Hybrid supported catalyst

Patent metadata

Field	Value
Publication number	US-11091571-B2
Application number	US-201716084066-A
Country	US
Kind code	B2
Filing date	Aug 18, 2017
Priority date	Dec 5, 2016
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

The present invention provides a hybrid supported catalyst capable of easily preparing an olefin polymer capable of having improved melt strength even while having appropriate molecular weight distribution, and thus having improved bubble stability and exhibiting excellent blown film processability, and a method for preparing an olefin polymer using the same.

First claim

The invention claimed is:

1. A hybrid supported catalyst comprising:
one or more of a first transition metal compound represented by the following Chemical Formula 1;
one or more of a second transition metal compound represented by the following Chemical Formula 2; and
a support supporting the first and second transition metal compounds,
wherein the first transition metal compound and the second transition metal compound are contained in a mixing molar ratio of 7:1 to 3:1,

in the above Chemical Formula 1,
M 1 is Ti, Zr or Hf,
X 11 and X 12 are the same as or different from each other and each independently represent a halogen,
R 1 and R 2 are each hydrogen, or are connected with each other to form an aliphatic ring having 3 to 10 carbon atoms, and
R 3 to R 20 are each hydrogen;

in the above Chemical Formula 2,
M 2 is Ti, Zr or Hf,
X 21 and X 22 are each independently represent a halogen,
R 21 to R 24 are each methyl;
R 25 , and R 27 to R 30 are each hydrogen;
R 26 is butyl or phenyl;
T is Si, and
Q 1 and Q 2 are the same as or different from each other and each independently represent an alkyl group having 1 to 20 carbon atoms.

2. The hybrid supported catalyst of claim 1 , wherein the first transition metal compound is any one of compounds represented by the following structural formulas:

3. The hybrid supported catalyst of claim 1 , wherein the second transition metal compound is any one of the compounds represented by the following structural formulas:

4. The hybrid supported catalyst of claim 1 , wherein the first transition metal compound and the second transition metal compound are contained in a mixing molar ratio of 7:1.

5. The hybrid supported catalyst of claim 1 , wherein the support includes any one selected from the group consisting of silica, alumina, and magnesia, or a mixture of two or more thereof.

6. The hybrid supported catalyst of claim 1 , further comprising at least one cocatalyst selected from the group consisting of compounds represented by the following Chemical Formulas 3 to 5:
R 32 —[Al(R 31 )—O] n —R 33   [Chemical Formula 3]

in the above formula 3,
R 31 , R 32 and R 33 are each independently hydrogen, a halogen, a hydrocarbyl group having 1 to 20 carbon atoms or a hydrocarbyl group having 1 to 20 carbon atoms substituted with a halogen,
n is an integer of 2 or more,
D(R 34 ) 3   [Chemical Formula 4]

in the above formula 4,
D is aluminum or boron,
each R 34 is independently a halogen, a hydrocarbyl group having 1 to 20 carbon atoms, a hydrocarbyloxy group having 1 to 20 carbon atoms, or a hydrocarbyl group having 1 to 20 carbon atoms substituted with a halogen,
[L-H] + [W(A) 4 ] − or [L] + [W(A) 4 ] −   [Chemical Formula 5]

in the above formula 5,
L is a neutral or cationic Lewis base, H is a hydrogen atom,
W is a Group 13 element, each A is independently a hydrocarbyl group having 1 to 20 carbon atoms, or a hydrocarbyloxy group having 1 to 20 carbon atoms, each of which is optionally substituted with at least one substituent selected from a halogen, a hydrocarbyloxy group having 1 to 20 carbon atoms or a hydrocarbyl(oxy)silyl group having 1 to 20 carbon atoms.

7. A method for preparing an olefin polymer comprising a step of polymerizing an olefin monomer in the presence of the hybrid supported catalyst of claim 1 .

8. The method for preparing an olefin polymer of claim 7 , wherein the olefin monomer includes at least one selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 4-methyl-1-pentene, 1-hexene, 1-heptene, 1-octene, 1-decene, 1-undecene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-eicosene, norbornene, norbornadiene, ethylidenenorbornene, phenylnorbornene, vinylnorbornene, dicyclopentadiene, 1,4-butadiene, 1,5-pentadiene, 1,6-hexadiene, styrene, alpha-methylstyrene, divinylbenzene and 3-chloromethylstyrene.

Assignees

• Lg Chemical Ltd

Inventors

• Park Sung Ho
• Kwon Heon Yong
• Kwon Hyun Jee
• Lee Jin Young
• Lee Ki Soo
• Hong Dae Sik
• Cho Sol
• Kwon Oh Joo

Classifications

• C08F4/65916

  supported on a carrier, e.g. silica, MgCl2, polymer · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• C08F4/022

  Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts · CPC title

• C08F210/02

  Ethene · CPC title

• C07F17/00

  Metallocenes · CPC title