Method based on fluidizing for modifying and preparing low-cost titanium powders for 3D printing

Patent metadata

Field	Value
Publication number	US-11090718-B2
Application number	US-201916624916-A
Country	US
Kind code	B2
Filing date	Sep 30, 2019
Priority date	Nov 23, 2018
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

A method based on fluidizing for modifying and preparing low-cost titanium powders for 3D printing includes: using hydrogenated-dehydrogenated irregularly-shaped titanium powders as the raw material, adding the titanium powders to a fluidized bed reactor, and introducing Ar or H2 at the flow rate of 0.5-1.5 L/min, heating the reactor to 300-700° C., and fluidizing for 5-90 min to modify the titanium powders. When filled with high-purity argon gas and heated at high temperature, the sharp edges and corners of irregularly-shaped titanium powders are ground collision of the particles due to the friction among powder particles.

First claim

What is claimed is:

1. A method based on fluidizing for modifying and preparing titanium powders for 3D printing, comprising the following steps:
(1) adding a raw material comprising hydrogenated-dehydrogenated irregularly-shaped titanium powders to a fluidized bed reactor, and introducing a predetermined amount of Ar or H 2 gas into the fluidized bed reactor from bottom to top to remove air in the fluidized bed reactor and provide a gas protective environment for the raw material;
(2) after the air in the fluidized bed reactor is removed, transferring the fluidized bed reactor to a heating system for fluidization, and during the fluidization, continuously introducing a stable flow of the Ar or H 2 gas, heating the fluidized bed reactor to a constant temperature for the fluidization, and holding the fluidized bed reactor at the constant temperature for a predetermined time, wherein collision and friction occur among the hydrogenated-dehydrogenated irregularly-shaped titanium powders at the constant temperature in an Ar or H 2 protective atmosphere, thereby modifying the hydrogenated-dehydrogenated irregularly-shaped titanium powders, modifying a surface morphology and a particle size distribution of the raw material; and
(3) after the fluidization is completed, removing the fluidized bed reactor from the heating system, continuously introducing the stable flow of the Ar or H 2 gas into the fluidized bed reactor, cooling the fluidized bed reactor in atmospheric air, and when the fluidized bed reactor is cooled, stopping introduction of the Ar or H 2 gas, and collecting the titanium powders in a hopper;
wherein, a flow rate of the stable flow of the Ar or H 2 gas in step (2) is 0.5-1.5 L/min;
wherein, the constant temperature is 300-700° C., and the predetermined time to perform the fluidization is 5-90 min;
wherein, the flowability of the achieved titanium powders is better than 30 s/50 g.

Assignees

• Univ Beijing Science & Technology

Inventors

• Qin Mingli
• Chen Gang
• Ding Wangwang
• Qu Xuanhui

Classifications

• B22F1/14 Primary

  Treatment of metallic powder (mixing with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F1/142

  Thermal or thermo-mechanical treatment · CPC title

• B22F1/065

  Spherical particles · CPC title

• B22F2201/11

  Argon · CPC title