Non-aqueous electrolytic solution for lithium ion secondary cell

Patent metadata

Field	Value
Publication number	US-11094965-B2
Application number	US-201916572919-A
Country	US
Kind code	B2
Filing date	Sep 17, 2019
Priority date	Sep 19, 2018
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

Provided is a non-aqueous electrolytic solution for a lithium ion secondary cell that can reduce the initial resistance of the lithium ion secondary cell and can suppress the increase in resistance when the lithium ion secondary cell is allowed to stand at high temperature. The non-aqueous electrolytic solution for a lithium ion secondary cell disclosed herein includes a light metal salt represented by the following formula (I) and a silyl sulfate compound represented by the following formula (II). The content of the light metal salt in the non-aqueous electrolytic solution for a lithium ion secondary cell is 0.1% by mass or more and 1.5% by mass or less. The content of the silyl sulfate compound in the non-aqueous electrolytic solution for a lithium ion secondary cell is 0.1% by mass or more and 5.0% by mass or less (each symbol in the formulas is as defined in the specification).

First claim

What is claimed is:

1. A non-aqueous electrolytic solution for a lithium ion secondary cell, comprising:
a light metal salt represented by the following formula (I); and
a silyl sulfate compound selected from bis[dimethyl(2-methoxyethyl)silyl] sulfate, wherein
a content of the light metal salt in the non-aqueous electrolytic solution for a lithium ion secondary cell is 0.1% by mass or more and 1.5% by mass or less, and
a content of the silyl sulfate compound in the non-aqueous electrolytic solution for a lithium ion secondary cell is 0.1% by mass or more and 5.0% by mass or less,

wherein R11 represents a —C(═O)—R—C(═O)— group (R represents an alkylene group, a halogenated alkylene group, an arylene group, or a halogenated arylene group), or a —C(═O)—C(=O)—group; R12 represents a halogen atom, an alkyl group, a halogenated alkyl group, an aryl group or a halogenated aryl group; X11 and X12 independently represent an oxygen atom or a sulfur atom; M11 represents a transition metal element or a Group 13 element, a Group 14 element or a Group 15 element in the periodic table; M12 represents a Group 1 element, a Group 2 element in the periodic table, or an aluminum element; a is an integer of 1 to 4; b is an integer of 0 to 8; c is an integer of 1 to 3; d is an integer of 1 to 3; e is an integer of 1 to 3; and f is an integer of 1 to 3.

2. The non-aqueous electrolytic solution for a lithium ion secondary cell according to claim 1 , wherein the light metal salt is at least one oxalate complex selected from the group consisting of lithium bis(oxalato)borate, lithium difluoro(oxalato)borate, lithium difluorobis(oxalato)phosphate, and lithium tetrafluoro(oxalato)phosphate.

3. The non-aqueous electrolytic solution for a lithium ion secondary cell according to claim 1 , wherein the non-aqueous electrolytic solution does not include bis(triethyl silyl)sulfate.

4. A lithium ion secondary cell comprising the non-aqueous electrolytic solution for a lithium ion secondary cell according to claim 1 .

5. A lithium ion secondary cell comprising the non-aqueous electrolytic solution for a lithium ion secondary cell according to claim 2 .

Assignees

• Toyota Motor Co Ltd

Inventors

• Asano Hiroto
• Kondo Shimpei
• Kohyama Akira

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title