Methods of forming ceramic matrix composites using sacrificial fibers and related products

Patent metadata

Field	Value
Publication number	US-11097983-B2
Application number	US-201916521308-A
Country	US
Kind code	B2
Filing date	Jul 24, 2019
Priority date	Jun 14, 2017
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

Methods for preparing ceramic matrix composites using melt infiltration and chemical vapor infiltration are provided as well as the resulting ceramic matrix composites. The methods and products include the incorporation of sacrificial fibers to provide improved infiltration of the fluid infiltrant. The sacrificial fibers are removed, such as decomposed during pyrolysis, resulting in the formation of regular and elongate channels throughout the ceramic matrix composite. Infiltration of the fluid infiltrant can then take place using the elongate channels resulting in improved density and an improved ceramic matrix composite product.

First claim

What is claimed is:

1. A ceramic matrix composite (CMC) product comprising:
a ceramic matrix,
a plurality of ceramic reinforcing fibers disposed throughout the ceramic matrix, and one or more infiltrant veins traversing the CMC product;
wherein the CMC product comprises a plurality of infiltrant veins, wherein the plurality of infiltrant veins are elongate bodies disposed in a grid pattern.

2. The CMC product according to claim 1 , wherein the ceramic matrix comprises one or more of silicon carbide, silicon nitride, silicon oxycarbides, silicon oxynitrides, silicides, aluminum oxide, silicon dioxide, yttrium aluminum garnet, aluminosilicates, zirconium carbide, hafnium carbide, carbon, or boron carbide, and wherein the ceramic reinforcing fibers comprise one or more of silicon carbide, silicon nitride, silicon oxycarbides, silicon oxynitrides, silicides, aluminum oxide, silicon dioxide, yttrium aluminum garnet, aluminosilicates, zirconium carbide, hafnium carbide, carbon, SiNC, SiBNC, or boron carbide.

3. The CMC product according to claim 1 , wherein the one or more infiltrant veins have an aspect ratio of about 10 to about 10,000, and wherein the one or more infiltrant veins comprise about 0.1% to about 15% by volume of the CMC product.

4. The CMC product according to claim 1 , wherein the one or more infiltrant veins comprise silicon.

5. The CMC product according to claim 1 , wherein the one or more infiltrant veins comprise a core and shell, wherein the core comprises a porous core structure.

6. The CMC product according to claim 5 , wherein the shell and the porous core structure comprise silicon carbide.

7. A ceramic matrix composite (CMC) product comprising:
a ceramic matrix,
ceramic reinforcing fibers disposed in the ceramic matrix, and
one or more infiltrant veins;
wherein the one or more infiltrant veins comprise a core and shell, wherein the core comprises a porous core structure, wherein the one or more infiltrant veins have an aspect ratio of about 10 to about 10,000.

8. The CMC product according to claim 7 , wherein the ceramic matrix comprises one or more of silicon carbide, silicon nitride, silicon oxycarbides, silicon oxynitrides, silicides, aluminum oxide, silicon dioxide, yttrium aluminum garnet, aluminosilicates, zirconium carbide, hafnium carbide, carbon, or boron carbide.

9. The CMC product according to claim 7 , wherein the ceramic reinforcing fibers comprise one or more of silicon carbide, silicon nitride, silicon oxycarbide, silicon oxynitrides, a silicide, aluminum oxide, silicon dioxide, yttrium aluminum garnet, aluminosilicates, zirconium carbide, hafnium carbide, carbon, SiNC, SiBNC, or boron carbide.

10. The CMC product according to claim 7 , wherein the one or more infiltrant veins are formed from elongate bodies disposed in a grid pattern.

11. The CMC product according to claim 7 , wherein the one or more infiltrant veins are formed from elongate bodies oriented in a parallel direction.

12. The CMC product according to claim 7 , wherein the one or more infiltrant veins comprise about 0.1% to about 15% by volume of the CMC product.

13. The CMC product according to claim 7 , wherein the shell and the porous core structure comprise silicon carbide.

14. A ceramic matrix composite (CMC) product comprising:
a ceramic matrix,
ceramic reinforcing fibers in the ceramic matrix, and
infiltrant veins having an aspect ratio of about 10 to about 10,000.

15. The CMC product according to claim 14 , wherein the ceramic matrix comprises one or more of silicon carbide, silicon nitride, silicon oxycarbides, silicon oxynitrides, silicides, aluminum oxide, silicon dioxide, yttrium aluminum garnet, aluminosilicates, zirconium carbide, hafnium carbide, carbon, or boron carbide.

16. The CMC product according to claim 14 , wherein the ceramic reinforcing fibers comprise one or more of silicon carbide, silicon nitride, silicon oxycarbides, silicon oxynitrides, silicides, aluminum oxide, silicon dioxide, yttrium aluminum garnet, aluminosilicates, zirconium carbide, hafnium carbide, carbon, SiNC, SiBNC, or boron carbide.

17. The CMC product according to claim 14 , wherein the infiltrant veins are disposed in a grid arrangement.

18. The CMC product according to claim 14 , wherein infiltrant veins are oriented parallel to each other.

19. The CMC product according to claim 14 , wherein the infiltrant veins comprise about 0.1% to about 15% by volume of the CMC product.

Assignees

• Gen Electric

Inventors

• Hall David Bruce
• Murray James Joseph
• Parolini Jason Robert
• Vallance Michael Alan
• Borja Juan
• Norton Daniel George
• Weaver Jared Hogg
• Dunn Daniel Gene

Classifications

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B2235/616

  Liquid infiltration of green bodies or pre-forms · CPC title

• C04B2235/5212

  Organic · CPC title

• C04B2235/5244

  Silicon carbide · CPC title

• C04B2235/80

  Phases present in the sintered or melt-cast ceramic products other than the main phase · CPC title