System and method for storing hydrogen

Patent metadata

Field	Value
Publication number	US-11101479-B2
Application number	US-201916453713-A
Country	US
Kind code	B2
Filing date	Jun 26, 2019
Priority date	Jun 26, 2019
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

A system includes a canister and a fuel cell. The canister defines an internal volume configured to have a hydride bed positioned therein. The canister includes at least 1.0 kWH/kg of energy based on a heating value of 120 kJ/g of hydrogen present. The hydride bed includes lithium aluminum hydride, aluminum hydride, or a combination thereof. The hydride bed is configured to release hydrogen gas when heated to a predetermined temperature. The fuel cell is configured to receive the hydrogen gas from the canister and to use the hydrogen gas as fuel to produce power for a load.

First claim

What is claimed is:

1. A canister, comprising:
a body defining a single, contiguous internal volume configured to have a hydride bed positioned therein, wherein the hydride bed comprises lithium aluminum hydride, aluminum hydride, or a combination thereof, wherein a scaling factor of the canister is greater than about 0.5 and less than about 1.0, wherein the scaling factor comprises a mass of the hydride bed divided by a mass of the canister with the hydride bed therein, and wherein the canister comprises at least 1.0 kWH/kg of energy;
a first heater element positioned at least partially in the internal volume and embedded at least partially within the hydride bed, wherein the first heater element is oriented in a helical configuration, and wherein the first heater element is configured to heat the hydride bed substantially uniformly, thereby causing the hydride bed to release hydrogen; and
a first temperature sensor positioned at least partially in the internal volume, wherein the first temperature sensor is configured to measure a temperature in the internal volume.

2. The canister of claim 1 , further comprising a second heater element positioned at least partially in the internal volume, wherein the first heater element and the second heater element are oriented in a double helix configuration within the internal volume.

3. The canister of claim 2 , wherein the first heater element is positioned radially-inward from the second heater element.

4. The canister of claim 3 , wherein the first temperature sensor is coupled to the first heater element.

5. The canister of claim 4 , further comprising a second temperature sensor that is coupled to the second heater element or to an inner surface of the body, wherein the second temperature sensor is configured to measure the temperature in the internal volume closer to the inner surface of the body than the first temperature sensor.

6. The canister of claim 5 , further comprising a third temperature sensor that is coupled to an outer surface of the body, wherein the third temperature sensor is configured to measure a temperature of an outer surface of the body.

7. The canister of claim 5 , wherein the body defines a first cable opening configured to have the first heater element extending therethrough and into the internal volume, and wherein the canister further comprises a first wire interconnect coupled to the body proximate to the first cable opening, wherein the first wire interconnect comprises:
an inner washer positioned in the internal volume;
an inner electrical connection positioned in the internal volume, wherein the inner washer is positioned between the inner electrical connection and the inner surface of the body;
an outer washer positioned outside of the body;
an outer electrical connection positioned outside of the body, wherein the outer washer is positioned between the outer electrical connection and the outer surface of the body; and
an adhesive positioned on the inner washer, the inner electrical connection, the outer washer, and the outer electrical connection.

8. The canister of claim 7 , wherein the body further defines:
a second cable opening configured to have the second heater element extending therethrough and into the internal volume;
a third cable opening configured to have the first temperature sensor extending therethrough and into the internal volume; and
a fourth cable opening configured to have the second temperature sensor extending therethrough and into the internal volume.

9. The canister of claim 7 , wherein the body defines a fluid opening through which the hydrogen flows, and wherein the canister further comprises:
an inner flange portion positioned in the internal volume, wherein the inner flange portion is at least partially frustoconical;
an outer nut portion positioned outside of the body; and
a connector extending at least partially through the fluid opening, wherein the inner flange portion and the outer nut portion are coupled to the connector.

10. The canister of claim 9 , further comprising:
a filter coupled to the inner flange portion and configured to prevent particles in the hydrogen from flowing out of the canister; and
a tube extending at least partially through the fluid opening and the connector, wherein an end of the tube is positioned between the filter and the fluid opening.

11. A system, comprising:
a canister defining an internal volume configured to have a hydride bed positioned therein, wherein the canister comprises a heater element comprising first and second heater portions in the internal volume that are oriented in a concentric double helix configuration with the first helix portion being located radially inward from the second helix portion, wherein the canister comprises at least 1.0 kWH/kg of energy based on a heating value of 120 kJ/g of hydrogen present, wherein the hydride bed comprises lithium aluminum hydride, aluminum hydride, or a combination thereof, and wherein the hydride bed is configured to release hydrogen gas when heated to a predetermined temperature; and
a fuel cell configured to receive the hydrogen gas from the canister and to use the hydrogen gas as fuel to produce power for a load.

12. The system of claim 11 , wherein a total amount of energy stored in the canister is from about 0.1 kWh to about 50 kWh, and wherein a mass of the hydride bed is from about 0.03 kg to about 20 kg.

13. The system of claim 11 , wherein a scaling factor of the canister is greater than about 0.5 and less than about 1.0, and wherein the scaling factor comprises a mass of the hydride bed divided by a mass of the canister with the hydride bed therein.

14. The system of claim 11 , wherein a specific energy of the canister is from about 1.9 kWh/kg to about 2.7 kWh/kg.

15. The system of claim 11 , wherein an energy density of the canister is from about 2 kWh/L to about 2.7 kWh/L.

16. A method, comprising: storing a hydride bed in a canister; heating the hydride bed with a first heater element in the canister, which causes the hydride bed to release hydrogen gas, wherein the first heater element is oriented in a helical configuration: transferring the hydrogen gas from the canister to a fuel cell; generating power with the fuel cell using the hydrogen gas as fuel; and providing the power from the fuel cell to a load to power the load,
wherein a scaling factor of the canister is greater than about 0.5 and less than about 1.0; a specific energy of the canister is from about 1.9 kWh/kg to about 2.7 kWh/kg; and an energy density of the canister is from about 2 kWh/L to about 2.7 kWh/L.

17. The method of claim 16 , further comprising providing the power from the fuel cell to the first heater element to power the first heater element.

18. The method of claim 16 , further comprising:
measuring a first temperature inside the canister using a first temperature sensor, wherein the first temperature sensor is coupled to the first heater element;
measuring a second temperature inside the canister using a second temperature sensor, wherein the second temperature sensor is coupled to a second heater element in the canister, and wherein the first and second heater elements are oriented in a concentric double helix configuration; and
measuring a third temperature outside the canister using a third temperature sensor.

19. The method of claim 18 , further comprising controlling an amount of heat generated in the canister with the first heater element and the second heater element based at least partially upon the first temperatu

Assignees

• Boeing Co

Inventors

• Graetz Jason
• Sorensen Adam E
• Vajo John J

Classifications

• H01M8/1018

  Polymeric electrolyte materials · CPC title

• H01M8/04089 Primary

  of gaseous reactants · CPC title

• H01M8/04373

  of auxiliary devices, e.g. reformers, compressors, burners · CPC title

• H01M8/04619

  of fuel cell stacks · CPC title

• H01M8/065 Primary

  by dissolution of metals or alloys; by dehydriding metallic substances · CPC title