Ink composition, ink set, image forming method, and printed matter

Patent metadata

Field	Value
Publication number	US-11091662-B2
Application number	US-201816111417-A
Country	US
Kind code	B2
Filing date	Aug 24, 2018
Priority date	Feb 29, 2016
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

Provided is an ink composition used for image formation by an ink jet method. The ink composition includes plate-like metal particles that include a metal element having a standard oxidation-reduction potential nobler than −1.65 V, that have an average equivalent circle diameter of 10 nm or more and less than 500 nm, and that have an average aspect ratio, which is the ratio of the average equivalent circle diameter to an average thickness, of 3 or more. Also provided are an ink set, an image forming method, and a printed matter.

First claim

What is claimed is:

1. An ink composition used for image formation by an ink jet method,
the ink composition comprising plate-like metal particles that include a metal element having a standard oxidation-reduction potential nobler than −1.65 V, that have an average equivalent circle diameter of 10 nm or more and less than 500 nm, and that have an average aspect ratio, which is a ratio of the average equivalent circle diameter to an average thickness, of 8 or more.

2. The ink composition according to claim 1 , wherein the metal element having a standard oxidation-reduction potential nobler than −1.65 V is at least one metal element selected from the group consisting of gold, silver, and platinum.

3. The ink composition according to claim 1 , wherein the plate-like metal particles include silver in an amount of 80% by mass or more relative to the total amount of the plate-like metal particles.

4. The ink composition according to claim 1 , wherein a content of the plate-like metal particles is 3% to 8% by mass relative to the total amount of the ink composition.

5. The ink composition according to claim 1 , comprising water.

6. The ink composition according to claim 5 , comprising gelatin.

7. The ink composition according to claim 6 , wherein a ratio of a mass content of the plate-like metal particles to a mass content of the gelatin is 1 to 100.

8. The ink composition according to claim 1 , comprising an organic solvent.

9. The ink composition according to claim 1 , comprising at least one surfactant selected from the group consisting of fluorosurfactants and acetylene glycol surfactants.

10. The ink composition according to claim 1 , wherein the ink composition is used for decorative printing by an ink jet method.

11. An ink set comprising:
a first ink that is the ink composition according to claim 1 ; and
a second ink that is different from the first ink, the second ink containing a coloring agent.

12. An image forming method comprising an ink application step of applying the ink composition according to claim 1 to a substrate by an ink jet method.

13. The image forming method according to claim 12 , wherein in the ink application step, the ink composition is applied to the substrate by ejecting the ink composition through a nozzle of an ink jet head, the nozzle having a nozzle diameter of less than 25 μm.

14. An image forming method that uses the ink set according to claim 11 , the method comprising:
a first ink application step of applying the first ink to a substrate by an ink jet method; and
a second ink application step of applying the second ink to the substrate by the ink jet method.

15. A printed matter comprising:
a substrate; and
an image disposed on the substrate, the image containing plate-like metal particles that include a metal element having a standard oxidation-reduction potential nobler than −1.65 V, that have an average equivalent circle diameter of 10 nm or more and less than 500 nm, and that have an average aspect ratio, which is a ratio of the average equivalent circle diameter to an average thickness, of 8 or more.

16. The printed matter according to claim 15 , further comprising a color image containing a coloring agent, the color image being disposed on the image containing the plate-like metal particles and/or between the substrate and the image containing the plate-like metal particles.

Assignees

• Fujifilm Corp

Inventors

• Watanabe Kosuke
• HONGO Yushi
• Masui Kensuke
• Kiyoto Naoharu
• Makuta Toshiyuki
• Hamada Kazuhiro

Classifications

• C09D11/40

  Ink-sets specially adapted for multi-colour inkjet printing · CPC title

• B41M5/00

  Duplicating or marking methods; Sheet materials for use therein (by using light-sensitive materials G03; electrography, magnetography G03G {; repeatedly usable boards or tablets for writing or drawing B43L1/00}) · CPC title

• C09D11/322

  Pigment inks · CPC title

• C08K2201/016

  Additives defined by their aspect ratio · CPC title

• C09D11/52

  Electrically conductive inks · CPC title