Flow reactor synthesis of polymers

Patent metadata

Field	Value
Publication number	US-11104765-B2
Application number	US-202016742282-A
Country	US
Kind code	B2
Filing date	Jan 14, 2020
Priority date	Oct 13, 2015
Publication date	Aug 31, 2021
Grant date	Aug 31, 2021

Abstract

A flow reactor system and methods having tubing useful as polymerization chamber. The flow reactor has at least one inlet and at least one mixing chamber, and an outlet. The method includes providing two phases, an aqueous phase and a non-aqueous phase and forming an emulsion for introduction into the flow reactor.

First claim

What is claimed is:

1. A method for polymerizing one or more monomers for producing a polymer salt comprising:
introducing, using a fluid flow control device, a reactant composition comprising an aqueous monomer solution of the one or more monomers and a non-aqueous solution into a mixing chamber;
emulsifying the reactant composition in the mixing chamber;
controlling a flow of the reactant composition that was emulsified into an amount of tubing via an inlet port of the amount of tubing, wherein the amount of tubing comprises a length and an inner diameter;
controlling a temperature of at least a portion of the amount of tubing;
polymerizing the one or more monomers; and
forming, in the amount of tubing, a polymer salt from the one or more monomers that were polymerized.

2. The method of claim 1 , wherein introducing, using a fluid flow control device, a reactant composition comprising an aqueous monomer solution of the one or more monomers and a non-aqueous solution into a mixing chamber comprises using an aqueous monomer fluid flow control device and a non-aqueous fluid flow control device.

3. The method of claim 1 , further comprising introducing a catalyst and the reactant composition that was emulsified in the mixing chamber into a second mixing chamber.

4. The method of claim 1 , further comprising introducing an organic solvent to the amount of tubing to recover the polymer salt.

5. The method of claim 4 , further comprising flushing the amount to tubing with water prior to introducing the organic solvent to recover the polymer salt.

6. A method for continuous flow synthesis of polyaniline (PAM) salt, comprising:
introducing, using a fluid flow control device, a reactant composition comprising an aqueous aniline solution and a non-aqueous acid solution into a mixing chamber;
emulsifying, in the mixing chamber, the reactant composition;
flowing a portion of the reactant composition that was emulsified into an amount of tubing via an inlet port of the amount of tubing fluidically coupled to an outlet of the mixing chamber to obtain a threshold back pressure, wherein the amount of tubing comprises a length and an inner diameter;
controlling a temperature of at least a portion of the amount of tubing; and
forming, in the amount of tubing, a polyaniline (PAM) salt.

7. The method of claim 6 , wherein introducing, using a fluid flow control device, a reactant composition comprising an aqueous monomer solution of the one or more monomers and a non-aqueous solution into a mixing chamber comprises using an aqueous monomer fluid flow control device and a non-aqueous fluid flow control device.

8. The method of claim 6 , further comprising introducing a catalyst and the reactant composition that was emulsified in the mixing chamber into a second mixing chamber.

9. The method of claim 6 , further comprising terminating flowing the portion of the reactant composition that was emulsified into the amount of tubing.

10. The method of claim 9 , further comprising flushing the amount of tubing with water subsequent to terminating flowing the portion of the reactant composition that was emulsified into the amount of tubing.

11. The method of claim 10 , further comprising introducing an organic solvent to the amount of tubing to recover the polyaniline (PANT) salt subsequent to flushing the amount to tubing with water.

12. The method claim 8 , further comprising flowing a second portion of the reactant composition that was emulsified into a second amount of tubing via a second inlet port of the second amount of tubing fluidically coupled to the outlet of the second mixing chamber to obtain the threshold back pressure, wherein the second amount of tubing comprises a length and an inner diameter.

13. The method of claim 12 , further comprising terminating flowing the second portion of the reactant composition that was emulsified into the second amount of tubing.

14. The method of claim 13 , further comprising flushing the second amount of tubing with water subsequent to terminating flowing the second portion of the reactant composition that was emulsified into the second amount of tubing.

15. The method of claim 12 , further comprising introducing an organic solvent to the second amount of tubing to recover the polyaniline (PANT) salt subsequent to flushing the amount to tubing with water.

16. A method for diffusion limited synthesis of a conductive polymer salt:
introducing, using a fluid flow control device, a reactant composition comprising an aqueous monomer solution and a non-aqueous acid solution into a mixing chamber;
emulsifying, in the mixing chamber, the reactant composition;
flowing the reactant composition that was emulsified into an amount of tubing via an inlet port of the amount of tubing fluidically coupled to an outlet of the mixing chamber and controlling a temperature of at least a portion of the amount of tubing to provide a diffusion limited polymerization condition within the amount of tubing, wherein the amount of tubing comprises a length and an inner diameter;
forming, in the amount of tubing, a polyaniline (PANT) salt; and
discharging the polyaniline (PANT) salt from an outlet port of the amount of tubing.

17. The method of claim 16 , wherein introducing, using a fluid flow control device, a reactant composition comprising an aqueous monomer solution and a non-aqueous acid solution into a mixing chamber comprises using an aqueous monomer fluid flow control device and a non-aqueous fluid flow control device.

18. The method of claim 16 , further comprising introducing a catalyst and the reactant composition that was emulsified in the mixing chamber into a second mixing chamber.

19. The method of claim 16 , further comprising introducing an organic solvent to the amount of tubing to recover the polymer salt.

20. A method for polymerizing a monomer for producing a polymer salt comprising:
introducing an emulsion comprising a monomer and an acid into a flow reactor, the flow reactor comprising a length of tubing;
polymerizing the monomer; and
forming a salt of the polymerized monomer with the acid within the length of tubing.

Assignees

• Boeing Co

Inventors

• Kinlen Patrick John
• Zweig Andrew M

Classifications

• C08K5/42

  Sulfonic acids; Derivatives thereof · CPC title

• C08G73/0266 Primary

  Polyanilines or derivatives thereof · CPC title

• B01J2219/00891

  Feeding or evacuation · CPC title

• B01J2219/00889

  Mixing · CPC title

• B01J2219/00792

  One or more tube-shaped elements · CPC title