Catalyst made from an organic compound and use thereof in a hydroprocessing and/or hydrocracking method

Patent metadata

Field	Value
Publication number	US-11097258-B2
Application number	US-201716321098-A
Country	US
Kind code	B2
Filing date	Jun 22, 2017
Priority date	Jul 28, 2016
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

The invention has as its object a catalyst that comprises a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and an organic compound of formula (I)in which R1, R2, R3, R4 and R5 are selected from among a hydrogen atom, or a hydroxyl radical, or a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, and R6 is selected from a hydrogen atom, a hydrocarbon radical that comprises from 1 to 12 carbon atoms that can also comprise at least one oxygen atom, a methacryloyl radical, an acryloyl radical or an acetyl radical. The invention also relates to the method for preparation of said catalyst and its use in a method for hydrotreatment and/or hydrocracking.

First claim

The invention claimed is:

1. A catalyst, comprising a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and 2-methoxyethyl 3-oxobutanoate.

2. The catalyst according to claim 1 , in which the content of the at least one element from group VIB is between 5 and 40% by weight that is expressed in terms of metal oxide from group VIB in relation to the total weight of the catalyst, and the content of the at least one element from group VIII is between 1 and 10% by weight that is expressed in terms of metal oxide from group VIII in relation to the total weight of the catalyst.

3. The catalyst according to claim 1 , in which the molar ratio of the at least one element from group VIII to the at least one element from group VIB in the catalyst is between 0.1 and 0.8.

4. The catalyst according to claim 1 , which further contains phosphorus, with the phosphorus content being between 0.1 and 20% by weight that is expressed in terms of P 2 O 5 in relation to the total weight of the catalyst, and the ratio of phosphorus to the at least one element from group VIB in the catalyst is greater than or equal to 0.05.

5. The catalyst according to claim 1 , in which the content of 2-methoxyethyl 3-oxobutanoate is between 1 and 45% by weight in relation to the total weight of the catalyst.

6. The catalyst according to claim 1 , which further contains an organic compound other than 2-methoxyethyl 3-oxobutanoate that contains oxygen, nitrogen or sulfur, or a combination thereof.

7. The catalyst according to claim 6 , in which said organic compound is a compound that comprises one or more chemical groups selected from the group consisting of the following chemical groups: carboxylic, alcohol, thiol, thioether, sulfone, sulfoxide, ether, aldehyde, ketone, ester, carbonate, amine, nitrile, imide, oxime, urea, and amide.

8. The catalyst according to claim 7 , in which said organic compound is triethylene glycol, diethylene glycol, ethylene glycol, ethylenediaminetetraacetic acid, maleic acid, malonic acid, citric acid, dimethylformamide, N-methylpyrrolidone, propylene carbonate, bicine, or tricine.

9. The catalyst according to claim 1 , which is at least partially sulfurized.

10. A catalyst according to claim 1 , comprising a substrate based on alumina or silica or silica-alumina, at least one element from group VIII, at least one element from group VIB, and 2-methoxyethyl 3-oxobutanoate, which catalyst has not been calcined or which catalyst has not been calcined after the 2-methoxyethyl 3-oxobutanoate has been added to the catalyst.

11. A method for preparing the catalyst according to claim 1 , comprising
a) bringing into contact at least one component of an element from group VIB, at least one component of an element from group VIII, 2-methoxyethyl 3-oxobutanoate, and optionally phosphorus with a substrate based on alumina or silica or silica-alumina, or bringing into contact a regenerated catalyst that contains a substrate based on alumina or silica or silica-alumina, at least one component of an element from group VIB, at least one component of an element from group VIII, and optionally phosphorus with 2-methoxyethyl 3-oxobutanoate to obtain a catalyst precursor,
b) drying said catalyst precursor obtained from step a) at a temperature lower than 200° C., without being calcined subsequently.

