Method for coating boron

Patent metadata

Field	Value
Publication number	US-11090686-B2
Application number	US-201916403606-A
Country	US
Kind code	B2
Filing date	May 5, 2019
Priority date	May 9, 2018
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

The present application relates to a method for coating boron, to a boron-containing resin solution, to a boron-coated thermal neutron converter obtained by the method for coating boron, and further to a thermal neutron detector comprising the boron-coated thermal neutron converter. The method for coating boron as provided in the application is applicable for various substrates and has small restrictions on substrate shapes, particularly for substrates having complex surface structures and high aspect ratios.

First claim

The invention claimed is:

1. A boron-containing resin solution comprising a solute and a solvent, the solute comprising boron powder, a resin and a curing agent, wherein the weight ratio of the solute to the solvent is from 1:1 to 1:20.

2. The boron-containing resin solution according to claim 1 , wherein in the solute, the ratio of the total weight of the resin and curing agent to the weight of the boron powder is from 1:2 to 1:20.

3. The boron-containing resin solution according to claim 1 , wherein in the solute, the weight ratio of the curing agent to the resin is from 1:3 to 1:5.

4. A method for coating boron, comprising the following steps:
1) applying the boron-containing resin solution according to claim 1 on an internal surface and/or an external surface of a substrate;
2) removing the solvent in the boron-containing resin solution and hardening the resin, to form a boron-containing coating layer on the surface of the substrate.

5. The method for coating boron according to claim 4 , further comprising a pretreatment step prior to the step 1), wherein the pretreatment is to form a resin layer on the internal surface and/or external surface of the substrate.

6. The method for coating boron according to claim 5 , wherein the pretreatment step comprises the following steps:
a) weighing a resin, a curing agent and a solvent, and mixing them well to produce a resin solution;
b) applying the resin solution on the internal surface and/or external surface of the substrate;
c) removing the solvent in the resin solution and hardening the resin to form a resin layer on the surface of the substrate;
wherein the ratio of the total weight of the resin and curing agent to the weight of the solvent is 1:2 to 1:6.

7. The method for coating boron according to claim 6 , wherein, in the solute, the weight ratio of the curing agent to the resin is 1:3 to 1:5.

8. The method for coating boron according to claim 4 , wherein in the step 1), the boron-containing resin solution is applied on the surface of the substrate by the means of brush coating, spray coating or dipping coating.

9. The method for coating boron according to claim 4 , wherein in the step 2), a method of removing the solvent is to evaporate the solvent in the boron-containing resin solution by the means of baking.

10. A method for making a boron-coated thermal neutron converter, comprising the following steps:
1) preparing a substrate:
2) adhering a boron-containing coating layer on an internal surface and/or an external surface of the substrate using the method for coating boron according to claim 4 .

11. The boron-containing resin solution according to claim 1 , wherein the boron powder is a nanometer-sized boron powder.

12. The boron-containing resin solution according to claim 1 , wherein the resin is an epoxy resin having a molecular weight from 200 to 500.

13. The boron-containing resin solution according to claim 12 , wherein the resin selected from the group consisting of: bisphenol A epoxy resin, bisphenol F epoxy resin, novolac epoxy type resin vinyl ester resin and combinations thereof.

14. The boron-containing resin solution according to claim 1 , wherein the curing agent is selected from the group consisting of: ethylenediamine, triethylamine, diethylenetriamine, triethylenetetramine, N,N-dimethylaminopropylamine, N,N-diethylaminopropylamine, xylenediamine, m-phenylenediamine and combinations thereof.

15. The boron-containing resin solution according to claim 1 , wherein the solvent is a solvent having boiling point between 100° C. and 200° C.

16. The boron-containing resin solution according to claim 15 , wherein the solvent is selected from the group consisting of: butyl glycidyl ether, benzyl glycidyl ether, phenyl glycidyl ether, ethylene glycol diglycidyl ether, alkylene glycidyl ether and combinations thereof.

17. The boron-containing resin solution according to claim 1 , wherein the resin is a bisphenol A epoxy resin, the curing agent is triethylenetetramine, and the solvent is butyl glycidyl ether.

18. The method for coating boron according to claim 4 , wherein the substrate is a metallic substrate or a non-metallic insulating substrate.

19. The method for coating boron according to claim 18 , wherein the substrate is a substrate of aluminum, copper or Aramid paper.

Assignees

• Nuctech Co Ltd
• Univ Tsinghua

Inventors

• Yang Yigang
• Fang Zhujun
• Li Yulan

Classifications

• C09D1/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title

• B05D7/14

  to metal, e.g. car bodies (involving a chemical reaction between the metal and the coating C23) · CPC title

• B05D2202/25

  based on Al · CPC title

• B05D1/02

  performed by spraying · CPC title

• B05D3/0209

  Multistage baking · CPC title