Photopolymer composition

Patent metadata

Field	Value
Publication number	US-11079678-B2
Application number	US-201816343153-A
Country	US
Kind code	B2
Filing date	Sep 11, 2018
Priority date	Sep 27, 2017
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

A photopolymer composition comprising a polymer matrix or a precursor thereof including a reaction product between (i) a (meth)acrylate-based (co)polymer in which a silane-based functional group is located in a branched chain and an equivalent weight of the silane-based functional group is 300 g/eq to 2000 g/eq, and (ii) a linear silane crosslinking agent; a photoreactive monomer; and a photoinitiator, a hologram recording medium using the same, an optical element using the hologram recording medium, and a holographic recording method. The photopolymer composition can more easily provide a photopolymer layer having improved durability against temperature and humidity while having a large refractive index modulation value.

First claim

The invention claimed is:

1. A photopolymer composition comprising:
a polymer matrix or a precursor thereof including a reaction product between (i) a (meth)acrylate-based (co)polymer in which a silane-based functional group is located in a branched chain and an equivalent weight of the silane-based functional group is 300 g/eq to 2000 g/eq, and (ii) a linear silane crosslinking agent;
a photoreactive monomer; and
a photoinitiator;
wherein the linear silane crosslinking agent includes a linear polyether main chain having a weight average molecular weight of 100 g/mol to 2000 g/mol and a silane-based functional group bonded to a terminal or branched chain of the linear polyether main chain.

2. The photopolymer composition of claim 1 , wherein the linear silane crosslinking agent is contained in an amount of 10 parts by weight to 90 parts by weight, based on 100 parts by weight of the (meth)acrylate-based (co)copolymer.

3. The photopolymer composition of claim 1 , wherein a modulus (storage modulus) of the reaction product is 0.01 MPa to 5 MPa as measured at a frequency of 1 Hz at room temperature using DHR equipment (TA Instruments).

4. The photopolymer composition of claim 1 , wherein the silane-based functional group and the linear polyether main chain are bonded via a urethane bond.

5. The photopolymer composition of claim 1 , wherein an equivalent weight of the silane-based functional group contained in the linear silane crosslinking agent is 200 g/eq to 1000 g/eq.

6. The photopolymer composition of claim 1 , wherein a ratio between the equivalent weight of the silane-based functional group located in the branched chain of the (meth)acrylate-based (co)polymer and the equivalent weight of the silane-based functional groups contained in the linear silane crosslinking agent is from 22:1 to 0.5:1.

7. The photopolymer composition of claim 1 , wherein the photoreactive monomer comprises a polyfunctional (meth)acrylate monomer or a monofunctional (meth)acrylate monomer.

8. The photopolymer composition of claim 1 , wherein the photoreactive monomer has a refractive index of 1.5 or more.

9. The photopolymer composition of claim 1 , wherein the photopolymer composition comprises: 20% to 80% by weight of the polymer matrix or a precursor thereof; 10% to 70% by weight of the photoreactive monomer; and 0.1% to 15% by weight of the photoinitiator based on the total weight of the photopolymer composition.

10. The photopolymer composition of claim 1 , wherein the photopolymer composition further comprises a fluorine-based compound.

11. The photopolymer composition of claim 10 , wherein the fluorine-based compound includes at least two difluoromethylene groups, and at least one functional group selected from the group of an ether group, an ester group, and an amide group.

12. The photopolymer composition of claim 10 , wherein the fluorine-based compound has a refractive index of less than 1.45.

13. The photopolymer composition of claim 10 , wherein the fluorine-based compound is contained in an amount of 30 parts by weight to 150 parts by weight, based on 100 parts by weight of the photoreactive monomer.

14. The photopolymer composition of claim 1 , wherein the polymer matrix has a refractive index of 1.46 to 1.53.

15. The photopolymer composition of claim 1 , wherein the photopolymer composition further comprises a photosensitizing dye, or other additives.

16. A hologram recording medium produced by curing the photopolymer composition of claim 1 .

17. An optical element comprising the hologram recording medium of claim 16 .

18. A holographic recording method comprising selectively polymerizing photoreactive monomers contained in the photopolymer composition of claim 1 by a coherent laser.

Assignees

• Lg Chemical Ltd

Inventors

• Jang Seok Hoon
• Kim Heon
• Heo Yongjoon
• Kwon Se Hyun
• Chang Yeong Rae

Classifications

• G03F7/033

  the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers · CPC title

• C08F2/50 Primary

  with sensitising agents · CPC title

• G03F7/001

  Phase modulating patterns, e.g. refractive index patterns · CPC title

• C08F299/028

  photopolymerisable compositions · CPC title

• C08L33/06

  of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical · CPC title