Dye compound and photopolymer composition

Patent metadata

Field	Value
Publication number	US-11084933-B2
Application number	US-201816651906-A
Country	US
Kind code	B2
Filing date	Dec 7, 2018
Priority date	Dec 15, 2017
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

The present invention relates to a compound having a novel structure, a photopolymer composition including the compound as a dye, a hologram recording medium produced from the photopolymer composition, an optical element including the hologram recording medium, and a holographic recording method using the hologram recording medium.

First claim

The invention claimed is:

1. A compound selected from the group consisting of Chemical Formulae 3 to 5:

wherein, in the Chemical Formulae 3 to 5,
R 11 and R 12 are each independently hydrogen, a linear or branched alkyl group having 1 to 10 carbon atoms, or a linear or branched alkenyl group having 2 to 20 carbon atoms,
X 1 and X 2 are each independently a halogen group; or a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms,
R 30 and R 60 are each independently a halogen group; or a linear or branched alkyl group having 1 to 10 carbon atoms,
m and n are each independently 1 to 4 in the Chemical Formulae 3 and 5, and 1 to 3 in the Chemical Formula 4, and
Ar 3 is an aromatic ring having 6 to 20 carbon atoms substituted with one or more halogen groups.

2. A photopolymer composition comprising:
a polymer matrix or a precursor thereof;
a dye containing the compound of claim 1 ;
a photoreactive monomer; and
a photoinitiator.

3. The photopolymer composition according to claim 2 , wherein the polymer matrix or a precursor thereof includes 1) a reaction product between a compound containing one or more isocyanate groups and a polyol; or 2) a polymer matrix including a (meth)acrylate-based (co)polymer having a silane-based functional group in a branched chain thereof, and a silane crosslinking agent.

4. The photopolymer composition according to claim 3 , wherein the silane crosslinking agent includes a linear polyether main chain having a weight average molecular weight of 100 to 2000, and a silane-based functional group bonded at a terminal end or a branched chain of the main chain.

5. The photopolymer composition according to claim 3 , wherein the (meth)acrylate-based (co)polymer having a silane-based functional group in a branched chain,
includes a (meth)acrylate repeating unit and a (meth)acrylate repeating unit having the silane-based functional group in the branched chain, and
has a weight average molecular weight of 100,000 to 1,000,000.

6. The photopolymer composition according to claim 2 , wherein the photoreactive monomer includes a polyfunctional (meth)acrylate monomer, or a monofunctional (meth)acrylate monomer.

7. The photopolymer composition according to claim 2 , comprising 1% to 80% by weight of the polymer matrix or a precursor thereof; 1% to 80% by weight of the photoreactive monomer; 0.0001% to 10% by weight of the dye; and 0.1% to 20% by weight of the photoinitiator based on the total weight of the photopolymer composition.

8. The photopolymer composition according to claim 2 , wherein the photopolymer composition further comprises at least one selected from the group consisting of a catalyst, a phosphate-based compound, and a low refractive index fluorine-based compound.

9. The photopolymer composition according to claim 8 , wherein the low refractive index fluorine-based compound includes at least one functional group selected from the group consisting of an ether group, an ester group and an amide group, and at least two difluoromethylene groups.

10. A hologram recording medium produced from the photopolymer composition of claim 2 .

11. An optical element comprising the hologram recording medium of claim 10 .

12. A holographic recording method comprising selectively polymerizing photoreactive monomers contained in the photopolymer composition of claim 2 by a coherent laser.

13. The optical element of claim 11 , wherein the optical element includes a hologram display device.

Assignees

• Lg Chemical Ltd
• Korea Advanced Inst Sci & Tech

Inventors

• Kim Heon
• Kim Yoosik
• Kharbash Raisa
• Kwon Se Hyun
• Chang Yeongrae
• Jang Seokhoon

Classifications

• G03F7/035

  the binders being polyurethanes · CPC title

• C09B67/0013

  with polymeric coatings · CPC title

• C09B57/00 Primary

  Other synthetic dyes of known constitution · CPC title

• G03H2260/12

  Photopolymer · CPC title

• G03F7/0758

  with silicon- containing groups in the side chains · CPC title