12. The method according to claim 11 , in which step a) is the following step:
a′) impregnating a substrate based on alumina or silica or silica-alumina by at least one solution that contains at least one element from group VIB, at least one element from group VIII, 2-methoxyethyl 3-oxobutanoate, and optionally phosphorus to obtain a catalyst precursor.

13. The method according to claim 11 , in which step a) comprises the following steps:
a1) impregnating a substrate based on alumina or silica or silica-alumina by at least one solution that contains at least one element from group VIB, at least one element from group VIII, and optionally phosphorus to obtain an impregnated substrate,
a2) drying the impregnated substrate that is obtained in step a1) at a temperature lower than 200° C. to obtain a dried impregnated substrate, and optionally calcining the dried impregnated substrate to obtain a calcined impregnated substrate,
a3) impregnating the dried and optionally calcined impregnated substrate that is obtained in step a2) by an impregnation solution that comprises 2-methoxyethyl 3-oxobutanoate to obtain a catalyst precursor,
a4) optionally allowing to mature the catalyst precursor that is obtained in step a3).

14. The method according to claim 11 , in which step a) comprises the following steps:
a1′) preparing a substrate that comprises 2-methoxyethyl 3-oxobutanoate and optionally at least one part of phosphorus,
a2′) impregnating the substrate obtained in step a1′) by an impregnation solution that comprises at least one element from group VIB, at least one element from group VIII, and optionally phosphorus to obtain a catalyst precursor,
a3′) optionally allowing to mature the catalyst precursor that is obtained in step a2′).

15. The method according to claim 11 , in which step a) comprises the following steps:
a1″) bringing into contact a solution that contains at least one element from group VIB, at least one element from group VIII, 2-methoxyethyl 3-oxobutanoate or at least one organic compound that contains oxygen, nitrogen or sulfur or a combination thereof, which at least one organic compound is not 2-methoxyethyl 3-oxobutanoate, and optionally phosphorus by co-impregnation with a substrate based on alumina or silica or silica-alumina to obtain an impregnated substrate,
a2″) drying the impregnated substrate obtained from step a1″) at a temperature that is lower than 200° C., without being calcined subsequently, to obtain a dried impregnated substrate,
a3″) bringing into contact the dried impregnated substrate obtained from
step a2″) with a solution of 2-methoxyethyl 3-oxobutanoate or at least one organic compound that contains oxygen, nitrogen or sulfur or a combination thereof, which at least one organic compound is not 2-methoxyethyl 3-oxobutanoate, and which is identical to or different from said at least one organic compound in step a1″) to obtain a catalyst precursor,
a4″) optionally allowing to mature the catalyst precursor that is obtained in step a3″),
and 2-methoxyethyl 3-oxobutanoate is present in at least one of step a1″) or step a3″).

16. The method according to claim 11 , in which step a) comprises the following steps:
a1′″) impregnating a regenerated catalyst that contains a substrate based on alumina or silica or silica-alumina, at least one component of an element from group VIB, at least one component of an element from group VIII, and optionally phosphorus by an impregnation solution that comprises 2-methoxyethyl 3-oxobutanoate to obtain a catalyst precursor,
a2′″) optionally allowing to mature the catalyst precursor that is obtained in step a1′″).

17. The method according to claim 11 , in which the molar ratio of 2-methoxyethyl 3-oxobutanoate to the at least one element from group VIII is between 0.1 and 5.0 mol/mol.

18. A method for at least one of hydrotreating and hydrocracking a hydrocarbon fraction, comprising performing said at least one of hydrotreating and hydrocracking in the presence of the catalyst according to claim 1 .

19. A method for at least one of hydrotreating and hydrocracking a hydrocarbon fraction, comprising performing said at least o

Assignees

• Ifp Energies Now

Inventors

• Carrette Pierre-Louis

Classifications

• C10G47/10

  with catalysts deposited on a carrier · CPC title

• B01J27/28

  Regeneration or reactivation · CPC title

• B01J38/62

  organic · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J27/0515

  with iron group metals or platinum group metals · CPC title