Functionalized polymer compositions for low VOC coalescence of water based emulsions

Patent metadata

Field	Value
Publication number	US-11084952-B2
Application number	US-201916387806-A
Country	US
Kind code	B2
Filing date	Apr 18, 2019
Priority date	Apr 18, 2018
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

A coating composition is described that has good film forming and blocking properties in a composition that also has low or no VOCs. The coating compositions herein include functionalized urethane (meth)acrylate polymers that allow better film formation and particle coalescence while maintaining the low or no VOC levels. In one aspect, the coating compositions include functionalized polymers with a higher glass transition temperature (Tg) to aid in achieving good block resistance but a low minimum film forming temperature (MFFT) to achieve good particle coalescence and film formation all while being substantially free of co-solvents, coalescent aid and/or plasticizers.

First claim

What is claimed is:

1. A low VOC latex coating composition for improved coalescence of water-based emulsions, the low VOC latex coating composition comprising:
a polymer obtained from monomers including one or more of a vinyl acetate monomer, an alkyl (meth)acrylate monomer, a styrenic monomer, or combinations thereof together with a urethane (meth)acrylate monomer;
the urethane (meth)acrylate monomer providing about 4 to about 15 percent of sterically available hydrogen bonding sites per urethane (meth)acrylate monomer;
the urethane (meth)acrylate monomer having the formula:

wherein R is hydrogen or a methyl group, R 1 is an alkylene chain with 1 to 10 carbons, R 2 is an alkyl chain with 1 to 3 carbons or an alkyl carbamate having an alkyl endcap with 1 to 4 carbons, and R 4 is an alkyl chain with 1 to 4 carbons;
the polymer having a glass transition temperature as measured by differential scanning calorimetry of about 17° C. or greater and a minimum film forming temperature of about 12° C. or lower at the same time;
water;
one or more of inorganic pigment particles, opaque polymer particles, or extender pigment particles; and
wherein the low VOC latex coating composition is substantially free of co-solvents, plasticizers, coalescence aids, and mixtures thereof.

2. The low VOC latex coating composition of claim 1 , wherein the low VOC latex coating composition includes the inorganic pigment particles and wherein the inorganic pigment particles include one of titanium dioxide, zinc oxide, magnesium oxide, potassium oxide, or combinations thereof.

3. The low VOC latex coating composition of claim 1 , wherein the urethane (meth)acrylate monomer provides about 2 to about 9 percent sterically available hydrogen bonding sites that are spaced 1 to 3 carbon atoms from a terminal end of the urethane (meth)acrylate monomer.

4. The low VOC latex coating composition of claim 1 , wherein the coating composition, when dry, forms a homogeneous film at the minimum film forming temperature of about 12° C. or lower and being substantially free of the co-solvents, plasticizers, coalescence aids, and mixtures thereof at least in part by a coalesced polymer network including amide nitrogen to carbonyl oxygen hydrogen bonds between polymer particles therein.

5. The low VOC latex coating composition of claim 1 , wherein the R 2 group is a linear alkyl chain.

6. The low VOC latex coating composition of claim 1 , wherein the low VOC latex coating composition has less than about 0.5 weight percent of the co-solvents, plasticizers, coalescence aids, and mixtures thereof.

7. The low VOC latex coating composition of claim 1 , wherein the polymer includes about 2 to about 20 mol percent of the urethane (meth)acrylate monomer units.

8. The low VOC latex coating composition of claim 1 , wherein R 2 is an alkyl carbamate moiety of the formula

wherein R 3 is an alkylene chain with 1 to 6 carbons and R 4 is an alkyl chain with 1 to 4 carbons.

9. The low VOC latex coating composition of claim 1 , wherein the polymer has a glass transition temperature as measured by differential scanning calorimetry of about 17 to about 40° C. and a minimum film forming temperature of about 0 to about 12° C.

10. The low VOC latex coating composition of claim 9 , wherein a difference between the glass transition temperature as measured by differential scanning calorimetry and the minimum film forming temperature is at least about 5° C.

11. The low VOC latex coating composition of claim 1 , wherein a difference between the glass transition temperature as measured by differential scanning calorimetry and the minimum film forming temperature is about 5° C. to about 40° C.

12. The low VOC latex coating composition of claim 1 , wherein the low VOC latex coating composition has a VOC of about 5 g/L or less.

13. The low VOC coating composition of claim 1 , wherein a dried coating thereof exhibits a blocking resistance of 4 or higher as measured by ASTM D4946-89.

14. A low VOC latex coating composition for improved coalescence of water-based emulsions, the low VOC latex coating composition comprising:
a polymer obtained from monomers including one or more of a vinyl acetate monomer, an alkyl (meth)acrylate monomer, a styrenic monomer, or combinations thereof together with a urethane (meth)acrylate monomer;
the urethane (meth)acrylate monomer providing about 4 to about 15 percent of sterically available hydrogen bonding sites per urethane (meth)acrylate monomer;
the polymer having a glass transition temperature as measured by differential scanning calorimetry of about 17° C. or greater and a minimum film forming temperature of about 12° C. or lower at the same time;
water;
one or more of inorganic pigment particles, opaque polymer particles, or extender pigment particles;
wherein the low VOC latex coating composition is substantially free of co-solvents, plasticizers, coalescence aids, and mixtures thereof; and
wherein the polymer includes the vinyl acetate monomer, the alkyl (meth)acrylate monomer, and the urethane (meth)acrylate monomer.

15. The low VOC coating composition of claim 14 , wherein the polymer includes about 2 to about 20 mol percent of the urethane (meth) acrylate monomer, about 20 to about 97 mol percent of the alkyl (meth)acrylate monomer, and about 20 to about 90 mol percent of the vinyl acetate monomer.

16. The low VOC latex coating composition of claim 15 , wherein the polymer further includes about 0.2 to about 10 mol acrylic acid.

17. The low VOC latex coating composition of claim 14 , wherein a difference between the glass transition temperature as measured by differential scanning calorimetry and the minimum film forming temperature is about 5° C. to about 40° C.

18. The low VOC latex coating composition of claim 14 , wherein the low VOC latex coating composition has a VOC of about 5 g/L or less.

19. The low VOC latex coating composition of claim 18 , wherein the low VOC latex coating composition has less than about 0.5 weight percent of the co-solvents, plasticizers, coalescence aids, and mixtures thereof.

Assignees

• Univ Akron
• Swimc Llc

Inventors

• Soucek Mark
• Cobaj Anisa
• Makowski Brian

Classifications

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title

• C09D133/062 Primary

  Copolymers with monomers not covered by C09D133/06 · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08G18/30

  Low-molecular-weight compounds {(C08G18/2805 takes precedence)} · CPC title