Protective film for lithium electrode, and lithium electrode and lithium secondary battery comprising same
US-2018294513-A1 · Oct 11, 2018 · US
US11094963B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11094963-B2 |
| Application number | US-201916700794-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 2, 2019 |
| Priority date | Mar 14, 2013 |
| Publication date | Aug 17, 2021 |
| Grant date | Aug 17, 2021 |
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A solid electrolyte represented by general formula Li y SiR x (MO 4 ), where x is an integer from 1 to 3 inclusive, y=4−x, each R present is independently C1-C3 alkyl or C1-C3 alkoxy, and M is sulfur, selenium, or tellurium. Methods of making the solid electrolyte include combining a phenylsilane and a first acid to yield mixture including benzene and a second acid, and combining at least one of an alkali halide, and alkali amide, and an alkali alkoxide with the second acid to yield a product d represented by general formula Li y SiR x (MO 4 ) y . The second acid may be in the form of a liquid or a solid. The phenylsilane includes at least one C1-C3 alkyl substituent or at least one C1-C3 alkoxy substituent, and the first acid includes at least one of sulfuric acid, selenic acid, and telluric acid.
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What is claimed is: 1. A solid electrolyte represented by general formula Li y SiR x (MO 4 ) y , wherein: x is an integer from 1 to 3 inclusive, y=4−x, each R present is independently a halogen atom, a cyano group, or an acetate group, and M is sulfur or selenium.
Hydroxides · CPC title
the electrolyte being constituted of organic materials only · CPC title
Energy storage using batteries · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
Polymeric materials, e.g. gel-type or solid-type · CPC title
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