Separation method, and production method for (meth)acrylate

Patent metadata

Field	Value
Publication number	US-11097209-B2
Application number	US-202016820933-A
Country	US
Kind code	B2
Filing date	Mar 17, 2020
Priority date	Sep 29, 2017
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

An object of the present invention is to provide a separation method capable of efficiently separating a light liquid and a heavy liquid from a mixed liquid containing the light liquid, the heavy liquid, and an emulsion liquid of the light liquid and the heavy liquid, such as an emulsion-layer extraction liquid in a vicinity of an interface in an extraction column. The present invention relates to a separation method for continuously separating a light liquid and a heavy liquid having a specific gravity larger than that of the light liquid from a mixed liquid containing the light liquid, the heavy liquid, and an emulsion liquid of the light liquid and the heavy liquid by introducing the mixed liquid into a separation tank, in which a specific separation layer is used for the separation tank.

First claim

The invention claimed is:

1. A separation method, for continuously separating a light liquid and a heavy liquid having a specific gravity larger than that of the light liquid from a mixed liquid containing the light liquid, the heavy liquid, and an emulsion liquid of the light liquid and the heavy liquid by continuously introducing the mixed liquid into a separation tank,
wherein the separation tank comprises:
a tank body;
a chamber A into which the mixed liquid is introduced and in which an interface between the light liquid and the heavy liquid is formed, a chamber B separated from the chamber A by an overflow part, and a chamber C separated from the chamber A by an erected wall erected from a bottom surface of the tank body, wherein an upper end of the erected wall partitioning the chamber A and the chamber C is positioned higher than the overflow part;
a liquid transfer pipe having one end opened at a bottom part of the chamber A and having the other end opened in the chamber C; and
an extraction part for an emulsion liquid configured to extract the emulsion liquid from a middle of the chamber A, the middle of the chamber A being defined in a vertical direction,
wherein when a height from a bottom part of the tank body to the overflow part is defined as h 1 ,
a height from the bottom part of the tank body to an opening of the liquid transfer pipe in the chamber C is defined as h 2 ,
a height from the bottom part of the tank body to the interface in the chamber A is defined as h 1 ·α, and
a ratio P H /P L of specific gravity P H of the heavy liquid to specific gravity P L of the light liquid is defined as X,
a relationship of α=(h 2 ×X−h 1 )/h 1 (X−1) is established, where a is in a range of 0.2-0.7,
wherein the separation tank includes a detection part configured to confirm presence or absence of the emulsion liquid by detecting the height from the bottom part of the tank body to the interface in the chamber A,
wherein the separation tank includes outflow parts configured to allow liquids to flow out from the chamber B and the chamber C respectively so as to keep liquid levels in the chambers within a predetermined range, and
wherein the mixed liquid contains the light liquid, the heavy liquid having the specific gravity larger than that of the light liquid, and an emulsion liquid of the light liquid and the heavy liquid, which are extracted from a vicinity of an interface in an extraction column,
the separation method further comprising the steps of:
introducing the mixed liquid into the chamber A, which forms the interface between the light liquid and the heavy liquid, overflowing the light liquid into the chamber B by the overflow part, and flowing the heavy liquid from the bottom part of the chamber A into the chamber C via the liquid transfer pipe,
detecting the height of the emulsion liquid in the chamber A by the detection part, and
extracting the emulsion liquid from the middle of the chamber A by the extraction part.

2. The separation method according to claim 1 , wherein the detection part is a sight-through part for viewing the inside of the tank body, which is provided in the tank body.

3. The separation method according to claim 1 , wherein the separation tank includes an illumination part configured to illuminate the inside of the tank body.

4. The separation method according to claim 1 ,
wherein at least one of the chamber B and the chamber C of the separation tank is constituted of one chamber or a plurality of chambers,
when at least one of the chamber B and the chamber C of the separation tank is constituted of a plurality of chambers, the respective chambers are partitioned by an erected wall erected from the bottom surface of the tank body, and are connected in series by an overflow part or a connection pipe provided on the erected wall.

5. The separation method according to claim 1 , wherein the tank body is a horizontal cylindrical container or a vertical cylindrical container.

6. The separation method according to claim 1 , wherein the separation tank includes at least one of a heat-retaining part configured to retain heat of the tank body and a heating part configured to heat the mixed liquid to be supplied to the tank body.

7. The separation method according to claim 1 , wherein the heavy liquid is introduced into the chamber A in advance of a start of operation of the separation tank.

8. The separation method according to claim 1 , wherein the light liquid comprises (meth)acrylate, and the heavy liquid comprises water.

9. A production method for (meth)acrylate, comprising:
reacting (meth)acrylic acid, alcohol, and an acid catalyst in a reactive distillation part including a reactor and a distillation column to obtain a crude (meth)acrylate from the reactor;
recovering the acid catalyst contained in the crude (meth)acrylate, followed by circulating the recovered acid catalyst to the reactive distillation part;
washing the crude (meth)acrylate from which the acid catalyst has been recovered in a neutralization washing column to produce a washed crude (meth)acrylate and a mixed liquid comprising (meth)acrylate;
separating a low-boiling-point compound from the washed crude (meth)acrylate by a second distillation column to obtain a liquid at a bottom of the second distillation column;
purifying the liquid obtained from the bottom of the second distillation column to obtain purified (meth)acrylate, and
separating the mixed liquid by the separation method according to claim 1 to obtain additional purified (meth)acrylate.

Assignees

• Mitsubishi Chem Corp

Inventors

• Ogawa Yasushi
• Katou Masakazu
• Hasegawa Yukihiro

Classifications

• C07C69/54

  Acrylic acid esters; Methacrylic acid esters · CPC title

• B01D17/00

  Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion (devices for separating or removing fatty or oily substances or similar floating material from water, waste water, or sewage C02F1/40; cleaning or keeping clear the surface of open water from oil or like materials E02B15/04; arrangements for separating lubricants from refrigerants F25B43/02) · CPC title

• B01D17/12

  Auxiliary equipment particularly adapted for use with liquid-separating apparatus, e.g. control circuits · CPC title

• C07C67/52

  by change in the physical state, e.g. crystallisation · CPC title

• B01D17/0208 Primary

  by sedimentation · CPC title