Yarn with coating over yarn core

Patent metadata

Field	Value
Publication number	US-11091874-B2
Application number	US-201816203708-A
Country	US
Kind code	B2
Filing date	Nov 29, 2018
Priority date	Nov 29, 2018
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

A coated yarn has a yarn core and a coating disposed coaxially on the yarn core. This coating contains: (i) porous particles present in an amount of at least 4 weight % and up to and including 20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, having a mode particle size of 2-50 μm and up to and including 50 μm; (ii) a film-forming binder material having a T g of less than or equal to 25° C., which is present in an amount of 40-90 weight %; and (iii) an inorganic filler material having a value of less than 5 on the MOHS scale of mineral hardness, which inorganic filler material is present in an amount of 4 weight % and up to and including 30 weight %.

First claim

The invention claimed is:

1. A coated yarn comprising a yarn core; and a coating disposed coaxially on the yarn core, which coating comprises:
(i) porous particles present in an amount of at least 4 weight % and up to and including 20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, the porous particles having a mode particle size of at least 2 μm and up to and including 50 μm;
(ii) a film-forming binder material having a T g of less than or equal to 25° C., which film-forming binder material is present in an amount of at least 40 weight % and up to and including 90 weight %; and
(iii) an inorganic filler material having a value of less than 5 on the MOHS scale of mineral hardness, which inorganic filler material is present in an amount of at least 4 weight % and up to and including 30 weight %,
wherein the amounts of the (i) porous particles, the (ii) film-forming binder material, and the (iii) inorganic filler material are based on the total weight of the coating.

2. The coated yarn of claim 1 , wherein the coating consists essentially of the (i) porous particles, the (ii) film-forming binder material, and the (iii) inorganic filler material.

3. The coated yarn of claim 1 , wherein the yarn core is a mono- or multifilament core that is composed of multiple glass or polyester filaments.

4. The coated yarn of claim 1 , wherein the coating is disposed coaxially and directly on the yarn core.

5. The coated yarn of claim 1 , comprising at least one intermediate coating disposed coaxially between the yarn core and the coating.

6. The coated yarn of claim 5 , wherein the at least one intermediate coating comprises at least one flame-retarding polymer.

7. The coated yarn of claim 1 , wherein the coating is disposed coaxially and directly on the yarn core, and the coated yarn further comprises an outer coating disposed coaxially on the coating.

8. The coated yarn of claim 7 , wherein the outer coating comprises at least one flame-retarding polymer.

9. The coated yarn of claim 1 , wherein the weight ratio of the (ii) film-forming binder material to the (i) porous particles in the coating is at least 2:1 to and including 25:1.

10. The coated yarn of claim 1 , wherein the weight ratio of the (ii) film-forming binder material to the (iii) inorganic filler material in the coating is at least 1.5:1 to and including 25:1.

11. The coated yarn of claim 1 , wherein the weight ratio of the (i) porous particles to the (iii) inorganic filler material in the coating is at least 0.1:1 to and including 5:1.

12. The coated yarn of claim 1 , wherein the (i) porous particles are present in the coating at a coverage of at least 4 g/m 2 .

13. The coated yarn of claim 1 , wherein the (iii) inorganic filler material is a non-abrasive, whitening inorganic filler material.

14. The coated yarn of claim 1 , wherein the (iii) inorganic filler material comprises barium sulfate, calcium carbonate, mica, fluorite, clay, gypsum, or zinc sulfide.

15. The coated yarn of claim 1 , wherein the (iii) inorganic filler material comprises zinc sulfide.

16. The coated yarn of claim 1 , wherein the (i) porous particles have a mode particle size of at least 3 μm and up to and including 30 μm, a porosity of at least 35 volume % and up to and including 65 volume %, and have a continuous polymeric phase composed of one or more of a polyester, a vinyl copolymer, and a cellulosic polymer.

17. The coated yarn of claim 1 , wherein the (ii) film-forming binder material comprises one or more acrylic polymers.

18. The coated yarn of claim 1 , wherein the (ii) film-forming binder material comprises a copolymer derived from vinyl chloride and one or more non-halogenated acrylic monomers.

19. The coated yarn of claim 1 , wherein the coating further comprises one or more of the following optional materials that are different from all of (i), (ii), and (iii): thickening agent, flame retardant, UV radiation stabilizer, tinting agent, dispersant, biocide, heat stabilizer, lubricant, and moisture or deflection control agent.

20. The coated yarn of claim 1 , wherein the coating contains no carbon black.

21. A coated yarn comprising a multifilament fiberglass core; and an aqueous-based coating disposed coaxially on the multifilament fiberglass core, which aqueous-based coating comprises:
(i) porous particles present in an amount of at least 4 weight % and up to and including 20 weight %, each porous particle comprising a continuous polymeric phase and discrete pores dispersed within the continuous polymeric phase, the porous particles having a mode particle size of at least 3 μm and up to and including 30 μm;
(ii) a film-forming binder material having a T g of less than or equal to 0° C., which film-forming binder material is present in an amount of at least 40 weight % and up to and including 90 weight %; and
(iii) a non-abrasive, whitening inorganic filler material having a value of less than 5 on the MOHS scale of mineral hardness, which non-abrasive, whitening inorganic filler material comprises zinc sulfide and is present in an amount of at least 4 weight % and up to and including 30 weight %,
wherein the amounts of the (i) porous particles, the (ii) film-forming binder material, and the (iii) non-abrasive, whitening inorganic filler material are based on the total weight of the aqueous-based coating, and
the (i) porous particles are present in the aqueous-based coating at a coverage of at least 4 g/m 2 .

Assignees

• Eastman Kodak Co

Inventors

• Nair Mridula
• Brick Mary Christine
• Sedita Joseph Salvatore

Classifications

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title

• D06M2200/40

  Reduced friction resistance, lubricant properties; Sizing compositions · CPC title

• C09D5/18

  Fireproof paints {including high temperature resistant paints} · CPC title

• C09D127/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• D06M2200/30

  Flame or heat resistance, fire retardancy properties · CPC title