Synergistic sulfide scavenging additives for use in oilfield operations

Patent metadata

Field	Value
Publication number	US-11078403-B2
Application number	US-201916715338-A
Country	US
Kind code	B2
Filing date	Dec 16, 2019
Priority date	Dec 22, 2014
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

Systems, compositions, and methods for synergistic additives for use in the scavenging of sulfur-containing compounds encountered in oilfield operations are provided. In one embodiment, the methods comprise injecting a sulfide scavenging additive that does not comprise a significant amount of an aldehyde into at least a portion of a subterranean formation where one or more sulfur-containing species are present; and injecting a synergistic additive comprising at least one base into at least the portion of the subterranean formation.

First claim

What is claimed is:

1. A method comprising:
injecting a sulfide scavenging additive that is substantially free of aldehyde, the additive comprising at least one compound selected from the group consisting of an acrylate-based compound, an acrylonitrile-based compound, and any combination thereof into at least a portion of a subterranean formation where one or more sulfur-containing species are present; and
injecting a synergistic additive comprising at least one weak base into at least the portion of the subterranean formation;
wherein at least one of the sulfide scavenging additive or the synergistic additive is injected as a liquid or a mist.

2. The method of claim 1 wherein the synergistic additive catalyzes a reaction of the sulfide scavenging additive and the sulfur-containing species.

3. The method of claim 1 wherein the sulfide scavenging additive reacts with the sulfur-containing species to form products that are at least one of nonhazardous and noncorrosive.

4. The method of claim 1 wherein the synergistic additive reacts with the sulfur-containing species.

5. The method of claim 4 wherein the reaction of the synergistic additive and the sulfur-containing species forms products that are at least one of nonhazardous and noncorrosive.

6. The method of claim 1 wherein the synergistic additive increases a pH level of at least the portion of the subterranean formation.

7. The method of claim 1 wherein the at least one weak base comprises at least one amine.

8. The method of claim 1 wherein the sulfide scavenging additive and the synergistic additive are not mixed prior to injection into the at least the portion of the subterranean formation.

9. The method of claim 1 wherein the sulfide scavenging additive and the synergistic additive are mixed prior to injection into the at least the portion of the subterranean formation.

10. The method of claim 1 wherein the sulfide scavenging additive is injected in an amount of from about 0.1% up to about 50% by weight of the combination of the sulfide scavenging agent and the synergistic additive.

11. The method of claim 1 wherein at least one of the sulfide scavenging additive or the synergistic additive further comprises a surfactant.

12. A method comprising:
injecting a sulfide scavenging additive that is substantially free of aldehyde, the additive comprising at least one compound selected from the group consisting of an acrylate-based compound, an acrylonitrile-based compound, and any combination thereof into at least a portion of a subterranean formation where one or more sulfur-containing species are present, and
injecting a synergistic additive comprising at least one base into at least the portion of the subterranean formation;
wherein at least one of the sulfide scavenging additive or the synergistic additive is injected as a liquid or a mist.

13. The method of claim 12 wherein the synergistic additive catalyzes a reaction of the sulfide scavenging additive and the sulfur-containing species.

14. The method of claim 12 wherein the sulfide scavenging additive reacts with the sulfur-containing species to form products that are at least one of nonhazardous and noncorrosive.

15. The method of claim 12 wherein the synergistic additive reacts with the sulfur-containing species.

16. The method of claim 15 wherein the reaction of the synergistic additive and the sulfur-containing species forms products that are at least one of nonhazardous and noncorrosive.

17. The method of claim 12 wherein the sulfide scavenging additive and the synergistic additive are not mixed prior to injection into the at least the portion of the subterranean formation.

18. The method of claim 12 wherein the sulfide scavenging additive and the synergistic additive are mixed prior to injection into the at least the portion of the subterranean formation.

19. The method of claim 12 wherein the sulfide scavenging additive is injected in an amount of from about 0.1% up to about 50% by weight of the combination of the sulfide scavenging agent and the synergistic additive.

20. The method of claim 12 wherein at least one of the sulfide scavenging additive or the synergistic additive further comprises a surfactant.

Assignees

• Multi Chem Group Llc
• Halliburton Energy Services Inc

Inventors

• Shi Liu
• Zhao Funian
• Qu Liangwei
• Corrin Edward

Classifications

• C09K8/035 Primary

  Organic additives · CPC title

• C09K2208/20

  Hydrogen sulfide elimination · CPC title

• B09C1/08

  chemically · CPC title

• E21B43/00

  Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells (applicable only to water E03B) · CPC title

• C02F1/66

  by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58) · CPC title