Method for preparing methyl mercaptan

Patent metadata

Field	Value
Publication number	US-11104642-B2
Application number	US-202016869826-A
Country	US
Kind code	B2
Filing date	May 8, 2020
Priority date	Jul 4, 2014
Publication date	Aug 31, 2021
Grant date	Aug 31, 2021

Abstract

The present invention relates to a method for preparing methyl mercaptan, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a) such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and possibly hydrogen (H2); c) optionally recirculating said hydrogen sulphide (H2S) formed during step b) to step a); and d) recovering the methyl mercaptan.

First claim

The invention claimed is:

1. Process for preparing methyl mercaptan, said process being batchwise or continuous and comprising at least the following steps:
a) reaction of at least one hydrocarbon charge in the presence of hydrogen sulphide (H 2 S) and optionally of sulphur (S) to form carbon disulphide (CS 2 ) and hydrogen (H 2 ),
b) hydrogenation reaction of said carbon disulphide (CS 2 ) in the presence of said hydrogen (H 2 ), both obtained in step a), to form methyl mercaptan (CH 3 SH), hydrogen sulphide (H 2 S) and optionally hydrogen (H 2 ),
c) optionally, recycling said hydrogen sulphide (H 2 S) formed in step b) to step a), and
d) recovery of the methyl mercaptan.

2. Process according to claim 1 , wherein the hydrocarbon charge is in gaseous, liquid or solid form, and comprises at least one hydrocarbon having a hydrocarbon chain in saturated or unsaturated linear, branched or cyclic form.

3. Process according to claim 1 , wherein the hydrocarbon charge comprises at least one alkane.

4. Process according to claim 1 , wherein the hydrocarbon charge is methane.

5. Process according to claim 1 , wherein the hydrogen sulphide formed in step b) is recycled into step a).

6. Process according to claim 1 , wherein the hydrogen optionally formed in step b) may be reacted with sulphur to form hydrogen sulphide.

7. Process according to claim 1 , wherein the molar H 2 S/hydrocarbon charge ratio is between 0 and about 100.

8. Process according to claim 1 , wherein the reaction temperature in step a) is between 500° C. and 1300° C.

9. Process according to claim 1 , wherein the reaction temperature in step b) is between 100° C. and 400° C.

10. Process according to claim 1 , wherein the methyl mercaptan is reacted with sulphur to form dimethyl disulphide.

11. Process according to claim 1 , wherein the process is a continuous process.

12. Process according to claim 2 , wherein the hydrocarbon charge is in gaseous or liquid form.

13. Process according to claim 2 , wherein the hydrocarbon charge is in gaseous form.

14. Process according to claim 3 , wherein the hydrocarbon charge is at least one of methane, ethane, propane and butane.

15. Process according to claim 7 , wherein the molar H 2 S/hydrocarbon charge ratio is between 0.5 and about 10.

16. Process according to claim 7 , wherein the molar H 2 S/hydrocarbon charge ratio is between 1 and about 3.

17. Process according to claim 8 , wherein the reaction temperature in step a) is between 700° C. and 1100° C.

18. Process according to claim 8 , wherein the reaction temperature in step a) is between 800° C. and 1000° C.

19. Process according to claim 9 , wherein the reaction temperature in step b) is between 200° C. and 300° C.

Assignees

• Arkema France

Inventors

• Fremy Georges
• Barre Patrice
• Raymond Jean-Michel

Classifications

• B01J2219/00033

  Continuous processes · CPC title

• C01B32/75 Primary

  Preparation by reacting sulfur or sulfur compounds with hydrocarbons · CPC title

• C07C321/14

  of an acyclic saturated carbon skeleton · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• C07C319/02 Primary

  of thiols · CPC title