Iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites, preparation method and application thereof

Patent metadata

Field	Value
Publication number	US-11111605-B2
Application number	US-201816171317-A
Country	US
Kind code	B2
Filing date	Oct 25, 2018
Priority date	Oct 26, 2017
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

Iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites, preparation method and its application in wastewater treatment are disclosed. Bismuth citrate and sodium carbonate as precursors, sodium carbonate as a precipitating agent, dispersed in a mixed solution of water and ethylene glycol, sodium iodide as a iodine source, nano carbon fiber membrane act as the carrier, to synthesis carbon fiber membrane that modified by iodine-doped Bi2O2CO3 nanosheets; then sodium molybdate and thioacetamide as precursors, dispersed in water to react to obtain iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites. The composite material synthesized through a series of steps exhibit excellent photocatalytic activity for the degradation of Rhodamine B and can be recycled for many times. And this invention has the advantages of simple preparation process, easy recovery and multiple use, etc., and has industrial application prospect in water pollution treatment.

First claim

What is claimed is:

1. A preparation method of iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites, characterized in comprising the following steps:
(1) dispersing nano carbon fiber membrane, bismuth citrate, sodium iodide and sodium carbonate in a mixed solution of water and ethylene glycol to obtain a kind of nano carbon fiber material modified by iodine doped bismuthyl carbonate;
(2) dispersing sodium molybdate and thioacetamide in water, then adding said nano carbon fiber material modified by iodine doped bismuthyl carbonate, reacting to obtain iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites.

2. The preparation method of iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites according to claim 1 , wherein in step (1), using an N.N-dimethylformamide solution of polyacrylonitrile as raw material, obtaining polyacrylonitrile fiber membrane by electrospinning method, then calcining to obtain nano carbon fiber membrane; the diameter of said nano carbon fiber membrane is 0.5 μm.

3. The preparation method of iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites according to claim 2 , wherein in step (1), the calcination conditions are calcination for 3 to 6 hours under argon, the calcination temperature is 400 to 600° C., the heating rate is 2 to 15° C. per minute.

4. The preparation method of iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites according to claim 1 , wherein in step (1), the mass ratio of said bismuth citrate, sodium carbonate, sodium iodide and said nanocarbon fiber membrane is (132 to 134):(38 to 40):100:(8 to 10), after dispersing nano carbon fiber membrane, bismuth citrate, sodium iodide and sodium carbonate in a mixed solution of water and ethylene glycol, waiting 2 to 4 hours to start the reaction, the reaction temperature is 150 to 180° C., and reaction time is 24 to 36 hours.

5. The preparation method of iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites according to claim 1 , wherein in step (2), the mass ratio of said sodium molybdate and thioacetamide is 1.2:1, dispersing said sodium molybdate and thioacetamide in water, after ultrasonic treatment for half an hour, adding said nano carbon fiber material modified by iodine doped bismuthyl carbonate, the reaction temperature is 180 to 250° C., reaction time is 6 to 8 hours.

6. The preparation method of iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites according to claim 1 , wherein in step (1), after the reaction is finished, the product is washed with water and ethanol respectively, and then vacuum-dried to obtain nano carbon fiber material modified by iodine doped bismuthyl carbonate; in step (2), the product is washed with water and ethanol respectively, and then vacuum-dried to obtain iodine doped bismuthyl carbonate nanosheet and molybdenum disulfide modified carbon nanofiber composites.

7. A preparation method of nano carbon fiber material modified by iodine doped bismuthyl carbonate, characterized in comprising the following steps: dispersing nano carbon fiber membrane, bismuth citrate, sodium iodide and sodium carbonate in a mixed solution of water and ethylene glycol to obtain a kind of nano carbon fiber material modified by iodine doped bismuthyl carbonate.

8. The preparation method of nano carbon fiber material modified by iodine doped bismuthyl carbonate according to claim 7 , wherein using an N.N-dimethylformamide solution of polyacrylonitrile as raw material, obtaining polyacrylonitrile fiber membrane by electrospinning method, then calcining to obtain nano carbon fiber membrane; the diameter of said nano carbon fiber membrane is 0.5 μm, the mass ratio of said bismuth citrate, sodium carbonate, sodium iodide and said nanocarbon fiber membrane is (132 to 134):(38 to 40):100:(8 to 10), after dispersing nano carbon fiber membrane, bismuth citrate, sodium iodide and sodium carbonate in a mixed solution of water and ethylene glycol, waiting 2 to 4 hours to start the reaction, the reaction temperature is 150 to 180° C., and reaction time is 24 to 36 hours.

Assignees

• Univ Soochow

Inventors

• Lu Jianmei
• Chen Dongyun

Classifications

• D01F9/22

  from polyacrylonitriles · CPC title

• D01F11/127

  Metals (metal depositing by electrolysis D01F11/16; metal alloys with reinforcing carbon fibres C22C49/14) · CPC title

• D01D10/02

  Heat treatment (heating for finishing D02J13/00) · CPC title

• C01P2002/50

  Solid solutions · CPC title

• C01B32/156

  After-treatment · CPC title