Electrolytic cell and electrolytic device for carbon dioxide

Patent metadata

Field	Value
Publication number	US-11111589-B2
Application number	US-201916560380-A
Country	US
Kind code	B2
Filing date	Sep 4, 2019
Priority date	Mar 16, 2018
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

An electrolytic cell for carbon dioxide of an embodiment includes: an anode part including an anode to oxidize water or a hydroxide ion and thus produce oxygen and an anode solution flow path to supply an anode solution to the anode; a cathode part including a cathode to reduce carbon dioxide and thus produce a carbon compound, a cathode solution flow path to supply a cathode solution to the cathode, a gas flow path to supply the carbon dioxide to the cathode, and a hydrophobic porous body disposed between the cathode and the gas flow path; and a separator to separate the anode part and the cathode part from each other.

First claim

What is claimed is:

1. An electrolytic cell for carbon dioxide comprising:
an anode part including an anode to oxidize water or a hydroxide ion and thus produce oxygen and an anode solution flow path to supply an anode solution to the anode;
a cathode part including a cathode to reduce carbon dioxide and thus produce a carbon compound, a cathode solution flow path to supply a cathode solution to the cathode, a gas flow path to supply the carbon dioxide to the cathode, and a hydrophobic porous body disposed between the cathode and the gas flow path; and
a separator to separate the anode part and the cathode part from each other,
wherein the cathode includes a catalyst layer facing the cathode solution flow path and a gas diffusion layer in contact with the hydrophobic porous body, and the hydrophobic porous body is disposed between the gas diffusion layer and the gas flow path.

2. The cell according to claim 1 , wherein the hydrophobic porous body contains a fluororesin in an amount of 50 mass % or more as a hydrophobic substance.

3. The cell according to claim 1 ,
wherein the hydrophobic porous body contains a fluororesin in an amount of 50 mass % or more as a hydrophobic substance, and
wherein the gas diffusion layer contains a fluororesin in an amount of not less than 5 mass % nor more than 10 mass % as a hydrophobic substance.

4. The cell according to claim 1 , wherein the hydrophobic porous body has a porosity of not less than 40% nor more than 90%.

5. The cell according to claim 1 , wherein the anode part includes an anode current collector plate in electrical connection with the anode, and the cathode part includes a cathode current collector plate in electrical connection with the cathode.

6. The cell according to claim 5 , wherein the cathode current collector plate is disposed between the cathode solution flow path and the cathode.

7. The cell according to claim 6 , wherein the cathode current collector plate has an opening with a 40% open area ratio or more.

8. The cell according to claim 5 , wherein the cathode current collector plate is disposed between the cathode and the hydrophobic porous body.

9. The cell according to claim 8 , wherein the cathode current collector plate has an opening with a 40% open area ratio or more.

10. The cell according to claim 1 , wherein the hydrophobic porous body is larger in area than the cathode.

11. An electrolytic device for carbon dioxide comprising:
the electrolytic cell according to claim 1 ; and
a power source to pass a current across the anode and the cathode of the electrolytic cell.

12. An electrolytic cell for carbon dioxide comprising:
an anode part including an anode to oxidize water or a hydroxide ion and thus produce oxygen and an anode solution flow path to supply an anode solution to the anode;
a cathode part including a cathode to reduce carbon dioxide and thus produce a carbon compound, a cathode solution flow path to supply a cathode solution to the cathode, a gas flow path to supply the carbon dioxide to the cathode, and a hydrophobic porous body disposed between the cathode and the gas flow path; and
a separator to separate the anode part and the cathode part from each other,
wherein the hydrophobic porous body contains a fluororesin in an amount of 50 mass % or more as a hydrophobic substance.

13. The cell according to claim 12 , wherein the hydrophobic porous body has a porosity of not less than 40% nor more than 90%.

14. The cell according to claim 12 , wherein the anode part includes an anode current collector plate in electrical connection with the anode, and the cathode part includes a cathode current collector plate in electrical connection with the cathode.

15. The cell according to claim 14 , wherein the cathode current collector plate is disposed between the cathode solution flow path and the cathode.

16. The cell according to claim 14 , wherein the cathode current collector plate is disposed between the cathode and the hydrophobic porous body.

17. An electrolytic device for carbon dioxide comprising:
the electrolytic cell according to claim 12 ; and
a power source to pass a current across the anode and the cathode of the electrolytic cell.

18. An electrolytic cell for carbon dioxide comprising:
an anode part including an anode to oxidize water or a hydroxide ion and thus produce oxygen and an anode solution flow path to supply an anode solution to the anode;
a cathode part including a cathode to reduce carbon dioxide and thus produce a carbon compound, a cathode solution flow path to supply a cathode solution to the cathode, a gas flow path to supply the carbon dioxide to the cathode, and a hydrophobic porous body disposed between the cathode and the gas flow path; and
a separator to separate the anode part and the cathode part from each other, wherein the anode part includes an anode current collector plate in electrical connection with the anode, and the cathode part includes a cathode current collector plate in electrical connection with the cathode, and
wherein the cathode current collector plate is disposed between the cathode and the hydrophobic porous body.

19. The cell according to claim 18 , wherein the cathode current collector plate has an opening with a 40% open area ratio or more.

20. An electrolytic device for carbon dioxide comprising:
the electrolytic cell according to claim 18 ; and
a power source to pass a current across the anode and the cathode of the electrolytic cell.

Assignees

• Toshiba Kk

Inventors

• Kudo Yuki
• Ono Akihiko
• Yamagiwa Masakazu
• Kitagawa Ryota
• Tamura Jun
• Sugano Yoshitsune
• Tsukagoshi Takayuki
• MOTOSHIGE Asahi
• Mikoshiba Satoshi

Classifications

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C25B9/73

  of the filter-press type · CPC title

• C25B15/08 Primary

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25B9/23 Primary

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• C25B1/04

  by electrolysis of water · CPC title