Low sulfur fuel with adequate combustion quality

Patent metadata

Field	Value
Publication number	US-11099144-B2
Application number	US-201916716941-A
Country	US
Kind code	B2
Filing date	Dec 17, 2019
Priority date	Jul 22, 2019
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

Fuel compositions that are low sulfur and have adequate combustion quality are disclosed. An example fuel composition that is low sulfur may have the following enumerated properties: a sulfur content of about 0.50% or less by weight of the fuel composition; a calculated carbon aromaticity index of about 870 or less; a density at 15° C. of about 900 kg/m3 to about 1,010 kg/m3; a kinematic viscosity at 50° C. of about 100 centistokes to about 700 centistokes; and an estimated cetane number of about 7 or greater.

First claim

The invention claimed is:

1. A fuel composition having low sulfur content comprising from 10 vol % to 90 vol % of at least one petroleum distillate fraction having a cetane index of at least 8 and a residual component at from 10 vol % to 90 vol %, the fuel composition having the following enumerated properties:
a sulfur content of about 0.50% or less by weight of the fuel composition;
a calculated carbon aromaticity index of about 870 or less;
a density at 15° C. of about 900 kg/m 3 to about 1,010 kg/m 3 ;
a kinematic viscosity at 50° C. of about 100 centistokes to about 700 centistokes; and
an estimated cetane number of about 7 to about 13.

2. The fuel composition of claim 1 , wherein the sulfur content is about 0.40 wt. % to about 0.5 wt. %.

3. The fuel composition of claim 1 , wherein the calculated aromaticity index is about 800 to about 870, wherein the density at 15° C. is about 950 kg/km 3 to about 1,000 kg/m 3 , wherein the kinematic viscosity at 50° C. is about 100 centistokes to about 380 centistokes, and wherein the estimated cetane number is about 7 to about 10.

4. The fuel composition of claim 1 , wherein the fuel composition is a residual marine fuel.

5. The fuel composition of claim 1 , wherein the residual component comprises a vacuum residual.

6. The fuel composition of claim 1 , wherein the residual component comprises a vacuum residual and FCC bottoms.

7. The fuel composition of claim 1 , wherein the at least one petroleum distillate fraction is present in an amount of about 25 vol. % or greater and has a cetane index of about 8 to about 29.

8. The fuel composition of claim 1 , wherein the at least one petroleum distillate fraction is present in an amount of about 10 vol. % or greater and has a cetane index of about 30 or greater.

9. The fuel composition of claim 1 , wherein the fuel composition comprises a residual component in an amount of about 50 vol. % to about 80 vol. % and a petroleum distillate fraction in an amount of about 20 vol. % to about 50 vol. %, wherein the petroleum distillate fraction has a cetane index of from about 8 to about 29.

10. The fuel composition of claim 1 , wherein the fuel composition comprises a first residual component in an amount of about 40 vol. % to about 65 vol. %, a second residual component in an amount of about 5 vol. % to about 20 vol. %, and a petroleum distillate fraction in an amount of about 15 vol. % to about 55 vol. %, wherein the petroleum distillate fraction has a cetane index of from about 8 to about 29.

11. The fuel composition of claim 1 , wherein the fuel composition comprises a residual component in an amount of about 45 vol. % to about 65 vol. %, a first petroleum distillate fraction in an amount of about 30 vol. % to about 40 vol. %, and a second petroleum distillate fraction in an amount of about 5 vol. % to about 25 vol. %, wherein the first petroleum distillate fraction has a cetane index of about 8 to about 29, and wherein the second petroleum distillate fraction has a cetane index of about 30 or greater.

12. The fuel composition of claim 1 , wherein the fuel composition comprises a first residual component in an amount of about 45 vol. % to about 65 vol. %, a second residual component in an amount of about 5 vol. % to about 20 vol. %, and a petroleum distillate fraction in an amount of about 5 vol. % to about 40 vol. %, wherein the petroleum distillate fraction has a cetane index of about 30 or greater.

13. The fuel composition of claim 1 , wherein the fuel composition comprises a first residual component in an amount of about 40 vol. % to about 60 vol. %, a second residual component in an amount of about 5 vol. % to about 20 vol. %, a first petroleum distillate fraction in an amount of about 10 vol. % to about 40 vol. %, and a second petroleum distillate fraction in an amount of about 5 vol. % to about 30 vol. %, wherein the first petroleum distillate fraction has a cetane index of about 8 to about 29, and wherein the second petroleum distillate fraction has a cetane index of about 30 or greater.

14. The fuel composition of claim 1 , wherein the fuel composition comprises a residual component having a T50 of about 615° C. or greater and a first distillate fraction having a density of about 910 kg/m 3 or less, and wherein the fuel composition is further characterized by at least one of the following: (i) an amount of about 25 vol. % or greater of the first distillate fraction with a cetane index of about 8 to about 29 or (ii) further comprising a second distillate fraction in an amount of about 10 vol. % or greater with a cetane index of about 30 or greater.

15. A method of blending fuel compositions, comprising:
blending at from 10 vol % to 90 vol % of one or more residual components and one or more petroleum distillate fractions to prepare a fuel composition, wherein the fuel composition includes from 10 vol % to 90 vol % of the one or more petroleum distillate fractions having a cetane index of at least 8, wherein the fuel composition has the following enumerated properties:
a sulfur content of about 0.50% or less by weight of the fuel composition;
a calculated carbon aromaticity index of about 870 or less;
a density at 15° C. of about 900 kg/m 3 to about 1,010 kg/m 3 ;
a kinematic viscosity at 50° C. of about 100 centistokes to about 700 centistokes; and
an estimated cetane number of about 7 to about 13.

16. The method of claim 15 , wherein the calculated aromaticity index is about 800 to about 870, wherein the density at 15° C. is about 950 kg/km 3 to about 1,000 kg/m 3 , and wherein the kinematic viscosity at 50° C. is about 100 centistokes to about 380 centistokes, and estimated cetane number is about 7 to about 13.

17. The method of claim 15 , wherein the petroleum distillate fraction comprises at least one of (i) a first distillate fraction in an amount of about 25 vol. % or greater with a cetane index of about 8 to about 29; or (ii) a second distillate fraction in an amount of about 10 vol. % or greater with a cetane index of about 30 or greater.

18. The method of claim 15 , wherein the one or more residual components comprises a residual component having a T50 of about 615° C. or greater, and wherein one or more petroleum distillate fractions comprises a first distillate fraction having a density of about 910 kg/m 3 or less.

19. The method of claim 15 , wherein the blending comprises blending an additional distillate fraction in an amount of about 10 vol. % or greater with a cetane index of about 30 or greater to enhance combustion quality of the fuel composition.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Fruchey Erin R
• Golisz Suzanne R
• Kar Kenneth C H
• Rubin-Pitel Sheryl B

Classifications

• G01N33/2829

  Mixtures of fuels · CPC title

• C10L1/04

  essentially based on blends of hydrocarbons · CPC title

• C10L2270/026

  for diesel engines, e.g. automobiles, stationary, marine · CPC title

• C10L2200/0461

  Fractions defined by their origin · CPC title

• C10L2290/543

  Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title