Alumina having acidity and structure with a porosity which are optimal

Patent metadata

Field	Value
Publication number	US-11110431-B2
Application number	US-201916521813-A
Country	US
Kind code	B2
Filing date	Jul 25, 2019
Priority date	Jul 25, 2018
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

An alumina exhibiting a structure with a porosity such that the volume of the pores having a diameter of between 70 and 2000 Å is between 0.15 and 0.50 ml/g, and comprising at least one alkali metal (M), such that the content by weight of alkali metal, expressed as M2O, is between 400 and 1500 ppm, with respect to the total weight of the alumina, and a process for the transformation of a feedstock comprising at least one alcohol into an olefinic effluent, said process comprising a stage of dehydration of said alcohol in the presence of the alumina according to the present invention, having an acidity and a structure with a porosity which are optimal.

First claim

The invention claimed is:

1. An alumina exhibiting a structure with a porosity such that the content of pores having a diameter of between 70 and 2000 Å is between 0.15 and 0.50 ml/g, and comprising at least one alkali metal (M), such that the content by weight of alkali metal, expressed as M 2 O, is between 400 and 1500 ppm, with respect to the total weight of the alumina, wherein the alumina exhibits a BET specific surface area of at least 150 m 2 /g and wherein the alumina contains at most 500 ppm by weight of silica, expressed as SiO 2 .

2. The alumina according to claim 1 , in which the volume of the pores having a diameter of between 70 and 2000 Å is greater than or equal to 0.20 ml/g, and less than or equal to 0.40 ml/g.

3. The alumina according to claim 1 , in which the content by weight of alkali metal, expressed as M 2 O, is between 400 and 950 ppm, with respect to the total weight of the alumina.

4. The alumina according to claim 1 , in which the total pore volume is greater than or equal to 0.50 ml/g.

5. The alumina according to claim 1 , exhibiting a volume of the pores with a diameter of greater than or equal to 70 Å, denoted V 70 Å , of greater than or equal to 0.35 ml/g.

6. The alumina according to claim 1 , exhibiting a BET specific surface area of at least 200 m 2 /g, and of at most 350 m 2 /g.

7. The alumina according to claim 1 , containing at most 100 ppm by weight of silica, expressed as SiO 2 .

8. The alumina according to claim 1 , having a structure comprising χ-alumina and amorphous alumina.

9. The alumina according to claim 1 , containing strictly less than 80% by weight of γ-alumina.

10. The alumina according claim 1 , containing strictly less than 35% by weight of η-alumina.

11. The alumina according to claim 1 , obtained by rapid dehydration of an aluminium hydroxide or oxyhydroxide.

12. A process for the transformation of a feedstock comprising at least one alcohol into an olefinic effluent, said process comprising a stage of dehydration of said alcohol in the presence of the alumina according to claim 1 .

13. The process according to claim 12 , in which the feedstock comprises at least 50% by weight of alcohol, with respect to the weight of said feedstock.

14. The process according to claim 12 , in which said alcohol comprises from 3 to 9 carbon atoms.

15. The process according to claim 12 , in which said alcohol is a secondary and/or tertiary alcohol.

16. The process according to claim 12 , in which the dehydration stage comprises a reaction section in which the dehydration reaction is carried out in the gas phase, in the liquid phase or in a mixed phase, at a temperature of between 200° C. and 450° C., at a pressure of between 0.1 and 4 MPa and with an hourly space velocity (HSV) of between 0.5 h −1 and 10 h −1 .

Assignees

• Axens

Inventors

• Nedez Christophe
• Ducreux Olivier

Classifications

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J21/04 Primary

  Alumina · CPC title

• B01J23/002

  Mixed oxides other than spinels, e.g. perovskite · CPC title

• B01J23/92

  of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 · CPC title

• Y02P20/584

  Recycling of catalysts · CPC title