System for simultaneously removing nitrogen oxides (NOx) and sulfur oxides (SOx) from exhaust gas

Patent metadata

Field	Value
Publication number	US-11110391-B2
Application number	US-201916245208-A
Country	US
Kind code	B2
Filing date	Jan 10, 2019
Priority date	Jan 25, 2018
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

A system for oxidizing nitrogen monoxide (NO) contained in exhaust gas injects a liquid oxidizing agent into the exhaust gas and simultaneously removes nitrogen oxides and sulfur oxides from exhaust gas using an organic catalyst. The system includes an absorption tank for storing an absorption solution containing an organic catalyst, the absorption tank communicating with an oxygen supply pipe for supplying oxygen-containing gas to the absorption tank; an absorption tower, extending upward from the absorption tank, through which the exhaust gas flows from an exhaust gas inlet duct to an exhaust gas outlet; a first injection unit to inject the absorption solution into the absorption tower; a second injection unit to inject an oxidizing agent solution into at least one of the inlet duct and the absorption tower; and an oxidizing agent supply unit for supplying the oxidizing agent solution to the second injection unit.

First claim

What is claimed is:

1. A system for simultaneously removing nitrogen oxides and sulfur oxides from exhaust gas, the system comprising:
an absorption tank for storing an absorption solution containing an organic catalyst, the absorption tank communicating with an oxygen supply pipe for supplying oxygen-containing gas to the absorption tank;
an absorption tower, extending upward from the absorption tank, through which the exhaust gas flows from an exhaust gas inlet duct to an exhaust gas outlet;
a first injection unit to inject the absorption solution into the absorption tower;
a second injection unit to inject an oxidizing agent solution into at least one of the inlet duct and the absorption tower; and
an oxidizing agent supply unit for supplying the oxidizing agent solution to the second injection unit.

2. The system according to claim 1 , wherein the organic catalyst includes an oil-derived organic sulfoxide.

3. The system according to claim 1 , wherein the oxidizing agent in the oxidizing agent solution includes at least one of H2O2, NaClO2, KMnO4, and P4O10.

4. The system according to claim 1 , wherein the exhaust gas introduced into the inlet duct primarily comes into contact with the oxidizing agent solution injected by the second injection unit, and secondarily comes into contact with the absorption solution injected by the first injection unit.

5. The system according to claim 1 , wherein the oxidizing agent supply unit comprises:
a storage tank for storing the oxidizing agent solution; and
a feed pump for supplying the stored oxidizing agent solution to the second injection unit.

6. The system according to claim 1 , wherein the second injection unit comprises a tray having a plurality of nozzles from which the oxidizing agent solution is injected.

7. The system according to claim 6 , wherein each of the nozzles is equipped with an ultrasonic mist generator.

8. The system according to claim 6 , wherein the tray consists of a plurality of trays alternately and respectively installed on opposite sides of the absorption tower.

9. The system according to claim 1 , further comprising a concentration meter for measuring a concentration of nitrogen monoxide (NO) in the exhaust gas introduced into the inlet duct.

10. The system according to claim 9 , further comprising a control unit to control an injection amount of the oxidizing agent solution injected by the second injection unit according to the concentration of nitrogen monoxide (NO) in exhaust gas measured by the concentration meter.

11. The system according to claim 10 , wherein the control unit is configured to increase the injection amount of the oxidizing agent solution injected by the second injection unit when the concentration of nitrogen monoxide (NO) in exhaust gas measured by the concentration meter exceeds a reference value, and to decrease the injection amount of the oxidizing agent solution injected by the second injection unit when the concentration of nitrogen monoxide (NO) in exhaust gas measured by the concentration meter does not exceed the reference value.

12. The system according to claim 1 , further comprising a turbulence generator installed in at least one of the inlet duct and the absorption tower.

13. The system according to claim 1 , further comprising a neutralization tank to neutralize nitric acid and sulfuric acid released from the absorption tank.

14. The system according to claim 13 , wherein the neutralizing agent for neutralization includes one of ammonia-water, urea-water, and calcium carbonate aqueous solution.

15. The system according to claim 1 , wherein a flow rate of the absorption solution injected by the first injection unit is regulated.

16. The system according to claim 1 , wherein the first injection unit comprises:
a plurality of header pipes installed in the absorption tower;
a plurality of injection nozzles installed to each of the header pipes;
a circulation pump for supplying the absorption solution in the absorption tank to the header pipes;
a first connection pipe connected to the circulation pump; and
a plurality of second connection pipes branched from the first connection pipe to be respectively connected to the header pipes.

17. The system according to claim 16 , wherein the first connection pipe is provided with a first flow control valve to regulate a flow rate of the absorption solution introduced into the second connection pipes.

18. The system according to claim 16 , wherein each of the second connection pipes is provided with a second flow control valve to regulate a flow rate of the absorption solution introduced into the header pipe connected to that second connection pipe.

19. The system according to claim 1 , further comprising at least one of:
a first flow meter installed in the inlet duct to measure a flow rate of the exhaust gas introduced through the inlet duct; and
a second flow meter installed in each of a plurality of regions in the absorption tower to measure a flow rate of exhaust gas in that region.

20. The system according to claim 1 , further comprising at least one of:
a first concentration meter installed in the inlet duct to measure a concentration of sulfur dioxide in the exhaust gas introduced through the inlet duct; and
a second concentration meter installed in each of a plurality of regions in the absorption tower to measure a concentration of sulfur dioxide in exhaust gas in that region.

Assignees

• Doosan Heavy Ind & Construction Co Ltd

Inventors

• Kim Joon Ho
• Jo Ho Yong
• Koo Ja Hyung
• Chang In Gab

Classifications

• B01D53/1481 Primary

  Removing sulfur dioxide or sulfur trioxide · CPC title

• B01D53/185 Primary

  Liquid distributors · CPC title

• B01D53/8637

  Simultaneously removing sulfur oxides and nitrogen oxides · CPC title

• B01D2257/302

  Sulfur oxides · CPC title

• B01D53/78

  with gas-liquid contact · CPC title