Rare earth thin film magnet and production method thereof

Patent metadata

Field	Value
Publication number	US-11114225-B2
Application number	US-201716077961-A
Country	US
Kind code	B2
Filing date	Feb 28, 2017
Priority date	Mar 7, 2016
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

A rare-earth thin film magnet is provided which includes Nd, Fe and B as essential components, characterized by including a Si substrate having an oxide film present on a surface thereof, a Nd base film formed as a first layer over the Si substrate, and a Nd—Fe—B film formed as a second layer on the first layer. The rare earth thin film magnet and a production process therefor provides a rare earth thin film magnet suffering neither film separation nor substrate breakage and having satisfactory magnetic properties even when the second layer has composition in the range of 0.120 ≤Nd/(Nd+Fe)<0.150, which corresponds to a compositional range in the vicinity of a stoichiometric composition.

First claim

The invention claimed is:

1. A rare earth thin film magnet having Nd, Fe and B as essential components comprising: a Nd base film, as a first layer, formed on a Si substrate having an oxide film on a surface thereof; and a Nd—Fe—B film as a second layer on the first layer; a composition (atomic ratio) of Nd—Fe—B of the second layer satisfies a conditional expression of 0.120≤Nd/(Nd+Fe)<0.150; and a film thickness of the second layer is 5 μm or more and 50 μm or less and a film thickness of the first layer is 0.2 μm or more and 5.0 μm or less.

2. The rare earth thin film magnet according to claim 1 , wherein the oxide film is a thermal oxide film.

3. The rare earth thin film magnet according to claim 2 , wherein the rare earth thin film magnet comprises a layer formed from Fe—Si—O between the Si substrate and the Nd base film.

4. The rare earth thin film magnet according to claim 3 , wherein the rare earth thin film magnet has a residual magnetization of 0.55 T or more.

5. The rare earth thin film magnet according to claim 4 , wherein the rare earth thin film magnet has a coercive force of 210 kA/m or more.

6. The rare earth thin film magnet according to claim 5 , wherein the rare earth thin film magnet has a maximum energy product (BH) max of 36 kJ/m 3 or more.

7. A method of producing a rare earth thin film magnet, wherein an oxide film is formed on a Si substrate, a Nd base film as a first layer is formed on the Si substrate via laser pulsed deposition, a Nd—Fe—B film as a second layer is subsequently formed thereon, and heat treatment is thereafter performed thereto to produce a rare earth thin film magnet having Nd, Fe and B as essential components comprising a Nd base film, as a first layer, formed on a Si substrate having an oxide film on a surface thereof, and a Nd—Fe—B film as a second layer on the first layer, a composition (atomic ratio) of Nd—Fe—B of the second layer satisfies a conditional expression of 0.120≤Nd/(Nd+Fe)<0.150, and a film thickness of the second layer is 5 μm or more and 50 μm or less and a film thickness of the first layer is 0.2 μm or more and 5.0 μm or less.

8. The method of producing a rare earth thin film magnet according to claim 7 , wherein the heat treatment is performed at a temperature of 500° C. or higher and 800° C. or less.

9. The rare earth thin film magnet according to claim 1 , wherein the rare earth thin film magnet comprises a layer formed from Fe—Si—O between the Si substrate and the Nd base film.

10. The rare earth thin film magnet according to claim 1 , wherein the rare earth thin film magnet has a residual magnetization of 0.55 T or more.

11. The rare earth thin film magnet according to claim 1 , wherein the rare earth thin film magnet has a coercive force of 210 kA/m or more.

12. The rare earth thin film magnet according to claim 1 , wherein the rare earth thin film magnet has a maximum energy product (BH) max of 36 kJ/m 3 or more.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Nakano Masaki
• Fukunaga Hirotoshi
• Yanai Takeshi
• Sawatari Hironobu

Classifications

• C22C38/00

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title

• H01F41/14

  for applying magnetic films to substrates · CPC title

• C23C14/58

  After-treatment · CPC title

• C23C14/28

  by wave energy or particle radiation (C23C14/32 - C23C14/48 take precedence) · CPC title

• H01F10/14

  containing iron or nickel ({H01F10/126} , H01F10/13, H01F10/16 take precedence) · CPC title