Co-solubilization process for preparing modified bitumen and product obtained thereof

Patent metadata

Field	Value
Publication number	US-11084930-B2
Application number	US-201916719146-A
Country	US
Kind code	B2
Filing date	Dec 18, 2019
Priority date	Dec 19, 2018
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

The present invention relates to a co-solubilization process for preparation of a polymer modified bitumen/asphalt and emulsified polymer modified bitumen/asphalt from bitumen, polymer, emulsifier etc. The present invention further relates to a polymer modified bitumen comprising bitumen and styrene-butadiene-styrene (SBS) linear co-polymer having high softening point. The present invention also relates to the use of the polymer modified bitumen and its emulsion in in micro-surfacing for maintenance of pavements.

First claim

We claim:

1. A co-solubilization process for preparation of a polymer modified bitumen, the process comprising:
(a) heating a softer grade bitumen to a temperature ranging from 150° C. to 200° C.;
(b) adding styrene-butadiene-styrene (SBS) linear co-polymer for 10 to 20 minutes to the softer grade bitumen to obtain a mixture;
(c) dispersing the mixture obtained in step (b) at a temperature ranging from 150° C. to 200° C. followed by milling to obtain a homogenous matrix;
(d) adding a harder grade bitumen to the homogenous matrix obtained in step (c) to obtain a mixture, wherein the mixture comprises styrene-butadiene-styrene (SBS) linear co-polymer in an amount ranging from 3 to 5% by weight of the mixture; and
(e) stirring the mixture obtained in step (d) at a temperature ranging from 150° C. to 200° C. followed by milling to obtain the polymer modified bitumen;
wherein the polymer modified bitumen has a high softening point ranging from 60° C. to 90° C.;
wherein the softer grade bitumen has absolute viscosity ranging from 800 to 1200 poise at a temperature of 60° C. and the harder grade bitumen has absolute viscosity ranging from 2400 to 3600 poise at a temperature of 60° C.

2. The process as claimed in claim 1 , wherein the styrene-butadiene-styrene (SBS) linear co-polymer is added in step (b) in an amount ranging from 15 to 20% by weight of the softer grade bitumen.

3. The process as claimed in claim 1 , wherein milling of the mixture in steps (c) and (de) is done for 20 to 30 minutes.

4. A process for preparation of a polymer modified bitumen emulsion, the process comprising:
(a) heating a softer grade bitumen to a temperature ranging from 150° C. to 200° C.;
(b) adding styrene-butadiene-styrene (SBS) linear co-polymer for 10 to 20 minutes to the softer grade bitumen to obtain a mixture;
(c) dispersing the mixture obtained in step (b) at a temperature ranging from 150° C. to 200° C. followed by milling to obtain a homogenous matrix;
(d) adding a harder grade bitumen to the homogenous matrix obtained in step (c) to obtain a mixture, wherein the mixture comprises styrene-butadiene-styrene (SBS) linear co-polymer in an amount ranging from 3 to 5% by weight of the mixture;
(e) stirring the mixture obtained in step (d) at a temperature ranging from 150° C. to 200° C. followed by milling to obtain a polymer modified bitumen;
(f) optionally, mixing the polymer modified bitumen obtained in step (e) with an organic solvent to obtain an organic phase;
(g) mixing water, an acid, calcium chloride salt solution and an emulsifier to obtain an aqueous phase; and
(h) mixing the organic phase obtained in step (f) with the aqueous phase obtained in step (g) by milling to obtain the polymer modified bitumen emulsion;
wherein the softer grade bitumen has an absolute viscosity ranging from 800 to 1200 poise at a temperature of 60° C. and the harder grade bitumen has an absolute viscosity ranging from 2400 to 3600 poise at a temperature of 60° C.

5. The process as claimed in claim 4 , wherein the styrene-butadiene-styrene (SBS) linear co-polymer is added in step (b) in an amount ranging from 15 to 20% by weight of the softer grade bitumen.

6. The process as claimed in claim 4 , wherein milling of the mixture in steps (c) and (e) is done for 20 to 30 minutes.

7. The process as claimed in claim 4 , wherein the organic solvent is selected from Straight run Kerosene Oil (SKO) or Mineral Turpentine Oil (MTO).

8. The process as claimed in claim 4 , wherein the aqueous phase comprises: 30 to 35 wt % of water, 1 to 2 wt % of acid, 0.15 to 0.5 wt % of calcium chloride salt solution, and 0.25 to 1.5 wt % of emulsifier; wherein the wt % of each of the components is calculated based on the total weight of the polymer modified bitumen emulsion.

9. The process as claimed in claim 8 , wherein the acid in the aqueous phase is a mineral acid.

10. The process as claimed in claim 8 , wherein the emulsifier in the aqueous phase is an amine selected from the group consisting of secondary, tertiary amine, and long chain fatty amines.

11. The process as claimed in claim 4 , wherein the polymer modified bitumen emulsion is used for micro-surfacing flexible pavements, construction and maintenance of roads and pavements, resurfacing and construction of parking lots.

Assignees

• Indian Oil Corp Ltd

Inventors

• Deorukhkar Amol
• Kochukutty David
• Irudayaraj Devotta
• Raman Naduhatty Selai
• Sau Madhusudan
• Mazumdar Sanjiv Kumar
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title

• C08L2555/84

  Polymers comprising styrene, e.g. , polystyrene, styrene-diene copolymers or styrene-butadiene-styrene copolymers · CPC title

• C08L2555/22

  Asphalt produced above 140°C, e.g. hot melt asphalt · CPC title

• C08J2409/06

  Copolymers with styrene · CPC title

• C08L95/00 Primary

  Compositions of bituminous materials, e.g. asphalt, tar, pitch · CPC title