Reforming process with improved heater integration

Patent metadata

Field	Value
Publication number	US-11084994-B2
Application number	US-201715587959-A
Country	US
Kind code	B2
Filing date	May 5, 2017
Priority date	May 13, 2016
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

A method and apparatus for processing a hydrocarbon stream are described. The method includes heating a feed stream in a convective bank. The heated feed stream is reacted in a first reaction zone to form a first effluent, which is heated in a first radiant cell. The first radiant cell combusts fuel to heat the first effluent and forms a first exhaust gas. The first exhaust gas is contacted with the convective bank to heat the feed stream. The outlet temperature the heated feed stream from the convective bank is controlled by introducing an additional gas stream into the convective bank. There can be additional reaction zones and radiant heaters.

First claim

The invention claimed is:

1. A method for processing a hydrocarbon stream in a reformer, the method comprising:
heating a naphtha feed stream in a convective bank, the convective bank in fluid and thermal communication with at least one radiant cell, wherein the entire naphtha feed stream is heated in the convective bank without passing through the at least one radiant cell or another radiant heater before reaching the convective bank;
reacting the heated naphtha feed stream in a first reformer reaction zone to form a first reformer effluent;
heating the first reformer effluent in a first radiant cell, wherein the first radiant cell combusts fuel to heat the first reformer effluent and forms a first flue gas;
introducing the first flue gas from the first radiant cell into the convective bank to heat the naphtha feed stream;
removing an exhaust gas from the convective bank at a temperature in a range of about 732° C. to about 899° C.; and
controlling an outlet temperature of the heated naphtha feed stream from the convective bank to a temperature in a range of about 427° C. to about 649° C. by introducing an additional gas stream into the convective bank so that the additional gas stream mixes with the flue gas to maintain a temperature in the convective bank in a range of about 732° C. to about 899° C., wherein the additional gas stream comprises a fresh gas at a temperature in a range of −12° C. to about 982° C., a recycled portion of the exhaust gas at a temperature in a range of about 149° C. to about 260° C., or a combination thereof, and wherein the fresh gas does not comprise steam.

2. The method of claim 1 where the additional gas stream comprises the fresh gas, and wherein a temperature of the fresh gas or an amount of the fresh gas, or both is adjusted based on the outlet temperature of the heated feed stream.

3. The method of claim 2 wherein the temperature of the fresh gas is increased.

4. The method of claim 1 where the additional gas stream comprises the fresh gas.

5. The method of claim 1 where the additional gas stream comprises the fresh gas, and wherein the fresh gas is compressed.

6. The method of claim 1 where the additional gas stream comprises the recycled portion of the exhaust gas, and wherein the recycled portion of the exhaust gas is compressed before being introduced into the convective bank.

7. The method of claim 1 where the additional gas stream comprises the recycled portion of the exhaust gas.

8. The method of claim 1 where the additional gas stream comprises the recycled portion of the exhaust gas, and wherein a temperature of the recycled portion of the exhaust gas or an amount of the recycled portion of the exhaust gas, or both is adjusted based on the outlet temperature of the heated naphtha feed stream.

9. The method of claim 1 wherein controlling the outlet temperature of the heated feed stream from the convective bank comprises:
monitoring the outlet temperature of the heated naphtha feed stream; and
adjusting an amount of the additional gas stream introduced into the convective bank, or adjusting a temperature of the additional gas stream introduced into the convective bank, or both based on the outlet temperature of the heated naphtha feed stream.

10. The method of claim 1 further comprising:
reacting the heated first reformer effluent in a second reformer reaction zone to form a second reformer effluent;
heating the second reformer effluent in a second radiant cell, wherein the second radiant cell combusts fuel to radiantly heat the second reformer effluent and the combusted fuel forms a second flue gas;
introducing the second flue gas from the second radiant cell into the convective bank so that the second flue gas mixes with the flue gas to heat the naphtha feed stream;
reacting the heated second reformer effluent in a third reformer reaction zone to form a third reformer effluent;
heating the third reformer effluent in a third radiant cell, wherein the third radiant cell combusts fuel to radiantly heat the third reformer effluent and the combusted fuel forms a third flue gas;
introducing the third flue gas from the third radiant cell into the convective bank so that the third flue gas mixes with the flue gas to heat the naphtha feed stream; and
reacting the heated third reformer effluent in a fourth reformer reaction zone to form a product effluent.

11. The method of claim 10 further comprising:
passing the naphtha feed stream and the product effluent through a heat exchanger before heating the naphtha feed stream in the convective bank to preheat the naphtha feed stream.

12. The method of claim 10 further comprising condensing the product effluent to form a product stream.

13. The method of claim 1 further comprising adding a gas stream comprising hydrogen to the naphtha feed stream before heating the naphtha feed stream in the convective bank.

14. A method for processing a hydrocarbon stream in a reformer, the method comprising:
heating a naphtha feed stream in a convective bank, the convective bank in fluid and thermal communication with at least one radiant cell, wherein the entire naphtha feed stream is heated in the convective bank without passing through the at least one radiant cell or another radiant heater before reaching the convective bank;
reacting the heated naphtha feed stream in a first reformer reaction zone to form a first reformer effluent;
heating the first reformer effluent in a first radiant cell, wherein the first radiant cell combusts fuel to heat the first reformer effluent and forms a first flue gas;
introducing the first flue gas from the first radiant cell into the convective bank to heat the naphtha feed stream;
removing an exhaust gas from the convective bank, the exhaust gas having a temperature in a range of about 732° C. to about 899° C.;
monitoring an outlet temperature of the heated naphtha feed stream from the convective bank; and
controlling the outlet temperature of the heated naphtha feed stream to a temperature in a range of about 427° C. to about 649° C. by introducing an additional gas stream into the convective bank so that the additional gas stream mixes with the first flue gas, and adjusting an amount of the additional gas, or adjusting a temperature of the additional gas, or both in response to the outlet temperature of the heated naphtha stream to maintain a temperature in the convective bank in a range of about 732° C. to about 899° C., wherein the additional gas stream comprises a fresh gas, a recycled portion of the exhaust gas, or a combination thereof, wherein the fresh gas is at a temperature in a range of −12° C. to about 982° C., and wherein the recycled portion of the first exhaust gas is at a temperature in a range of about 149° C. to about 260° C., and wherein the fresh gas does not comprise steam.

15. The method of claim 14 wherein the additional gas stream is compressed.

16. The method of claim 14 further comprising:
reacting the heated first reformer effluent in a second reformer reaction zone to form a second reformer effluent;
heating the second reformer effluent in a second radiant cell, wherein the second radiant cell combusts fuel to radiantly heat the second reformer effluent and the combusted fuel forms a second flue gas;
introducing the second flue gas from the second radiant cell into the convective bank so that the second flue gas mixes with the first flue gas to heat the naphtha feed stream;
reacting the second reformer effluent in a third reformer reaction zone to form a third reformer effluent;
heating the third reformer effluent in a thi

Assignees

• Uop Llc

Inventors

• Egolf Bryan J
• Brabson Charles
• Hartman William M
• Yanez William
• Martin Matthew
• Lok Ka

Classifications

• C10G9/36 Primary

  with heated gases or vapours · CPC title

• C10G59/02

  plural serial stages only · CPC title

• C10G69/08 Primary

  including at least one step of reforming naphtha · CPC title

• C10G2300/4006

  Temperature · CPC title

• C10G69/00

  Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process (C10G67/00 takes precedence) · CPC title