Method for producing methacrylate copolymer solution

Patent metadata

Field	Value
Publication number	US-11091575-B2
Application number	US-201716464540-A
Country	US
Kind code	B2
Filing date	Nov 29, 2017
Priority date	Nov 30, 2016
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

A method for producing a polymer solution including a methacrylate copolymer having a weight average molecular weight of not less than 100,000, a weight average molecular weight/number average molecular weight of 1.01 to 1.8 and a glass transition temperature of not more than 40° C. and including methyl methacrylate units and alkyl (meth)acrylate units containing a C10-36 alkyl group, and a first solvent having a boiling point of not less than 200° C., through steps including a step (I) of preparing the methacrylate copolymer by polymerizing monomers in a second solvent having a boiling point of below 200° C., and a step (II) of mixing the solution from the step (I) which includes the methacrylate copolymer and the second solvent, with the first solvent, and removing the second solvent to raise the content of the first solvent to not less than 10 mass % of the polymer solution.

First claim

The invention claimed is:

1. A method for producing a polymer solution comprising a methacrylate copolymer and a first solvent, the method comprising:
preparing the methacrylate copolymer by polymerizing monomers in a second solvent, thereby producing a solution comprising the methacrylate copolymer and the second solvent; and
mixing the solution with the first solvent, and
removing the second solvent to raise a content of the first solvent to not less than 10 mass % of the polymer solution,
wherein the methacrylate copolymer has a weight average molecular weight of not less than 100,000, a weight average molecular weight/number average molecular weight of 1.01 to 1.8 and a glass transition temperature of not more than 40° C. and comprises methyl methacrylate units and alkyl (meth)acrylate units containing a C10-36 alkyl group;
the first solvent has a boiling point of not less than 200° C.; and
the second solvent has a boiling point of below 200° C.

2. The method according to claim 1 , wherein the second solvent is an aromatic hydrocarbon.

3. The method according to claim 1 , wherein the first solvent is a mineral oil.

4. The method according to claim 1 , wherein the methacrylate copolymer comprises 5 to 90 mass % of methyl methacrylate units and 95 to 10 mass % of alkyl (meth)acrylate units containing a C10-36 linear alkyl group.

5. The method according to claim 1 , wherein the polymer solution has a viscosity at 200° C. of not more than 40,000 cps.

6. A method for producing a lubricant composition, comprising:
adding an additive to a polymer solution obtained by the method of claim 1 to form a lubricant composition.

7. The method for producing a lubricant composition according to claim 6 , wherein the additive is selected from a cleaning agent, dispersant, oiliness improver, antioxidant, thermal deterioration inhibitor, light stabilizer, UV absorber, lubricating agent, release agent, polymeric processing aid, antistatic agent, flame retardant, dye, pigment, light diffusing agent, organic colorant, matting agent, impact modifier, fluorescent material, antiwear agent, corrosion inhibitor, rust inhibitor, pour point depressant, demulsifier, metal deactivator, antifoaming agent, or ashless friction modifier.

Assignees

• Kuraray Co

Inventors

• Takahashi Toru
• Okabe Fumihiko
• Nakahara Atsuhiro

Classifications

• C08F6/20 Primary

  Concentration · CPC title

• C08F220/14 Primary

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F220/1812

  C12-(meth)acrylate, e.g. lauryl (meth)acrylate · CPC title

• C08F220/1818

  C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate · CPC title

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title