Methods and systems for producing para-xylene from C8-containing compositions

Patent metadata

Field	Value
Publication number	US-11111192-B2
Application number	US-202016936904-A
Country	US
Kind code	B2
Filing date	Jul 23, 2020
Priority date	Feb 22, 2019
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

A method for producing para-xylene (PX) includes introducing a C8 aromatic-containing composition to a xylene rerun column to separate the C8 aromatic-containing composition into a xylene-containing effluent and a heavy effluent and passing the xylene-containing effluent to a PX processing loop that includes a PX recovery unit operable to separate a PX product from the xylene-containing effluent, a membrane isomerization unit operable to convert a portion of the MX, OX, or both from the xylene-containing effluent to PX, an EB dealkylation unit operable to dealkylate EB from the xylene-containing effluent to produce benzene, toluene, and other C7− compounds, and a membrane separation unit operable to produce a permeate that is PX-rich and a retentate that is PX-lean. The permeate is passed to the PX recovery unit for recovery of PX, which the retentate is bypassed around the PX recovery unit circulated through the xylene processing loop.

First claim

What is claimed is:

1. A system for producing para-xylene (PX) from a C 8 aromatic-containing composition, the system comprising:
a xylene rerun column operable to separate the C 8 aromatic-containing composition into a xylene-containing effluent and a heavy effluent, the xylene-containing effluent comprising at least PX and one or more of ortho-xylene (OX), meta-xylene (MX), ethylbenzene (EB), or combinations of these;
a xylene processing loop comprising:
a PX recovery unit operable to separate the xylene-containing effluent into at least a PX product and a PX-depleted effluent;
an ethylbenzene dealkylation unit directly downstream of the PX recovery unit so that the PX-depleted effluent passes directly from the PX recovery unit to the ethylbenzene dealkylation unit, and operable to dealkylate at least a portion of the EB from the PX-depleted effluent to produce a dealkylation effluent comprising one or more C 7− compounds;
a stripper disposed directly downstream of the ethylbenzene dealkylation unit, the stripper operable to separate the dealkylation effluent into a C 7− effluent, an EB-depleted effluent, and a stripper bottoms;
a membrane isomerization unit disposed downstream of the stripper and operable to receive the EB-depleted effluent from the stripper and convert at least a portion of the MX, OX, EB, or combinations of these, in the EB-depleted effluent to PX to produce an isomerate; and
a membrane separation unit operable to separate the isomerate into a permeate that is PX-rich and a retentate that is PX-lean;
where the stripper is fluidly coupled to the xylene rerun column to recycle the stripper bottoms back to the xylene rerun column.

2. The system of claim 1 , in which the membrane isomerization unit comprises an acidic sulfonated catalytic membrane.

3. The system of claim 1 , in which the membrane separation unit comprises a carbon-based membrane.

4. The system of claim 1 , in which the PX-recovery unit is directly downstream of the xylene rerun column so that the xylene-containing effluent passes directly from the xylene rerun column to the PX recovery unit.

5. The system of claim 1 , in which the membrane separation unit is downstream of the xylene rerun column, and in which the PX recovery unit, the EB dealkylation unit, and the membrane isomerization unit are downstream of the membrane separation unit.

6. The system of claim 1 , in which the membrane separation unit is directly downstream of the membrane isomerization unit.

7. The system of claim 1 , where the EB-depleted effluent from the stripper is in fluid communication with the membrane isomerization unit to pass the EB-depleted effluent from the stripper to membrane isomerization unit.

8. The system of claim 1 , where the permeate from the membrane separation unit is in fluid communication with the PX recovery unit to pass the permeate from the membrane separation unit to the PX recovery unit.

9. The system of claim 1 , where the permeate from the membrane separation unit is in fluid communication with the xylene-containing effluent to combine the permeate with the xylene-containing effluent upstream of the PX-recovery unit.

10. The system of claim 1 , where the retentate is in fluid communication with the ethylbenzene dealkylation unit to pass the retentate from the membrane separation unit directly to the ethylbenzene dealkylation unit.

11. The system of claim 1 , where the retentate is in fluid communication with the PX-depleted effluent to combine the retentate with the PX-depleted effluent upstream of the ethylbenzene dealkylation unit.

12. The system of claim 1 , where the membrane separation unit is directly downstream of the xylene rerun column and the PX-recovery unit is directly downstream of the membrane separation unit.

13. The system of claim 12 , where:
the membrane separation unit is in fluid communication with the xylene rerun column to pass the xylene-containing effluent directly from the xylene rerun column to the membrane separation unit; and
the membrane separation unit is in fluid communication with the membrane isomerization unit to pass the isomerate directly from the membrane isomerization unit to the membrane separation unit.

Assignees

• Saudi Arabian Oil Co

Inventors

• Zhang Zhonglin
• Shaikh Sohel K
• Tammana Veera Venkata R
• Abudawoud Raed H
• Beadle Bruce Richard
• Bassam Hisham Tawfiq
• Bilaus Rakan Sulaiman

Classifications

• C07C7/144 Primary

  using membranes, e.g. selective permeation · CPC title

• C07C5/2743

  Acids of sulfur; Salts thereof; Sulfur oxides · CPC title

• C07C4/12

  from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene · CPC title

• C07C7/14

  by crystallisation; Purification or separation of the crystals · CPC title

• C07C5/2732 Primary

  Catalytic processes · CPC title