Fast conductivity polymer silver

Patent metadata

Field	Value
Publication number	US-11084950-B2
Application number	US-201716067624-A
Country	US
Kind code	B2
Filing date	Mar 10, 2017
Priority date	Mar 24, 2016
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

A conductive paste is provided for forming conductive traces on substrates. The conductive paste includes a vehicle and conductive material. The vehicle includes a resin, a plasticizer, and a solvent in which the resin is dissolved. After application to a substrate, the conductive paste is cured at ambient temperature by evaporation of the solvent from the paste, to thereby form a conductive trace on the substrate. The conductive trace does not require a curing agent, and attains low resistivity within minutes of application to the substrate.

First claim

What is claimed is:

1. A lead, cadmium, glass frit, and phthalate free conductive paste comprising 80-90 wt % conductive material comprising silver particles, and 10-20 wt % of a binder system,
wherein 100 wt % of the binder system includes:
10-20 wt % thermoplastic polymer resin comprising polyvinyl butyral,
5-20 wt % plasticizer comprising triethylene glycol bis(2-ethylhexanoate), and
70-75 wt % solvent,
wherein the thermoplastic polymer resin is dissolved in the solvent, wherein a weight ratio of the amount of thermoplastic polymer resin to the amount of the plasticizer is 1.25 to 1.75,
wherein when the conductive paste is applied to an associated substrate, within 5 minutes at ambient temperature, the conductive paste loses 0.5-1 wt % of its total weight by evaporation of the solvent,
wherein, without requiring heating, curing agent, infra-red (IR) radiation, laser beam, flash light, microwave radiation, UV radiation, or a combination thereof, a flexible conductive trace formed from the conductive paste on the substrate, wherein
the flexible conductive trace of the conductive paste achieves an electrical resistance of less than 1.00×10 4 ohms (Ω) within 1 minute of applying the conductive paste at ambient temperature to the substrate, and achieves an electrical resistance of less than 1 ohm within 5 minutes of applying the conductive paste at ambient temperature to the substrate, and wherein the flexible conductive trace formed from the conductive paste achieves a modulus of elasticity of about 1-4×10 3 psi as measured by ASTM D790-59T.

2. The conductive paste according to claim 1 , further comprising 0.5-1.5 wt % of a thixotrope.

3. The conductive paste according to claim 1 , further comprising 0.05-0.15 wt % defoamer.

4. The conductive paste according to claim 1 , further comprising 0.05-1 wt % of a gelling agent.

5. The conductive paste according to claim 4 , wherein the gelling agent comprising dibenzylidene sorbitol.

6. The conductive paste according to claim 1 , wherein the solvent comprising a mixture at isopropyl alcohol and denatured ethyl alcohol.

7. The conductive paste according to claim 1 , wherein the solvent is a mixture of a first solvent having an evaporation rate of less than 0.5 times the evaporation rate of n-butyl acetate at 25° C., and a second solvent having an evaporation rate of more than 2 times the evaporation rate of n-butyl acetate at 25° C.

8. The conductive paste according to claim 7 , wherein the first solvent is diethylene glycol n-butyl ether and the second solvent is isopropyl alcohol.

9. The conductive paste according to claim 1 , wherein the solvent is n-butanol.

10. A method of forming a flexible conductive trace on a substrate, the method comprising:
(a) providing a lead, cadmium, glass frit, and phthalate free conductive paste including 80-90 wt % conductive material, and 10-20 wt % of a binder system,
wherein 100 wt % of the binder system includes 10-20 wt % thermoplastic polymer resin, 5-20 wt % plasticizer, and 70-75 wt % solvent,
wherein the thermoplastic polymer resin is dissolved in the solvent, and
wherein a weight ratio of the amount of thermoplastic polymer resin to the amount of the plasticizer is 1.25 to 1.75, and
(b) applying the conductive paste to a substrate in a predetermined pattern; and
(c) curing the conductive paste by allowing the solvent to evaporate from the conductive paste at ambient temperature and without requiring heating, curing agent, infra-red (IR) radiation, laser beam, flash light, microwave radiation, UV radiation, or a combination thereof to thereby form a flexible conductive trace on the substrate,
wherein within 5 minutes after application of the conductive paste to the substrate at ambient temperature, the conductive paste loses 0.5-1 wt % of its total weight by evaporation of the solvent, and
wherein the flexible conductive trace achieves an electrical resistance of less than 1.00×10 4 ohms (Ω) within 1 minute from application of the conductive paste to the substrate at ambient temperature, and the flexible conductive trace achieves an electrical resistance of less than 1 ohm within 5 minutes from application of the conductive paste to the substrate, and wherein the flexible conductive trace achieves a modulus of elasticity of about 1-4×10 3 psi as measured by ASTM D790-59T.

