Liquid desiccant based dehumidification and cooling system

Patent metadata

Field	Value
Publication number	US-11090605-B2
Application number	US-201916384423-A
Country	US
Kind code	B2
Filing date	Apr 15, 2019
Priority date	Dec 14, 2017
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

A liquid desiccant system including a high desorber, a low desorber, and an absorber that are in fluid communication with a working solution, where the high desorber provides rejected water vapor from the working fluid for condensation in a condenser of the low desorber that provides heat for rejection of additional water from the working solution in the low desorber effectively multiplying the heat provided for desorption. The low desorber provided the concentrated working solution to the absorber where water from ambient air is condensed into the concentrated working solution to provide a dilute working solution within a working solution conduit of the absorber that is thermally coupled to an internal cooler of the absorber. In some embodiments, the working solution can be an aqueous solution of at least one ionic liquid.

First claim

What is claimed is:

1. A liquid desiccant dehumidification system (LDDS) for drying air, the system comprising:
at least one desorber;
at least one absorber;
at least one heat exchanger; and
at least one condenser,
wherein:
the at least one heat exchanger is located along a conduit extending between the at least one desorber and the at least one absorber;
the at least one absorber interfaces with humid ambient air, absorbs water vapor from the humid ambient air to form dehumidified air, and directs the dehumidified air to the condenser;
the at least one desorber generates desorbed vapor from a dilute desiccant solution in a still air environment; and
the at least one condenser is located downstream from both the at least one desorber and the at least one absorber, such that heat generated by the condensation of the desorbed vapor heats the dehumidified air.

2. The LDDS of claim 1 , wherein:
the at least one desorber comprises a first desorber and a second desorber; and
the at least one heat exchanger comprises a first heat exchanger and a second heat exchanger.

3. The LDDS of claim 1 , wherein the at least one desorber has an operating temperature of between about 120° C. and about the boiling point temperature of a desiccant in the dilute desiccant solution.

4. The LDDS of claim 1 , wherein the dilute desiccant solution comprises an ionic liquid (IL), and the IL is non-crystallizable.

5. The LDDS of claim 4 , wherein the IL comprises 1-butyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imide, 1-ethyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)amide, tetra-nbutylphosphonium trifluoromethanesulfonyl leucine, or N-alkyl-N,N-dimethylhydroxyethylammoniumbis(trifluoromethane) sulfonylimide.

6. The LDDS of claim 2 , wherein the dilute desiccant solution is formed by the at least one absorber by communicating water vapor from the humid ambient air.

7. The LDDS of claim 6 , wherein the first concentrated desiccant solution is an aqueous solution comprising at least one ionic liquid (IL).

8. The LDDS of claim 2 , wherein the second desorber is configured, with the at least one condenser, for condensation of water generated by one or more of the at least one heat exchanger upon evaporation from the dilute desiccant solution.

9. The LDDS of claim 1 , wherein one or more absorbers of the at least one absorber comprises an internal cooler, wherein the internal cooler comprises a conduit of cooling water being in thermal communication with the dilute desiccant solution, and wherein the internal cooler is situated within a closed loop flow path.

10. A method of drying air, comprising:
inputting humid ambient air at a first temperature through an inlet to an absorber of a liquid desiccant dehumidification system (LDDS), the LDDS further comprising:
at least one desorber;
at least one heat exchanger; and
at least one condenser,
wherein:
the at least one heat exchanger is located along a conduit extending between the at least one desorber and the absorber;
the at least one condenser is located downstream from both the at least one desorber and the absorber; and
the at least one desorber is configured to directly desorb water vapor from a dilute desiccant solution in a still air environment; the method further comprising:

dehumidifying the humid ambient air within the absorber, thereby generating warm dry air;
outputting desorbed vapor from the at least one desorber;
transferring the warm dry air from the absorber to the at least one condenser; and
outputting hot dry air from the at least one condenser.

11. The method of claim 10 , wherein:
the at least one desorber comprises a first and a second desorber; and
the at least one heat exchanger comprises a first and a second exchanger.

12. The method of claim 10 , wherein the at least one desorber has an operating temperature of between about 120° C. and about the boiling point temperature of a desiccant in the dilute desiccant solution.

13. The method of claim 10 , wherein the dilute desiccant solution comprises an ionic liquid (IL), and the IL is non-crystallizable.

14. The method of claim 13 , wherein the IL comprises 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)amide, tetra-nbutylphosphonium trifluoromethanesulfonyl leucine, or N-alkyl-N,N-dimethylhydroxyethylammoniumbis(trifluoromethane) sulfonylimide.

15. A liquid desiccant dehumidification system (LDDS) for drying air, the system comprising:
an absorber configured to receive an inlet air carrying water vapor and remove at least a portion of the water vapor from the inlet air using a concentrated desiccant solution, thereby forming a dehumidified outlet air, wherein the concentration desiccant solution absorbs at least a portion of the water vapor from the inlet air, thereby forming a dilute desiccant solution;
a desorber operably coupled to the absorber, the desorber being configured to directly desorb water vapor from the dilute desiccant solution in a still air environment; and
a condenser configured to condense the located downstream from both the absorber and the desorber, wherein heat generated by the condensation of the desorbed water vapor is used to heat the dehumidified outlet air.

16. The LDDS of claim 15 , wherein the desorber has an operating temperature of between about 120° C. and about the boiling point temperature of a desiccant in the concentrated desiccant solution.

17. The LDDS of claim 16 , wherein the desiccant comprises an ionic liquid (IL), the IL being non-crystallizable.

18. The LDDS of claim 17 , wherein the IL comprises 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)amide, tetra-nbutylphosphonium trifluoromethanesulfonyl leucine, or N-alkyl-N,N-dimethylhydroxyethylammoniumbis(trifluoromethane) sulfonylimide.

Assignees

• Univ Florida

Inventors

• Moghaddam Saeed

Classifications

• F25B15/02

  without inert gas ({F25B15/004, F25B15/006, F25B15/008}, F25B15/12, F25B15/14, F25B15/16 take precedence) · CPC title

• B01D53/1425 Primary

  Regeneration of liquid absorbents · CPC title

• C09K5/047

  for absorption-type refrigeration systems · CPC title

• B01D53/28

  Selection of materials for use as drying agents · CPC title

• B01D2259/65

  Employing advanced heat integration, e.g. Pinch technology · CPC title