Fiber-reinforced composite material molded article and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-11084187-B2
Application number	US-201615565730-A
Country	US
Kind code	B2
Filing date	Apr 15, 2016
Priority date	Apr 17, 2015
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

The purpose of the present invention is to obtain a fiber-reinforced composite material molded article having high adhesive strength in a boundary portion between an insert portion comprising a fiber-reinforced resin substrate and an integrally molded portion molded integrally with the insert portion. A fiber-reinforced composite material molded article (1) containing reinforcing fibers and a thermoplastic resin and being provided with a first layer (23), a second layer (22), and a third layer (21) in this order, the thickness of each layer, the ratio of the total volume of reinforcing fibers (x2) having a fiber length of 3 mm to less than 100 mm with respect to the total volume of reinforcing fibers present in the layer, the ratio of the total volume of reinforcing fibers (y2) having a fiber length of 0.02 mm to less than 3 mm with respect to the total volume of reinforcing fibers present in the layer, and the volume content of fibers in each layer being controlled so as to be in specific ranges.

First claim

What is claimed is:

1. A molded article of fiber-reinforced composite material, comprising:
reinforcing fibers;
a thermoplastic resin; and
a first layer, second layer and third layer formed in that order, wherein:
the first layer has a thickness of at least 300 μm, a ratio of a total volume of reinforcing fibers (x 2 ) with a fiber length of 3 mm or longer but shorter than 100 mm relative to an entire volume of reinforcing fibers in the first layer is set at 67 vol. % or higher, and a fiber volume ratio (Vf 1 ) is from 15 to 50 vol. %;
the second layer has a thickness of from 100 to 1500 μm, and relative to an entire volume of reinforcing fibers in the second layer, a ratio of the total volume of the reinforcing fibers (x 2 ) is more than 33 vol. % while a ratio of a total volume of reinforcing fibers (y 2 ) with a fiber length of 0.02 mm or longer but shorter than 3 mm is set at 36 vol. % or more and lower than 67 vol. %; and
the third layer has a thickness of at least 300 μm, a ratio of the total volume of the reinforcing fibers (y 2 ) relative to an entire volume of reinforcing fibers in the third layer is set at 67 vol. % or higher, and a fiber volume ratio (Vf 3 ) is from 5 to 25 vol.%,
wherein reinforcing fibers (x 2 ) and reinforcing fibers (y 2 ) are each inorganic fibers.

2. The molded article according to claim 1 , wherein the first layer and the third layer are bonded with the second layer placed between them.

3. The molded article according to claim 1 , wherein the fiber volume ratio (Vf 1 ) in the first layer, the fiber volume ratio (Vf 2 ) in the second layer and the fiber volume ratio (Vf 3 ) in the third layer satisfy formula (1):
Vf 3< Vf 2< Vf 1...  (1)

4. The molded article according to claim 1 , wherein reinforcing fibers (x 2 ) are carbon fibers.

5. The molded article according to claim 1 , wherein reinforcing fibers (y 2 ) are carbon fibers.

6. The molded article according to claim 1 , wherein reinforcing fibers (x 2 ) and reinforcing fibers (y 2 ) are each carbon fibers.

7. A method of producing the molded article of fiber-reinforced composite material as claimed in claim 1 , the method comprising:
integrally molding in a die a fiber-reinforced resin substrate (X) comprising a thermoplastic resin (x 1 ) and reinforcing fibers (x 2 ) with a fiber length of 3 mm or longer but shorter than 100 mm and a resin composition (Y) comprising a thermoplastic resin (y 1 ) and reinforcing fibers (y 2 ) with a fiber length of 0.02 mm or longer but shorter than 3 mm,
wherein:
relative to an entire volume of reinforcing fibers in the fiber-reinforced resin substrate (X), a ratio of a total volume of the reinforcing fibers (x 2 ) is 67 vol. % or higher, and a fiber volume ratio in the fiber-reinforced resin substrate (X) is from 15 to 50 vol. %;
relative to an entire volume of reinforcing fibers in the resin composition (Y), a ratio of a total volume of the reinforcing fibers (y 2 ) is 67 vol. % or higher, and a fiber volume ratio in the resin composition (Y) is from 5 to 25 vol. %; and
the integrally molding of the fiber-reinforced resin substrate (X) and the resin composition (Y) occurs in a state where the reinforcing fibers (x 2 ) are exposed on at least a portion of a surface of fiber-reinforced resin substrate (X).

8. The method according to claim 7 , further comprising, prior to the integrally molding:
exposing the reinforcing fibers (x 2 ) on at least a portion of the surface of fiber-reinforced resin substrate (X) by applying heat on a portion of the fiber-reinforced resin substrate (X) where no reinforcing fibers (x 2 ) are exposed.

9. The method according to claim 7 , wherein the resin composition (Y) is injected into the die during the integrally molding.

10. The method according to claim 9 , wherein the resin composition (Y) is injected when the fiber-reinforced resin substrate (X) is placed and is being shaped in the die, or after the fiber-reinforced resin substrate (X) is placed and shaped in the die.

11. The method according to claim 7 , wherein the fiber-reinforced resin substrate (X) and the resin composition (Y) are press-molded to be integrated with each other during the integrally molding.

12. The method according to claim 7 , wherein at least part of the thermoplastic resin (x 1 ) is fibrous.

13. The method according to claim 7 , wherein the fiber-reinforced resin substrate (X) is a fiber-reinforced resin substrate (X 1 ) which is compressible in a thickness direction.

Assignees

• Mitsubishi Chem Corp

Inventors

• Tomioka Masao
• Ishikawa Takeshi
• Sasaki Akinobu

Classifications

• B29C45/14631 Primary

  Coating reinforcements (fibre reinforcements B29C45/0005) · CPC title

• B29C43/20

  Making multilayered or multicoloured articles {(B29C43/14 takes precedence)} · CPC title

• B29C45/561

  Injection-compression moulding · CPC title

• B29C70/081

  Combinations of fibres of continuous or substantial length and short fibres · CPC title

• B29C45/14

  incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles {(B29C45/1671 takes precedence)} · CPC title