11. The method according to claim 10 , wherein the binder system includes:
12.5-17.5 wt % of the polymer resin,
8-10 wt % of the plasticizer, and
70-75 wt % of the solvent.

12. The method according to claim 10 , wherein the conductive paste further comprises 0.05-0.15 wt % defoamer.

13. The method according to claim 10 , wherein the conductive paste further comprising 0.5-1.5 wt % of a thixotrope.

14. The method according to claim 10 , wherein the conductive paste further comprising 0.05-1 wt % of a gelling agent.

15. The method according to claim 10 , wherein the polymer resin comprising polyvinyl butyral.

16. The method according to claim 15 , wherein the plasticizer comprising triethylene glycol bis(2-ethylhexanoate).

17. The method according to claim 10 , wherein the solvent is a mixture of a first solvent having an evaporation rate of less than 0.5 times the evaporation rate of n-butyl acetate at 25° C., and a second solvent having an evaporation rate of more than 2 times the evaporation rate of n-butyl acetate at 25° C.

18. The method according to claim 17 , wherein the first solvent is diethylene glycol n-butyl ether and the second solvent is isopropyl alcohol.

19. The method according to claim 10 , wherein the solvent comprising n-butanol.

20. The method according to claim 10 , wherein the conductive paste is applied to the substrate by one selected from the group consisting of syringe deposition, digital printing, screen printing, or combinations thereof.

21. A lead, cadmium, glass frit, and phthalate free conductive paste comprising 80-90 wt % conductive material comprising silver particles, and 10-20 wt % of a binder system,
wherein 100 wt % of the binder system includes:
25-30 wt % thermoplastic polymer resin comprising polyvinyl butyral, and 70-75 wt % solvent,
wherein the thermoplastic polymer resin is dissolved in the solvent, and
wherein the conductive paste is applied to an associated substrate at ambient temperature to form a flexible conductive trace, wherein
within 5 minutes of the application of the conductive paste to the associated substrate at ambient temperature, the conductive paste loses 0.5-1 wt % of its total weight by evaporation of the solvent,
wherein, without requiring heating, curing agent, infra-red (IR) radiation, laser beam, flash light, microwave radiation, UV radiation, or a combination, the flexible conductive trace achieves an electrical resistance of less than 1.00×10 4 ohms (Ω) within 1 minute from application of the conductive paste at ambient temperature to the substrate, wherein the flexible conductive trace achieves an electrical resistance less than 1 ohm within 5 minutes from application of the conductive paste at ambient temperature to the substrate, and a wherein the flexible conductive trace achieves modulus of elasticity of about 1-4×10 3 psi as measured by ASTM D790-59T.

22. The conductive paste according to claim 21 , wherein the solvent comprising cyclohexanone.

23. The conductive paste according to claim 21 , wherein the thermoplastic polymer resin comprising polyvinyl butyral and phenoxy resin.

2

Assignees

• Ferro Corp

Inventors

• Graddy Jr G Edward
• Cruz Ben E

Classifications

• C08K5/06

  Ethers; Acetals; Ketals; Ortho-esters · CPC title

• C08K3/08 Primary

  Metals · CPC title

• C09D5/38

  Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36 · CPC title

• C08K5/103

  with polyalcohols · CPC title

• C09D7/61

  inorganic · CPC title