Polymer composition comprising at least one vinyl aromatic diene block copolymer and specific amounts of oil

Patent metadata

Field	Value
Publication number	US-11078356-B2
Application number	US-201716311237-A
Country	US
Kind code	B2
Filing date	Jun 26, 2017
Priority date	Jun 29, 2016
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

The present invention relates to a polymer composition comprising at least one block copolymer and a specific amount of at least one oil component. The block copolymer, which is the polymeric matrix of the inventive composition, is built up from at least one vinyl aromatic monomer MA and at least one conjugated diene monomer MB, in particular the block copolymer is a styrene butadiene block copolymer (SBC).

First claim

The invention claimed is:

1. A polymer composition consisting of:
94.9 to 97.49% by weight, based on the total polymer composition:
at least one block copolymer P, having one of the following formulas (I) to (III):
(A-B/A) n -A  (I),

X—[(B/A-A) n ] m+1   (II),

Y—[(B/A-A) n ] m+1   (III),

wherein the abbreviations and indices have the following meaning:
A is a vinyl aromatic block forming a hard phase, which is composed of at least one vinyl aromatic monomer M A ,
B/A is a diene block forming a soft phase, which is composed of at least one conjugated diene monomer M B and at least one vinyl aromatic monomer M A ,
X is the radical of an m+1-functional initiator,
Y is the radical of an m+1-functional coupling agent,
n is a natural number from 1 to 10, and
m is a natural number from 1 to 10;

2.5 to 5% by weight, based on the total polymer composition,
at least one oil component C, wherein the oil component is one or more paraffin oil; and

0.01 to 1% by weight, based on the total polymer composition, one or more further components E;

wherein:
the at least one block copolymer P comprises 40 to 75% by weight, based on the block copolymer P, of the at least one vinyl aromatic monomer M A and 25 to 60% by weight, based on the block copolymer P, of the at least one conjugated diene monomer M B ;
the glass transition temperature's T g of the vinyl aromatic block's A is/are above 25° C. and the glass transition temperature's T g of the diene block's B/A is/are below 25° C.,
the proportion of the vinyl aromatic block's forming the hard phase is from 5 to 40% by volume, based on the total volume of block copolymer P;
the relative amount of 1,2 linkages in the diene block B/A, based on the sum of 1,2- and 1,4-cis/trans-linkages, is less than or equal to 15%; and
the weight average molecular weight M w of the block copolymer P is in the range of 120,000 to 300,000 g/mol.

2. The polymer composition according to claim 1 , wherein the vinyl aromatic monomer M A is at least one monomer selected from the group consisting of styrene, α-methylstyrene, vinyltoluene, and 1,1-diphenylethylene, and the conjugated diene monomer M B is at least one monomer selected from the group consisting of butadiene and isoprene.

3. The polymer composition according to claim 1 , wherein the vinyl aromatic monomer M A is at least one monomer selected from the group consisting of styrene and α-methylstyrene, and the conjugated diene monomer M B is butadiene.

4. The polymer composition according to claim 1 , wherein the molecular weight of the vinyl aromatic block's A is/are in the range of 5,000 to 100,000 g/mol; and the molecular weight of the diene block's B/A is/are in the range of 20,000 to 250,000 g/mol.

5. The polymer composition according to claim 1 , wherein the glass transition temperature T g of the vinyl aromatic block's A is/are above 50° C.; and the glass transition temperature T g of the diene block's B/A is/are below 5° C.

6. The polymer composition according to claim 1 , wherein the relative amount of 1,2 linkages in the diene block B/A of the block copolymer P, based on the sum of 1,2- and 1,4-cis/trans-linkages, is less than or equal to 12%.

7. The polymer composition according to claim 1 , wherein the oil component C is at least one paraffin oil having a viscosity in the range of 20 to 300 m Pas, measured at a temperature in the range of 20 to 25° C.

8. The polymer composition according to claim 1 , wherein the block copolymer P is obtained by a process which comprises the step of forming the block copolymer by sequential anionic polymerization, where at least the polymerization step of the at least one block B/A takes place in the presence of a potassium salt as randomizer.

9. A moulded part made from the polymer composition according to claim 1 .

10. The moulded part according to claim 9 , wherein the moulded part is selected from extruded sheets, extruded multilayer sheets, extruded tubings, multilumen tubings, drip chamber parts, food packagings, beakers, plates, and labels.

11. A process for the production of the polymer composition according to claim 1 , wherein the at least one block copolymer P is mixed with the at least one oil component C, and optionally further components E.

12. The process according to claim 11 , wherein the components are mixed by melt extrusion.

Assignees

• Ineos Styrolution Group Gmbh

Inventors

• Colombo Andrea
• Hamilton Michael
• Verswyvel Michiel
• Jahnke Eike
• Elbert Bernd
• Niessner Norbert
• Knoll Konrad

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08J2353/02

  of vinyl aromatic monomers and conjugated dienes · CPC title

• B29B7/002

  Methods (chemical aspects C08J3/00) · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• C08L91/00

  Compositions of oils, fats or waxes; Compositions of derivatives thereof · CPC title