Nitride Semiconductor Ultraviolet Light Emitting Device and Method for Manufacturing Same
US-2018277723-A1 · Sep 27, 2018 · US
US11107961B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11107961-B2 |
| Application number | US-201716753714-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 2, 2017 |
| Priority date | Nov 2, 2017 |
| Publication date | Aug 31, 2021 |
| Grant date | Aug 31, 2021 |
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The ultraviolet light-emitting device includes a base, a nitride semiconductor ultraviolet light-emitting element flip-chip mounted on the base, and a lens for sealing a nitride semiconductor ultraviolet light-emitting element to focus or diffuse light emitted from the nitride semiconductor ultraviolet light-emitting device. The lens is composed of an amorphous fluororesin in which a structural unit of a polymer or copolymer has a fluorine-containing aliphatic cyclic structure and a terminal functional group is a perfluoroalkyl group, and a density of the amorphous fluororesin is higher than 2.11 g/cm 3 .
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The invention claimed is: 1. An ultraviolet light-emitting device comprising: a base; a nitride semiconductor ultraviolet light-emitting element flip-chip mounted on the base; and a lens that seals the nitride semiconductor ultraviolet light-emitting element and focuses or diffuses light emitted from the nitride semiconductor ultraviolet light-emitting device, wherein the lens is composed of an amorphous fluororesin in which a structural unit of a polymer or copolymer has a fluorine-containing aliphatic cyclic structure and a terminal functional group is a perfluoroalkyl group, and a density of the amorphous fluororesin is larger than 2.11 g/cm 3 . 2. The ultraviolet light-emitting device according to claim 1 , wherein the density of amorphous fluororesin constituting the lens is greater than 2.21 g/cm 3 . 3. The ultraviolet light-emitting device according to claim 1 , wherein a part of a surface of the lens may be a spherical surface or a convex curved surface. 4. The ultraviolet light-emitting device according to claim 1 , wherein the emission center wavelength of the nitride semiconductor ultraviolet light-emitting element is 200 nm or more and 365 nm or less. 5. A method for manufacturing an ultraviolet light-emitting device, the method comprising: a first step of sealing a nitride semiconductor ultraviolet light-emitting element flip-chip mounted on a base to form a lens for focusing or diffusing light emitted from the nitride semiconductor ultraviolet light-emitting element; wherein the lens is formed of an amorphous fluororesin in which a structural unit of a polymer or copolymer has a fluorine-containing aliphatic cyclic structure and a terminal functional group is a perfluoroalkyl group; and, in the first step or a subsequent step, the amorphous fluororesin constituting the lens is heated to a glass transition temperature or higher, a pressure of 35 MPa or higher is applied to the amorphous fluororesin, and the lens is cooled to a temperature lower than the glass-transition temperature by 30° C. or more while the pressure is applied, thereby densifying the amorphous fluororesin. 6. The method for manufacturing an ultraviolet light-emitting device according to claim 5 , the method further comprising: simultaneously forming the lens for sealing each of a plurality of nitride semiconductor ultraviolet light-emitting elements flip-chip mounted on a base plate in which a plurality of bases are integrated in the first step; and a second step of dividing the base plate so that one or more of the nitride semiconductor ultraviolet light-emitting element sealed by the lens are included after densifying the amorphous fluororesin constituting the lens. 7. A method for manufacturing an ultraviolet light-emitting module, the method comprising: a third step of mounting one or more of ultraviolet light-emitting device having a nitride semiconductor ultraviolet light-emitting element flip-chip mounted on a base and sealed by a lens on a mounting member; and a fourth step of densifying the amorphous fluororesin after the third step, wherein the lens is formed of an amorphous fluororesin in which a structural unit of a polymer or copolymer has a fluorine-containing aliphatic cyclic structure and a terminal functional group is a perfluoroalkyl group; and in the fourth step, the amorphous fluororesin constituting the lens is heated to a glass-transition temperature or higher, a pressure of 35 MPa or higher is applied to the amorphous fluororesin, and the lens is cooled to a temperature lower than the glass-transition temperature by 30° C. or more while the pressure is applied.
of optical field-shaping means · CPC title
of encapsulations · CPC title
Interconnections, e.g. lead-frames, bond wires or solder balls · CPC title
characterised by their material, e.g. epoxy or silicone resins · CPC title
containing nitrogen, e.g. GaN · CPC title
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