Structurally-colored articles and methods for making and using structurally-colored articles

Patent metadata

Field	Value
Publication number	US-11112537-B2
Application number	US-201816146572-A
Country	US
Kind code	B2
Filing date	Sep 28, 2018
Priority date	Sep 29, 2017
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

One or more aspects of the present disclosure are directed to components having an optical element that imparts structural color to the component or article. The present disclosure is also directed to articles of manufacture including the component having an optical element, and methods for making components and articles having an optical element that imparts structural color.

First claim

What is claimed is:

1. A method of making a textile comprising:
providing a textile having a first surface, the first surface comprising a first thermoplastic material;
softening or melting the first thermoplastic material by increasing a temperature of at least a portion of the first surface of the textile to a first temperature at or above one of a creep relaxation temperature, a heat deflection temperature, a Vicat softening temperature, or a melting temperature of the first thermoplastic material;
altering a texture of the at least a portion of the first surface while the temperature of the first surface is at or above the first temperature by contacting a textured molding surface of a release paper transfer medium with the first surface of the textile and using the textured molding surface to alter the texture of the first surface; and
disposing an optical element onto the first thermoplastic material of the at least a portion of the first surface having the altered texture, wherein the optical element, as disposed on the first surface, imparts a visible structural color and a hue in the visible spectrum to the textile, wherein the structural color is an angle-independent structural color in that the hue, the hue and value, or the hue, value and chroma observed is independent of the angle of observation, wherein the optical element includes a plurality of layers, wherein adjacent layers have different indices of refraction, wherein at least one of the layers has a thickness that is about one-fourth of the wavelength of visible light to be reflected by the optical element to produce the visible structural color.

2. The method of claim 1 , further comprising:
lowering the temperature of the first surface to a second temperature that is below one of the creep relaxation temperature, the heat deflection temperature, the Vicat softening temperature, or the melting temperature of the first thermoplastic material to re-solidify the first thermoplastic material of the at least a portion of the first surface, and then, while the first surface is at or below the second temperature, disposing the optical element onto the at least a portion of the first surface.

3. The method of claim 1 , further comprising:
following the disposing, lowering the temperature of the first surface to a second temperature that is below one of the creep relaxation temperature, the heat deflection temperature, the Vicat softening temperature, or the melting temperature of the first thermoplastic material to re-solidify the first thermoplastic material.

4. The method of claim 1 , wherein the disposing includes disposing the optical element directly on the first surface of the textile using a deposition process.

5. The method of claim 1 , wherein an externally-facing side of the textile includes a first constituent comprising a first fiber, a first yarn, or a first film, and wherein disposing the optical element onto the first surface of the textile includes disposing the optical element onto a first surface of the first constituent of the textile.

6. The method of claim 5 , wherein the textile further comprises a second constituent, wherein the second constituent is a second fiber, a second yarn, or a second film, wherein the second constituent comprises a second polymeric material, wherein the second polymeric material is a second thermoset material or a second thermoplastic material having a creep relaxation temperature, a heat deflection temperature, a Vicat softening temperature, or a melting temperature that is at least 50 degrees C. above the creep relaxation temperature, the heat deflection temperature, the Vicat softening temperature, or the melting temperature of the first thermoplastic material; and
wherein increasing the temperature of the first surface of the article to a first temperature does not result in softening of the second constituent, and disposing the optical element on the textile does not dispose the optical element onto the second constituent, or disposes an amount of the optical element to the second constituent which is at least 20 percent less than an amount of the optical element disposed to the first constituent on a weight or surface area basis.

7. The method of claim 1 , wherein the first surface of the textile, prior to the increasing its temperature, includes a plurality of fibers comprising the first thermoplastic material, wherein the plurality of fibers have a filamentous conformation, and increasing the temperature further comprises:
increasing the temperature of the first thermoplastic material to a first temperature at or above a creep relaxation temperature, a heat deflection temperature, a Vicat softening temperature, or a melting temperature of the first thermoplastic material to soften or melt the first thermoplastic material and alter the conformation of at least a portion of the fibers at the first surface to have a non-filamentous conformation, producing a non-filamentous region on the first surface of the textile; and
wherein disposing the optical element onto the first surface comprises disposing the optical element onto the non-filamentous region of the first surface.

8. The method of claim 7 , further comprising:
lowering the temperature of the first thermoplastic material of the non-filamentous region of the first surface to a second temperature that is below the creep relaxation temperature, the heat deflection temperature, the Vicat softening temperature, or the melting temperature of the first thermoplastic material to re-solidify the first thermoplastic material of the non-filamentous region, and disposing the optical element onto the non-filamentous region while the non-filamentous region is at or below the second temperature.

9. The method of claim 8 , further comprising forming a textured surface on the non-filamentous region prior to disposing the optical element onto the non-filamentous region.

10. The method of claim 1 , further comprising disposing a primer layer having a percent transmittance of about 40 percent or less between the optical element and the first surface of the textile.

11. The method of claim 1 , wherein the optical element has from 2 to 20 layers, each layer independently having a thickness of about 10 to 500 nanometers.

12. The method of claim 1 , wherein the structural color imparted by the optical element is different from the color of the underlying first thermoplastic material.

13. The method of claim 1 , wherein the optical element contains no pigments and no dyes.

14. The method of claim 1 , wherein the structural color produced by optical element is a single-hued color.

15. The method of claim 1 , wherein the structural color has a hue selected from cyan, indigo, violet, blue, blue-green, and purple green.

16. The method of claim 1 , wherein a first layer of the optical element comprises titanium dioxide, wherein a second layer of the optical element comprises silicon dioxide, and wherein the first layer and the second layer are adjacent one another.

17. The method of claim 1 , wherein the angle-independent structural color displays the same hue or substantially the same hue when viewed from at least 3 different angles that are at least 15 degrees apart from each other to the textile.

Assignees

• Nike Inc

Inventors

• Bee Jennifer
• Gantz Jeremy
• Kovel Kim

Classifications

• B23B3/30

  Turning-machines with two or more working-spindles, e.g. in fixed arrangement · CPC title

• G02B5/285

  comprising deposited thin solid films (G02B5/281 - G02B5/289 take precedence; multilayered film filters for fibre optic multiplexing G02B6/29361) · CPC title

• G02B5/26

  Reflecting filters (G02B5/28 takes precedence) · CPC title

• B32B7/023 Primary

  Optical properties · CPC title

• A43B13/02

  characterised by the material · CPC title