Burner, furnace, and steam cracking processes using the same

Patent metadata

Field	Value
Publication number	US-11078429-B2
Application number	US-202016787757-A
Country	US
Kind code	B2
Filing date	Feb 11, 2020
Priority date	Mar 31, 2016
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

A burner sub-system, a furnace comprising the same, a fuel combustion process and steam cracking process carried out in the furnace. The burner sub-system comprises a barrier wall segment between the burner tip and the flue-gas recirculation (“FGR”) duct, effectively blocking direct gas flow between the burner tip and the FGR duct opening, but without encircling the whole burner tip. The presence of the partial barrier wall has the advantage of preventing the temperature inside the FGR duct from becoming too high, while achieving low NOx emissions from the combustion process without overheating the burner tip because of reduced amount of heat reflection to the burner tip compared to an annular barrier wall. The invention is particularly useful in furnaces where hydrogen-rich fuel gas is combusted.

First claim

The invention claimed is:

1. A furnace:
(A) a burner sub-system comprising:
a furnace floor segment having a floor burner opening and a flue-gas recirculation duct opening;
a tile enclosure lining the periphery of the floor burner opening, wherein the flue gas recirculation duct opening is adjacent the tile enclosure;
a burner comprising a burner tip adjacent and surrounded by the floor burner opening, the burner tip having a vertical centerline and configured to provide a floor burner flame through the floor burner opening; and
a barrier wall segment extending upwards from the upper surface of the furnace floor segment between the flue-gas recirculation duct opening and the burner tip, the barrier wall segment having an angle of view no greater than 180° when viewed from the point where the vertical centerline of the burner tip intercepts a plane of the furnace floor segment, wherein the barrier wall segment comprises a center portion and a first support structure portion connected to a first end of the center portion, wherein the first support structure portion extends upwards from the upper surface of the furnace floor segment;
(B) a furnace floor comprising the furnace floor segment of each of the at least one burner sub-system; and
(C) one or more furnace side walls;
wherein the furnace floor and the one or more furnace side walls form a furnace fire box.

2. The furnace of claim 1 , wherein the distance from the vertical centerline of any burner tip to any side wall is at least 30 centimeters.

3. The furnace of claim 1 , which comprises multiple burner sub-systems and is free of any partitioning wall between adjacent burner sub-systems.

4. The furnace of claim 1 , wherein the fire box has a height of at least 10.5 meters.

5. The furnace of claim 1 , wherein the fire box has a height of at least 15.0 meters.

6. The furnace of claim 1 , further comprising multiple side wall burners configured to produce at least one side wall burner flame from at least one of the furnace side walls.

7. The furnace of claim 1 , which is free of a side wall burner configured to produce a side wall burner flame from any of the furnace side wall.

8. The furnace of claim 1 , comprising at least three burner sub-systems configured to produce at least two rows of floor burner flames projecting upwards.

9. A fuel combustion process carried out in a furnace according to claim 1 , the process comprising:
supplying a fuel gas comprising at least 50 mol % of hydrogen into the at least one burner sub-system; and
combusting the fuel gas to form a floor burner flame above the burner tip inside the furnace fire box.

10. The fuel combustion process of claim 9 , wherein the floor flame has a height of at least 3.0 meters.

11. The fuel combustion process of claim 9 , wherein the distance from the vertical centerline of any floor burner flame to any side wall is at least 30 centimeters.

12. The fuel combustion process of claim 9 , which comprises multiple floor burner flames and is free of any partitioning wall between adjacent floor burner flames.

13. The fuel combustion process of claim 9 , further comprising multiple side wall burner flames produced by multiple side wall burners from at least one of the furnace side walls.

14. The fuel combustion process of claim 9 , which comprises at least two rows of floor burner flames.

15. A steam cracking process comprising a fuel combustion process of claim 9 , wherein a reactant stream comprising a hydrocarbon is heated inside a cracking tube which is heated inside the furnace by the floor burner flame.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Stephens George
• Spicer David B

Classifications

• F23C2900/09001

  Cooling flue gas before returning them to flame or combustion chamber · CPC title

• F23C9/006 Primary

  the recirculation taking place in the combustion chamber · CPC title

• F23M5/025

  specially adapted for burner openings · CPC title

• F23C2202/30

  Premixing fluegas with combustion air · CPC title

• C10G9/20 Primary

  Tube furnaces · CPC title