoplastic resin b as a constituent, which is a polyamide resin. 7. The method for manufacturing a three-dimensional structure of claim 1 , wherein the continuous thermoplastic resin fiber (B) contains thermoplastic resin b as a constituent, which is a polyamide resin that contains a structural unit derived from diamine and a structural unit derived from dicarboxylic acid, and, 50 mol % or more of the structural unit derived from diamine is derived from xylylenediamine. 8. The method for manufacturing a three-dimensional structure of claim 1 , wherein the continuous reinforcing fiber (A) is a carbon fiber or a glass fiber. 9. The method for manufacturing a three-dimensional structure of claim 1 , wherein the continuous thermoplastic resin fiber (B) has an impregnation rate of 80% or below.
Wound or wrapped core or coating [i.e., spiral or helical] · CPC title
including aramid fibres · CPC title
Carbon; Pitch · CPC title
Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title
using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title
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