Immobilized metalloporphyrin catalyst and its utilization in maleic acid preparation

Patent metadata

Field	Value
Publication number	US-11110445-B2
Application number	US-201916702172-A
Country	US
Kind code	B2
Filing date	Dec 3, 2019
Priority date	Mar 20, 2017
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

The present disclosure discloses an immobilized metalloporphyrin catalyst and its utilization in maleic acid preparation, belonging to the technical field of metalloporphyrin catalytic application. The immobilized metalloporphyrin catalyst is used for catalyzing furfural to prepare maleic acid and is good in catalytic effect, mild in reaction conditions and capable of greatly reducing the energy consumption required in the prior art. The catalyst disclosed by the present disclosure can provide a good microenvironment for a reaction, so that the yield and selectivity of maleic acid are increased; and according to a method disclosed by the present disclosure, the conversion ratio of furfural is 20.4%-95.6%, the yield of maleic acid is 10%-56.1%, and the selectivity is 43.6%-76.1%. Meanwhile, the catalyst is easy to separate and environmentally friendly and may be recycled for many times.

First claim

What is claimed is:

1. The method of using an immobilized metalloporphyrin catalyst, comprising oxidizing furfural with the immobilized metalloporphyrin catalyst, and obtaining maleic acid; wherein furfural serves as a substrate, oxygen serves as an oxidant and immobilized metalloporphyrin catalyst serves as a catalyst for producing maleic acid; wherein a weight ratio of amount of the immobilized metalloporphyrin catalyst to furfural is 20-100 milligrams of the immobilized metalloporphyrin catalyst per 0.282 gram of furfural; wherein the immobilized metalloporphyrin catalyst is obtained after combining metalloporphyrin with a molecular sieve carrier; wherein structural formula of the metalloporphyrin is

where R is selected from H, Br, Cl, F, CH 3 , OCH 3 , SO 3 Na and COOCH 3 ; and M represents for a metal element Fe, Mn, Co, Cu, Zn or Ni.

2. The method according to claim 1 , wherein the molecular sieve carrier is selected from a group consisting of MCM-41, SBA-15, ZSM-5, and a combination thereof.

Assignees

• Univ Jiangnan

Inventors

• Wang Haijun
• Huang Yi
• Wu Chunyan
• Yuan Wenwen

Classifications

• B01J2531/025

  Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles · CPC title

• B01J2231/70

  Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues · CPC title

• B01J2531/72

  Manganese · CPC title

• B01J2531/845

  Cobalt · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title