Flame retardant polymer composite materials and methods of making the same

Patent metadata

Field	Value
Publication number	US-11111364-B2
Application number	US-201716083880-A
Country	US
Kind code	B2
Filing date	Mar 10, 2017
Priority date	Mar 11, 2016
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

A polymer composite material includes a blend of one or more thermoplastic polymers and one or more bio-based flame retardant additives, wherein the one or more bio-based flame retardant additives are present in an amount of 35 to 100 parts per 100 parts by weight of the one or more thermo-plastic polymers. A method of forming the polymer composite material includes: blending the one or more thermoplastic polymers and the one or more bio-based flame retardant additives together at a temperature between 140° C. and 230° C. to form the polymer composite material; forming an article from the polymer composite material; and cooling the formed article.

First claim

The invention claimed is:

1. A polymer composite material, comprising a blend of one or more thermoplastic polymers and one or more bio-based flame retardant additives, wherein the one or more thermoplastic polymers comprises polystyrene and the one or more bio-based flame retardant additives comprises gelatin, wherein the one or more bio-based flame retardant additives are present in an amount of 35 to 100 parts per 100 parts by weight of the one or more thermoplastic polymers, and wherein the gelatin is present from about 40 to about 100 parts per 100 parts by weight of the one or more thermoplastic polymers.

2. The polymer composite material of claim 1 , wherein the one or more bio-based flame retardant additives further comprises tannic acid.

3. The polymer composite material of claim 2 , further comprising one or more additional flame retardant additive other than the gelatin and tannic acid.

4. The polymer composite material of claim 1 , wherein the gelatin comprises fish gelatin.

5. The polymer composite material of claim 1 , wherein the one or more thermoplastic polymers further comprises polyethylene.

6. The polymer composite material of claim 1 , wherein the one or more thermoplastic polymers further comprises low-density polyethylene (LDPE).

7. The polymer composite material of claim 1 , wherein the one or more thermoplastic polymers further comprises polypropylene.

8. The polymer composite material of claim 1 , wherein the one or more thermoplastic polymers further comprises one or more of acrylonitrile butadiene styrene (ABS) copolymer, nylon 6, nylon 6,6, polyamides, poly(butylene terephthalate), poly(ethylene terephthalate) and its copolymers, polyesters, thermoplastic polyurethanes, polyester-ether elastomers, and polyacetal.

9. The polymer composite material of claim 1 , wherein the polystyrene is expanded polystyrene.

10. The polymer composite material of claim 9 , wherein the polymer composite material is a foam material.

11. The polymer composite material of claim 1 , further comprising one or more maleated polymers.

12. The polymer composite material of claim 1 , further comprising one or more of citric acid, stearic acid, silicone oil, and dibenzylidene sorbitol.

13. The polymer composite material of claim 1 , further comprising one or more of PTFE, alumina, and clay.

14. A method of forming the polymer composite material of claim 1 , comprising:
blending the one or more thermoplastic polymers and the one or more bio-based flame retardant additives together at a temperature between 140° C. and 240° C. to form the polymer composite material;
forming an article from the polymer composite material; and
cooling the formed article.

Assignees

• Univ Case Western Reserve

Inventors

• Deans Taneisha
• Schiraldi David

Classifications

• C07G1/00

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• C09K21/06

  Organic materials · CPC title

• C08K5/1545

  Six-membered rings · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08L89/06

  derived from leather or skin {, e.g. gelatin} · CPC title