System and method for manufacturing ester-based composition

Patent metadata

Field	Value
Publication number	US-11111203-B2
Application number	US-202016838593-A
Country	US
Kind code	B2
Filing date	Apr 2, 2020
Priority date	Apr 4, 2019
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

The present disclosure relates to a method and a system for manufacturing an ester-based composition which are characterized in sequentially operating a plurality of batch reactors, and since an ester-based composition is semi-continuously manufactured, the productivity is high and the stability of a batch reactor is secured.

First claim

The invention claimed is:

1. A system for manufacturing an ester-based composition, the system comprising:
a mixer in which a reaction mixture of a polycarboxylic acid and a first alcohol having 3 to 10 alkyl carbon atoms is formed, wherein the mixer comprises a polycarboxylic acid injection path and a first alcohol injection path;
a reaction unit provided with N number of batch reactors connected in parallel in which an esterification reaction of the reaction mixture is performed, an inlet line for receiving the reaction mixture from the mixer, and an outlet line for discharging reaction products from the N number of batch reactors;
a supply control unit for controlling the injection amount and the injection path of the reaction mixture such that the reaction mixture is sequentially supplied to the N number of batch reactors from the mixer to allow the reaction to be sequentially completed, wherein the supply control unit is disposed between the mixer and the reaction unit; and
a separation unit for receiving the reaction products through the outlet line of the reaction unit and removing unreacted alcohol therefrom.

2. The system of claim 1 , further comprising a trans-reaction unit for performing a trans-esterification reaction by adding a second alcohol having 3 to 10 alkyl carbon atoms to the reaction products from which the unreacted alcohol has been removed, wherein the second alcohol injected from the trans-reaction unit is different from the first alcohol injected from the mixer.

3. The system of claim 1 , wherein at least one batch reactor a mong the N number of batch reactors comprises a gas-liquid separation column connected to an upper portion of the batch reactor and separating alcohol and water discharged through the upper portion of the batch reactor, a condenser for cooling a gas discharged through an upper line of the gas-liquid separation column, and a decanter for separating a liquid discharged through a lower line of the gas-liquid separation column and a liquid condensed in the condenser into different layers and recirculating the alcohol into the batch reactor.

4. The system of claim 1 , wherein the supply control unit controls one or more of the injection path and the injection flow rate of the reaction mixture to be changed according a predetermined time interval.

5. The system of claim 4 , wherein the time interval is 50% to 150% of a value obtained by dividing the reaction duration in one batch reactor by N.

6. A system for manufacturing an ester-based composition, the system comprising:
a mixer in which a reaction mixture of a polycarboxylic acid and a first alcohol having 3 to 10 alkyl carbon atoms is formed, wherein the mixer comprises a polycarboxylic acid injection path and a first alcohol injection path;
a reaction unit provided with N number of batch reactors connected in parallel in which an esterification reaction of the reaction mixture is performed, an inlet line for receiving the reaction mixture from the mixer, and an outlet line for discharging reaction products from the N number of batch reactors;
a supply control unit for controlling the injection amount and the injection path of the reaction mixture such that the reaction mixture is sequentially supplied to the N number of batch reactors from the mixer to allow the reaction to be sequentially completed, wherein the supply control unit is disposed between the mixer and the reaction unit; and
a separation unit for receiving the reaction products through the outlet line of the reaction unit and removing unreacted alcohol therefrom,
wherein the polycarboxylic acid is one or more selected from the group consisting of a dicarboxylic acid, a tricarboxylic acid, and a tetracarboxylic acid.

7. The system of claim 6 , wherein
the dicarboxylic acid is one or more selected from the group consisting of a linear dicarboxylic acid having 2 to 10 carbon atoms, a terephthalic acid, a phthalic acid, an isophthalic acid, a cyclohexane dicarboxylic acid, an anhydride thereof, and a derivative thereof,
the tricarboxylic acid is one or more selected from the group consisting of a citric acid, a trimellitate acid, a cyclohexane tricarboxylic acid, an anhydride thereof, and a derivative thereof, and
the tetracarboxylic acid is one or more selected from the group consisting of a benzenetetracarboxylic acid, a furantetracarboxylic acid, a cyclohexane tetracarboxylic acid, a tetrahydrofuran tetracarboxylic acid, an anhydride thereof, and a derivative thereof.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Hyun Kyu
• Lee Sung Kyu
• Moon Jeong Ju
• Jun Hyoung
• Jin Chan Hyu

Classifications

• C07C67/08 Primary

  by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

• B01J19/2445 Primary

  placed in parallel · CPC title

• C07C67/03

  by reacting an ester group with a hydroxy group · CPC title

• B01J2219/00038

  Processes in parallel · CPC title

• B01J2531/46

  Titanium · CPC title