Methods of deposition of thick environmental barrier coatings on CMC blade tips

Patent metadata

Field	Value
Publication number	US-11078798-B2
Application number	US-201916374004-A
Country	US
Kind code	B2
Filing date	Apr 3, 2019
Priority date	Mar 26, 2015
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

Methods for tape deposition of a sacrificial coating on a CMC substrate are provided. The method comprises: applying a matrix material onto a surface of a film; drying the matrix material to remove the solvent; and transferring the dried matrix material from the film to the CMC substrate. The matrix material comprises a mixture of a rare earth silicate powder, a sintering aid, and a solvent.

First claim

What is claimed:

1. A method of tape deposition of a sacrificial coating on a CMC substrate having a first rare earth silicate coating thereon, the method comprising:
applying a matrix material onto a portion of the first rare earth silicate coating, wherein the matrix material comprises a mixture of a rare earth silicate powder, a sintering aid, and a solvent;
drying the matrix material to remove the solvent;
transferring the dried matrix material from the film to the CMC substrate to form the sacrificial coating, and
forming a second rare earth silicate coating on the CMC substrate and the sacrificial coating, wherein the first rare earth silicate coating and the second rare earth silicate coating are merged where the sacrificial coating is not present to encase the sacrificial coating within the first rare earth silicate coating and the second rare earth silicate coating.

2. The method of claim 1 , wherein the matrix material further comprises a plurality of particles, and wherein the particles comprise BSAS particles, silicon particles, or a mixture thereof.

3. The method of claim 2 , wherein the particles have an average particle size of about 5 microns to about 100 microns.

4. The method of claim 2 , wherein the particles comprise about 30% to about 65% by volume of the matrix material after drying, with the balance being the rare earth silicate powder and the sintering aid.

5. The method of claim 2 , wherein the matrix material further comprises an organic binder and a plasticizer.

6. The method of claim 5 , wherein the organic binder comprises polyvinyl butyral.

7. The method of claim 5 , wherein the plasticizer comprises dibutyl phthalate or dipropylene glycol dibenzoate.

8. The method of claim 1 , wherein the CMC substrate is an airfoil having a blade tip.

9. The method of claim 8 , wherein transferring the dried matrix material from the film to the CMC substrate comprises transferring the dried matrix material from the film to the blade tip of the airfoil.

10. The method of claim 9 , wherein the tip includes a first rare earth silicate coating on a bond coat, wherein the first rare earth silicate coating comprises at least one rare earth silicate layer, and wherein the dried matrix material is applied onto the first rare earth silicate to form the sacrificial coating.

11. The method of claim 1 , wherein the sacrificial coating has a thickness of about 8 mils to about 25 mils.

12. The method of claim 1 , wherein the sacrificial coating has a thickness of about 16 mils to about 24 mils.

13. A method of tape deposition of a sacrificial coating on a CMC substrate, wherein the CMC substrate is an airfoil having a blade tip, the method comprising:
applying a matrix material onto a surface of a film, wherein the matrix material comprises a mixture of a rare earth silicate powder, a sintering aid, and a solvent;
drying the matrix material to remove the solvent; and
transferring the dried matrix material from the film to the blade tip of the airfoil, wherein the tip includes a first rare earth silicate coating on a bond coat, wherein the first rare earth silicate coating comprises at least one rare earth silicate layer, and wherein the dried matrix material is applied onto the first rare earth silicate to form the sacrificial coating;
forming a second rare earth silicate coating on the sacrificial coating where the sacrificial coating is present at the blade tip and on the first rare earth silicate coating where the sacrificial coating is not present, wherein the second rare earth silicate coating comprises at least one rare earth silicate layer, and wherein the first rare earth silicate coating and the second rare earth silicate coating are merged where the sacrificial coating is not present to surround the sacrificial coating at the blade tip such that the sacrificial coating is completely encased within the first rare earth silicate coating and the second rare earth silicate coating at the blade tip.

14. The method of claim 13 , further comprising:
forming an outer layer on the second rare earth silicate coating.

15. The method of claim 13 , wherein the matrix material further comprises a plurality of particles, and wherein the particles comprise BSAS particles, silicon particles, or a mixture thereof.

16. The method of claim 15 , wherein the particles have an average particle size of about 5 microns to about 100 microns.

17. The method of claim 13 , wherein the particles comprise about 30% to about 65% by volume of the matrix material after drying, with the balance being the rare earth silicate powder and the sintering aid.

18. The method of claim 13 , wherein the matrix material further comprises an organic binder and a plasticizer.

19. The method of claim 13 , wherein the sacrificial coating has a thickness of about 8 mils to about 25 mils.

20. The method of claim 13 , wherein the sacrificial coating has a thickness of about 16 mils to about 24 mils.

Assignees

• Gen Electric

Inventors

• Kirby Glen Harold

Classifications

• C04B41/009

  characterised by the material treated · CPC title

• C04B41/89 Primary

  for obtaining at least two superposed coatings having different compositions · CPC title

• F05D2300/6033

  Ceramic matrix composites [CMC] · CPC title

• F01D5/282

  Selecting composite materials, e.g. blades with reinforcing filaments · CPC title

• F05D2300/211

  Silica · CPC title