Carbonaceous nanoparticles as conductivity enhancement additives to water-in-oil emulsions, oil-in-water emulsions and oil-based wellbore fluids

Patent metadata

Field	Value
Publication number	US-11098233-B2
Application number	US-201314649604-A
Country	US
Kind code	B2
Filing date	Dec 4, 2013
Priority date	Dec 4, 2012
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

Various embodiments of the present disclosure provide methods of making wellbore fluids with enhanced electrical conductivities. In some embodiments, such methods comprise: (1) pre-treating a carbon material with an acid; and (2) adding the carbon material to the wellbore fluid. Further embodiments of the present disclosure pertain to wellbore fluids formed by the methods of the present disclosure. Additional embodiments of the present disclosure pertain to methods for logging a subterranean well by utilizing the aforementioned wellbore fluids.

First claim

What is claimed is:

1. A method for logging a subterranean well, wherein the method comprises:
treating a carbon material with at least one acid to provide an acid-treated carbon material,
wherein the at least one acid comprises at least hypophosphoric acid, and
wherein the acid-treated carbon material is selected from the group consisting of graphene-based carbon materials, graphite-based carbon materials, and combinations thereof;

adding the acid-treated carbon material to a non-aqueous fluid to provide a logging medium,
wherein the acid-treated carbon material is present in the logging medium at a concentration to permit logging of the subterranean well;

placing the logging medium into the subterranean well; and
acquiring a log of the subterranean well.

2. The method of claim 1 , wherein the logging of the subterranean well comprises electrical logging, and wherein the electrical logging acquires an electrical log of the subterranean well.

3. The method of claim 2 , wherein the electrical log of the subterranean well is acquired by at least one of radio frequency pulses, direct current (DC) pulses, alternating current (AC) pulses, radio waves, microwaves, electromagnetic waves, and combinations thereof.

4. The method of claim 2 , wherein the electrical log of the subterranean well is acquired at electromagnetic spectra ranging from about 1 kHz to about 5 GHz.

5. The method of claim 1 , wherein the at least one acid further comprises at least one selected from the group consisting of hydrochloric acid, phosphoric acid, sulfuric acid, fuming sulfuric acid, chlorosulfonic acid, and combinations thereof.

6. The method of claim 1 , wherein the acid-treated carbon material is functionalized with one or more functionalizing agents.

7. The method of claim 6 , wherein the functionalizing agents are selected from the group consisting of phenyl groups, aniline groups, alkanes, alkyl groups, aryl groups, tent-butyl groups, alkenyl groups, alkynyl groups, ester groups, carboxyl groups, halogens, metals, metal oxides, metal sulfides, sulfate groups, nitrophenyls, and combinations thereof.

8. The method of claim 1 , wherein the acid-treated carbon material is intercalated with one or more intercalation agents.

9. The method of claim 8 , wherein the intercalation agents are selected from the group consisting of small molecules, metals, functional groups, and combinations thereof.

10. The method of claim 8 , wherein the intercalation agents comprise ammonium persulfate.

11. The method of claim 1 , wherein the acid-treated carbon material is exfoliated.

12. The method of claim 1 , wherein the acid-treated carbon material comprises from about 0.0001% to about 10% by volume of the logging medium.

13. The method of claim 1 , wherein the acid-treated carbon material comprises graphene-based carbon materials, and wherein the graphene-based carbon materials are selected from the group consisting of graphene oxide, graphene nanoribbons, graphene oxide nanoribbons, functionalized graphene nanoribbons, graphene quantum dots, and combinations thereof.

14. The method of claim 1 , wherein the acid-treated carbon material comprises graphite-based carbon materials, and wherein the graphite-based carbon materials are is selected from the group consisting of functionalized graphite, graphite oxide, graphite platelets, graphite nano-platelets, exfoliated graphite, exfoliated graphite nano-platelets, thermally expanded graphite, graphite intercalated with one or more intercalation agents to form graphite intercalation complexes, and combinations thereof.

15. The method of claim 1 , wherein the electrical conductivity of the logging medium is enhanced by at least about 10% at frequencies ranging from about 1 kHz to about 5 GHz by the acid-treated carbon materials.

16. The method of claim 1 , wherein the electrical conductivity of the logging medium is enhanced by at least about 50% at frequencies ranging from about 1 kHz to about 5 GHz by the acid-treated carbon materials.

17. The method of claim 1 , wherein the logging medium is selected from the group consisting of water-in-oil emulsions, oil-based wellbore fluids, oil-based muds, and combinations thereof.

18. The method of claim 1 , further comprising a step of dispersing the acid-treated carbon materials in the logging medium.

19. The method of claim 18 , wherein the acid-treated carbon materials are dispersed in the logging medium by adding one or more dispersing agents to the logging medium.

20. The method of claim 19 , wherein the dispersing agents are selected from the group consisting of Triton X, sodium dodecyl sulfate (SDS), sodium stearate, dodecylbenzenesulfonates, X-114, CHAPS, DOC, NP-40, cetyl trimethylammonium bromide (CTAB), tetradecyitrimethyi ammonium bromide (TTAB), cetyl trimethylammonium chloride (CTAC), cetylpyridinium chloride (CPC), benzalkonium chloride (BAC), benzethonium chloride (BZT), 5-Bromo-5-nitro-1,3-dioxane, dimethyldioctadecylammonium chloride, cetrimonium bromide, dioctadecyldimethylammonium bromide (DODAB), MUL-XT™, and combinations thereof.

21. The method of claim 1 , further comprising:
collecting logging data; and
refining drill location based on the collected logging data.

22. The method of claim 1 , further comprising:
disposing an electrical well-logging tool in the subterranean well; and
performing an electrical well-logging survey of the portion of the subterranean well using the well-logging tool.

23. A method for logging a subterranean well, wherein the method comprises:
placing a logging medium into the subterranean well,
wherein the logging medium, comprising a non-aqueous fluid and an acid-treated carbon material, is an invert micro-emulsion or an invert emulsion with a non-oleaginous phase, distributed in an oleaginous phase, having an average diameter in a range of 0.5 to 5 microns,
wherein the acid-treated carbon material is selected from the group consisting of graphene-based carbon materials, graphite-based carbon materials, and combinations thereof, and
wherein the acid-treated carbon material is present in the logging medium at a concentration to permit logging of the subterranean well; and

acquiring a log of the subterranean well.

24. The method of claim 23 , wherein the range of the average diameter is 1 to 3 microns.

Assignees

• Univ Rice William M
• Mi Llc

Inventors

• Tour James M
• Ceriotti Gabriel
• Slesarev Alexander
• Ye Ruquan
• Price-Hoelscher Katherine
• Bovet Cara
• Friedheim Jim
• Young Steve

Classifications

• G01V3/24 Primary

  using AC · CPC title

• C09K8/32 Primary

  Non-aqueous well-drilling compositions, e.g. oil-based · CPC title

• C09K2208/10

  Nanoparticle-containing well treatment fluids · CPC title

• G01V3/18

  specially adapted for well-logging · CPC title

• Y02A90/30

  Assessment of water resources · CPC title