Compositions and methods for gel spinning of polyamides

Patent metadata

Field	Value
Publication number	US-11078601-B2
Application number	US-201816490847-A
Country	US
Kind code	B2
Filing date	Feb 13, 2018
Priority date	Mar 9, 2017
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

A composition for forming a fiber includes at least one polyamide and caprolactam. The at least one polyamide has a number average molecular weight between 38,000 Da and 100,000 Da. The polyamide is at least partially dissolved in the caprolactam. The caprolactam comprises between 20 wt. % and 90 wt. % of the composition.

First claim

The invention claimed is:

1. A composition for forming a fiber, the composition comprising:
at least one polyamide having a number average molecular weight between 38,000 Da and 88,000 Da, derived from formic acid viscosity (FAV) as determined according to ASTM D789 according to the relationship:
M n =4791.8×(log(FAV)) 2.4056 ; and
caprolactam, wherein the polyamide is at least partially dissolved in the caprolactam, the caprolactam comprising between 30 wt. % and 90 wt. % of the composition.

2. The composition of claim 1 , wherein the caprolactam comprises between 50 wt. % and 90 wt. % of the composition.

3. The composition of claim 1 , wherein the polyamide has a number average molecular weight between 41,000 Da and 68,000 Da, derived from formic acid viscosity (FAV) as determined according to ASTM D789.

4. A method of producing a fiber, the method comprising:
dissolving at least one polyamide having a number average molecular weight between 38,000 Da and 88,000 Da, derived from formic acid viscosity (FAV) as determined according to ASTM D789 according to the relationship:
M n =4791.8×(log(FAV)) 2.4056 , into caprolactam to form a spinnable solution; and
spinning the spinnable solution by extruding the spinnable solution through a spinneret to form the fiber, wherein the spinnable solution includes between 30 wt. % and 90 wt. % caprolactam.

5. The method of claim 4 , wherein dissolving the at least one polyamide is performed at a temperature of 150° C. to 270° C.

6. The method of claim 4 , wherein the spinnable solution includes between 50 wt. % and 90 wt. % caprolactam.

7. The method of claim 4 , wherein the polyamide has a number average molecular weight between 41,000 Da and 68,000 Da, derived from formic acid viscosity (FAV) as determined according to ASTM D789.

8. The method of claim 4 , further comprising quenching the spun fibers in a quench bath containing a quenching liquid.

9. The method of claim 8 , wherein an air gap is defined between the spinneret and the quenching liquid in the quench bath, the air gap from 0.25 inches to 11 inches in length.

10. The method of claim 8 , wherein quenching the spun fibers includes:
pulling the fiber through the quenching bath in a first direction; and
flowing the quenching liquid in a second direction, the second direction being opposite to the first direction.

11. The method of claim 8 , wherein the quenching liquid has a dynamic viscosity of between 1,000 centipoise and 26,000 centipoise.

12. The method of claim 8 , wherein the quenching liquid is at a temperature from 50° C. to 150° C.

Assignees

• Advansix Resins & Chemicals Llc

Inventors

• Chern Terry
• Heldenbrand Nathan
• Hu Yue
• Young John A
• Loy David J
• Kweeder James A

Classifications

• C08J3/11

  from solid polymers · CPC title

• C08J3/096

  Nitrogen containing compounds · CPC title

• D01F6/60 Primary

  from polyamides (from polyamino acids or polypeptides D01F6/68) · CPC title

• C08G69/14

  Lactams · CPC title

• D01D1/02

  Preparation of spinning solutions · CPC title