High melt flow fluoropolymer composition

Patent metadata

Field	Value
Publication number	US-11111612-B2
Application number	US-201515312363-A
Country	US
Kind code	B2
Filing date	May 19, 2015
Priority date	May 19, 2014
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

The invention relates to very high melt flow fluoropolymer compositions, having low melt viscosities. The fluoropolymers have low molecular weights of from 5 kDa to 200 kDa and melt viscosities of less than 2 kilopoise (kP) at 232° C. and 100 s−1. One use for the high melt flow fluoropolymers is in the formation of very small diameters fibers, useful for melt-blown non-woven materials. Fiber diameters of less than 9 microns, and preferably 500 to 2000 nm can be produced.

First claim

What is claimed is:

1. A fluoropolymer composition comprising a fluoropolymer, wherein said fluoropolymer is a homopolymer of vinylidene fluoride or a copolymer having a random homogeneous distribution of monomers and at least 70 weight percent of vinylidene fluoride monomer units; and wherein said fluoropolymer has a melt viscosity of 0.01 to 0.4 kP, at 100 s −1 and 232° C., as measured by parallel plate rheology, and has a weight average molecular weight of from 15,000 to 140,000 Dalton as measured by GPC relative to polymethyl methacrylate (PMMA) narrow standards.

2. The fluoropolymer composition of claim 1 , wherein said copolymer further comprises fluoromonomer(s) are selected from the group consisting of tetrafluorethylene (TFE), trifluoroethylene (TrFE), chlorotrifluoroethylene (CTFE), dichlorodifluoroethylene, hexafluoropropene (HFP), vinyl fluoride (VF), hexafluoroisobutylene (HFIB), perfluorobytylethylene (PFBE), pentafluoropropene, 3,3,-trifluoro-1-propene, 2-trifluoromethyl-3,3,3-trifluoropropene, fluorinated vinyl ethers including perfluoropropylvinyl ether (PPVE), perfluorobutylvinyl ether (PBVE), longer chain perflurinated vinyl ethers, fluorinated dioxoles, partially- or per-fluorinated alpha olefins of C 4 and higher, partially- or per-fluorinated cyclic alkenes of C 3 and higher, and combinations thereof.

3. The fluoropolymer composition of claim 2 , wherein said fluoropolymer hexafluoropropene monomer units.

4. The fluoropolymer composition of claim 1 , comprising said fluoropolymer and further comprising-one or more additives selected from the group consisting of plasticizers, inorganic fillers, colorants, dyes, antioxidants, compatible non-fluoropolymers, (meth)acrylate homopolymers and copolymers, and solvents.

5. An article comprising the fluoropolymer composition of claim 1 .

6. The article of claim 5 , wherein said article comprises 2 or more fibers having a number average diameter of less than 9.0 microns.

7. The article of claim 6 , wherein said article comprises 2 or more fibers having a number average diameter of from 50 t 5,000 nanometers.

8. The article of claim 6 , wherein said fibers have a number average diameter of from 500 to 2000 mu.

9. The article of claim 6 , wherein said fibers are formed by a melt-blowing process.

10. The article of claim 6 , wherein said article is a non-woven material comprising fluoropolymer fibers having a number average diameter of from 500-2,000 nm.

11. The article of claim 10 , wherein said non-woven material is a composite non-woven material, containing at least 1 weight percent of said fluoropolymer fibers having a number average diameter of from 500 to 2000 nm.

12. The article of claim 10 , wherein said non-woven article is a composite non-woven comprising said fluoropolymer fibers having a number average diameter of from 500 to 2000 nm, and further comprising one or more fibers selected from fluoropolymers having a diameter greater than 2.0 micron, and the fibers of any diameter selected from the group consisting of polyesters, polyolefins, poly(meth)acrylates, glass fibers, carbon fibers, celluloses, polyaramids, polysulfones, polyamides, polyimides, polyethers, polyether ketones, polycarbonates, polyether polylactic acids, polystyrenics, theremoplastic starch and carbon nanotubes.

13. The article of claim 10 , wherein said fluoropolymer fibers have been internally cross-linked after being formed into said article.

14. A process for forming the article of claim 5 , wherein said article is subjected to one or more of the following process either during formation of the article, or following the formation of the article:
a. calendaring, bonding, needle-punching, entanglement, stretching, pleating, electrical charging;
b. chemical, electromagnetic radiation, plasma, or thermal treatment;
c. cutting, grinding or chopping into shorter pieces;
d. pleating, stretching, or compression;
e. coloring or dying.

15. The article of claim 5 , wherein said article is an injection-molded part.

16. The article of claim 5 , wherein said article is bonded to a substrate.

17. The article of claim 16 , wherein said substrate comprises cellulose, glass fiber, metal fiber or wire, or non-fluorinated thermoplastic fibers.

Assignees

• Arkema Inc

Inventors

• Goldbach James T
• Henry James J
• Stabler Sean M
• Chauveau Jérôme

Classifications

• C08F114/22

  Vinylidene fluoride · CPC title

• D04H1/4318

  Fluorine series · CPC title

• C08F214/222

  with fluorinated vinyl ethers · CPC title

• D04H1/56 Primary

  in association with fibre formation, e.g. immediately following extrusion of staple fibres · CPC title

• C08F14/22

  Vinylidene fluoride · CPC title