Energy recovery in a method for preparing 1,3,5-trioxane

Patent metadata

Field	Value
Publication number	US-11097202-B2
Application number	US-201616062752-A
Country	US
Kind code	B2
Filing date	Dec 7, 2016
Priority date	Dec 18, 2015
Publication date	Aug 24, 2021
Grant date	Aug 24, 2021

Abstract

The present invention relates to a process for energy recovery in a process for the preparation of 1,3,5-trioxane.

First claim

The invention claimed is:

1. A process for energy recovery in a process for the preparation of 1,3,5-trioxane comprising the steps
a) reacting formaldehyde in the presence of water and at least one acidic catalyst in a first reactor to obtain a first product mixture, which comprises water and 1,3,5-trioxane, wherein the first product mixture is transferred as a first stream from the first reactor to a distillation tower,
b) contacting the first product mixture with at least one extractant in the distillation tower to obtain an overhead product, and a side cut, wherein the overhead product comprises the at least one extractant and water, and wherein the side cut comprises the at least one extractant and 1,3,5-trioxane, wherein the overhead product is transferred as a second stream from the distillation tower to a mechanical compressor, wherein the second stream has a first temperature and a first pressure,
c) mechanical compression of the second stream in the mechanical compressor to obtain a compressed stream, which has a second temperature and a second pressure, wherein the second temperature of the compressed stream is higher than the first temperature of the second stream and wherein the second pressure of the compressed stream is higher than the first pressure of the second stream,
d) transferring heat from the compressed stream to the first reactor.

2. The process according to claim 1 , wherein step d) comprises the following steps
d1) transferring the compressed stream from the mechanical compressor to a first heat exchanger in which heat is transferred from the compressed stream to a condensate in order to obtain a heated condensate,
d2) transferring heat from the heated condensate to the first reactor.

3. The process according to claim 2 , wherein step d2) comprises the following steps
d2-i) transferring the heated condensate as a fourth stream to a second heat exchanger, in which heat is transferred from the fourth stream to a mixture in order to obtain a heated mixture, wherein the mixture comprises formaldehyde and water,
d2-ii) transferring heat from the heated mixture to the first reactor.

4. The process according to claim 3 , wherein the mixture in step d2-i) is transferred as a stream 5 a from the first reactor to the second heat exchanger.

5. The process according to claim 3 , wherein in step d2-ii) the heated mixture is transferred as a stream 5 b from the second heat exchanger to the first reactor.

6. The process according to claim 1 , wherein the at least one extractant in step b) is selected from the group consisting of benzene, 1,2-dichloroethane and methylene chloride.

7. The process according to claim 1 , wherein the first stream in step a) comprises from 31 to 56% by weight of formaldehyde, from 8 to 32% by weight of 1,3,5-trioxane, from 11 to 35% by weight of water and from 1 to 25% by weight of byproducts, based on the total weight of the first stream.

8. The process according to claim 1 , wherein the first temperature of the second stream is in the range from 49 to 92° C.

9. The process according to claim 1 , wherein the first pressure of the second stream is in the range from 0.05 to 2 bara.

10. The process according to claim 1 , wherein the second temperature of the compressed stream is in the range from 161 to 205° C.

11. The process according to claim 1 , wherein the second pressure of the compressed stream is in the range from 4 to 14 bara.

12. The process according to claim 1 , wherein the second stream comprises from 80 to 94% by weight of the at least one extractant, from 4.5 to 12.5% by weight of water, from 0.7 to 3.2% by weight of byproducts, from 0.6 to 2.6% by weight of formaldehyde and from 0.01 to 1% by weight of 1,3,5-trioxane, based on the total weight of the second stream.

13. The process according to claim 2 , wherein the condensate in step d1) comprises water.

14. The process according to claim 3 , wherein the fourth stream has a temperature in the range from 120 to 170° C.

15. The process according to claim 5 , wherein the stream 5 b has a temperature in the range from 82 to 140° C.

Assignees

• Basf Se
• Kolon Plastics Inc

Inventors

• Stammer Achim
• Heitz Thomas
• Kramp Marvin
• Kim Jongmoon
• Cho In-Gi
• Choi Jin-Sang
• Lee Sang-Yup

Classifications

• B01D3/40

  Extractive distillation · CPC title

• B01D3/009

  in combination with chemical reactions · CPC title

• Y02P70/10

  Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working · CPC title

• B01D3/007 Primary

  Energy recuperation; Heat pumps · CPC title

• C07D323/06 Primary

  Trioxane · CPC title