Process for producing an in-situ foam

Patent metadata

Field	Value
Publication number	US-11091601-B2
Application number	US-201815888525-A
Country	US
Kind code	B2
Filing date	Feb 5, 2018
Priority date	Sep 24, 2012
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

A system for producing an in-situ foam, which comprises the components
from 50 to 98% by weight of one or more inorganic fillers A), from 1 to 48% by weight of one or more water-soluble, cationic polymers B), from 0.5 to 48% by weight of one or more surfactants C), from 0.01 to 5% by weight of one or more crosslinkers D) which are capable of reacting with the polymers B), from 0 to 20% by weight of one or more additives E),

where the percentages by weight of the components A) to E) are based on the nonaqueous fraction and the sum of A) to E) is 100% by weight, process for producing an in-situ foam using the components of the system and foaming by means of a gas or a gas mixture and use for thermal insulation and filling of hollow spaces and hollow bodies.

First claim

The invention claimed is:

1. A process for producing an in-situ foam, the process comprising providing a system, the system comprising the following components:
from 50 to 98% by weight of one or more inorganic fillers as component A,
from 1 to 48% by weight of one or more water-soluble, cationic polymers as component B,
from 0.5 to 48% by weight of one or more surfactants as component C,
from 0.01 to 5% by weight of one or more crosslinkers as component D, which are capable of reacting with the cationic polymers,
from 0 to 20% by weight of one or more additives as component E,
where the percentages by weight of the components A to E are based on the nonaqueous fraction and the sum of components A to E is 100% by weight and
introducing a gas, or a gas mixture to the system components to produce the in-situ foam;
wherein the providing of the system components comprises preparing an aqueous suspension having a solids content in the range from 30 to 50% by weight prepared from the components A to D, and introducing compressed air having a pressure in the range from 100 to 2000 kPa in to the aqueous suspension.

2. The process according to claim 1 , wherein the one or more cationic polymers includes polyvinylamine or a poly(vinylamine-vinylformamide) copolymer.

3. The process according to claim 1 , wherein the one or more surfactants includes a mixture of anionic and nonionic surfactants.

4. The process according to claim 1 , wherein the one or more crosslinkers includes a dialdehyde crosslinker.

5. The process according to claim 1 , wherein the one or more inorganic fillers are selected from calcium sulfate, aluminum silicates, or mixtures thereof.

6. A process for producing an in-situ foam, the process comprising providing a system, the system comprising the following components:
from 50 to 98% by weight of one or more inorganic fillers as component A,
from 1 to 48% by weight of one or more water-soluble, cationic polymers as component B,
from 0.5 to 48% by weight of one or more surfactants as component C,
from 0.01 to 5% by weight of one or more crosslinkers as component D, which are capable of reacting with the cationic polymers,
from 0 to 20% by weight of one or more additives as component E,
where the percentages by weight of the components A to E are based on the nonaqueous fraction and the sum of components A to E is 100% by weight and
introducing a gas, or a gas mixture to the system components to produce the in-situ foam;
wherein the introducing of the gas, or the gas mixture, comprises the introduction into an aqueous solution or suspension comprising at least the one or more components C, followed by
adding components A, B and D, and optionally the component E, either together or separately, with one or more mixing elements to the aqueous solution or suspension,
foaming the aqueous solution or suspension comprising at least the components A to D, and
drying to a water content below 0.5% by weight.

7. The process according to claim 6 , wherein the introducing of the gas or gas mixture is the introduction of compressed air having a pressure in the range from 100 to 2000 kPa, and the aqueous solution or suspension has a solids content in the range from 30 to 50% by weight.

8. A process for producing an in-situ foam, the process comprising providing a system, the system comprising the following components:
from 50 to 98% by weight of one or more inorganic fillers as component A,
from 1 to 48% by weight of one or more water-soluble, cationic polymers as component B,
from 0.5 to 48% by weight of one or more surfactants as component C,
from 0.01 to 5% by weight of one or more crosslinkers as component D, which are capable of reacting with the cationic polymers,
from 0 to 20% by weight of one or more additives as component E,
where the percentages by weight of the components A to E are based on the nonaqueous fraction and the sum of components A to E is 100% by weight and
introducing a gas, or a gas mixture to the system components to produce the in-situ foam;
wherein the introducing of the gas, or the gas mixture, comprises the introduction into an aqueous solution or suspension comprising at least the one or more components C, followed by
adding the components A and B, and optionally the component E, either together or separately, with one or more mixing elements to the aqueous solution or suspension,
foaming the aqueous solution or suspension comprising at least the components A to C, and optionally the component E,
adding the component D, and
drying to a water content below 0.5% by weight.

9. The process according to claim 8 , wherein the introducing of the gas or gas mixture is the introduction of compressed air having a pressure in the range from 100 to 2000 kPa, and the aqueous solution or suspension has a solids content in the range from 30 to 50% by weight.

10. The process according to claim 1 , wherein the in-situ foam is firm in air at 20° C. within a period in the range from 5 to 50 seconds after foaming.

11. The process according to claim 1 , wherein the in-situ foam has a density in the range from 10 to 300 kg/m 3 .

12. The process according to claim 1 , wherein the in-situ foam has a heat of combustion of less than 3.0 MJ/kg.

13. The process according to claim 6 , wherein the in-situ foam is firm in air at 20° C. within a period in the range from 5 to 50 seconds after foaming.

14. The process according to claim 8 , wherein the in-situ foam is firm in air at 20° C. within a period in the range from 5 to 50 seconds after foaming.

15. The process according to claim 6 , wherein the in-situ foam has a density in the range from 10 to 300 kg/m 3 .

16. The process according to claim 8 , wherein the in-situ foam has a density in the range from 10 to 300 kg/m 3 .

17. The process according to claim 6 , wherein the in-situ foam has a heat of combustion of less than 3.0 MJ/kg.

18. The process according to claim 8 , wherein the in-situ foam has a heat of combustion of less than 3.0 MJ/kg.

19. The process according to claim 6 , wherein the one or more cationic polymers includes polyvinylamine or a poly(vinylamine-vinylformamide) copolymer.

20. The process according to claim 6 , wherein the one or more inorganic fillers are selected from calcium sulfate, aluminum silicates, or mixtures thereof.

Assignees

• Basf Se

Inventors

• Simancas Kimberly
• Von Benten Rebekka
• Hähnle Hans-Joachim
• Hahn Klaus
• Nestle Nikolaus
• Ulanova Tatiana
• Assmann Jens

Classifications

• C04B38/10 Primary

  by using foaming agents (C04B38/02 takes precedence){or by using mechanical means, e.g. adding preformed foam} · CPC title

• C08J9/30 Primary

  by mixing gases into liquid compositions or plastisols, e.g. frothing with air · CPC title

• C04B38/00

  Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof (treating slag with gases or gas generating material C04B5/06 {; expanded graphite C04B35/536}) · CPC title

• C08J2339/02

  Homopolymers or copolymers of vinylamine · CPC title

• C04B2103/40

  Surface-active agents, dispersants · CPC title