Polycarbonate-polyorganosiloxane copolymer, polycarbonate resin composition including same, and molded product thereof

Patent metadata

Field	Value
Publication number	US-11111386-B2
Application number	US-201816490048-A
Country	US
Kind code	B2
Filing date	Mar 1, 2018
Priority date	Mar 1, 2017
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a):15≤wM1  (F1a)wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.

First claim

The invention claimed is:

1. A polycarbonate-based resin composition, comprising:
a polycarbonate-polyorganosiloxane copolymer (A) comprising polycarbonate blocks (A-1) each formed of a repeating unit represented by the following general formula (I); and
polyorganosiloxane blocks (A-2) each containing a repeating unit represented by the following general formula (II), wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a):
15≤ wM 1  (F1a)

wherein wM1 represents an average content (mass %) of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography;
an aromatic polycarbonate-based resin (B) except the polycarbonate-polyorganosiloxane copolymer (A); and
a polyester-based resin (C),
wherein the polyester-based resin (C) is blended with respect to 100 parts by mass of a total of the polycarbonate-polyorganosiloxane copolymer (A) and the aromatic polycarbonate-based resin (B), and
wherein a ratio of the polycarbonate-polyorganosiloxane copolymer (A) and the aromatic polycarbonate-based resin (B) in 100 mass % of a total amount of the polycarbonate-polyorganosiloxane copolymer (A) and the aromatic polycarbonate-based resin (B), and the polyester-based resin (C) is from 50 mass % or more to 99 mass % or less:

wherein R 1 and R 2 each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms, X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, a fluorenediyl group, an arylalkylene group having 7 to 15 carbon atoms, an arylalkylidene group having 7 to 15 carbon atoms, —S—, —SO—, —SO 2 —, —O—, or —CO—, R 3 and R 4 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and “a” and “b” each independently represent an integer of from 0 to 4.

2. The polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the aromatic polycarbonate-based resin (B) contains a polycarbonate block including, in a main chain thereof, a repeating unit represented by the following general formula (III):

wherein R 30 and R 31 each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms, X′ represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, —S—, —SO—, —SO 2 —, —O—, or —CO—, and “d” and “e” each independently represent an integer of from 0 to 4.

3. The polycarbonate-based resin composition according to claim 1 , wherein a mass ratio “(A)/(B)” of the polycarbonate-polyorganosiloxane copolymer (A) to the aromatic polycarbonate-based resin (B) is from 0.1/99.9 to 99.9/0.1.

4. The polycarbonate-based resin composition according to claim 1 , wherein a content of the polyorganosiloxane blocks (A-2) with respect to a total of the polycarbonate-polyorganosiloxane copolymer (A) and the aromatic polycarbonate-based resin (B) is from 0.1 mass % or more to 10 mass % or less.

5. The polycarbonate-based resin composition according to claim 1 , wherein a polycarbonate-based resin formed of the polycarbonate-polyorganosiloxane copolymer (A) and the aromatic polycarbonate-based resin (B) has a viscosity-average molecular weight (Mv) of from 9,000 or more to 50,000 or less.

6. The polycarbonate-based resin composition according to claim 1 , wherein the polyester-based resin (C) comprises at least one selected from a polyethylene terephthalate and a polybutylene terephthalate.

7. A molded article, which is obtained by molding the polycarbonate-based resin composition of claim 1 .

8. The molded article according to claim 7 , wherein the molded article comprises a casing for electrical and electronic equipment.

9. The molded article according to claim 7 , wherein the molded article comprises a part for an automobile and a building material.

Assignees

• Idemitsu Kosan Co

Inventors

• Ishikawa Yasuhiro
• Abe Tomoko
• Akimoto Takafumi

Classifications

• C08G64/34 Primary

  and cyclic ethers · CPC title

• C08G64/186 Primary

  containing polysiloxane sequences · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08G64/18

  Block or graft polymers · CPC title

• C08L83/04 Primary

  Polysiloxanes · CPC title