Copolymerization of elemental sulfur to synthesize high sulfur content polymeric materials

Patent metadata

Field	Value
Publication number	US-11078333-B2
Application number	US-201615744398-A
Country	US
Kind code	B2
Filing date	Jul 13, 2016
Priority date	Jul 13, 2015
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

Copolymerization of elemental sulfur with functional comonomers afford sulfur copolymers having a high molecular weight and high sulfur content. Nucleophilic activators initiate sulfur polymerizations at relative lower temperatures and in solutions, which enable the use of a wider range of comonomers, such as vinylics, styrenics, and non-homopolymerizing comonomers. Nucleophilic activators promote ring-opening reactions to generate linear polysulfide intermediates that copolymerize with comonomers. Dynamic sulfur-sulfur bonds enable re-processing or melt processing of the sulfur polymer. Chalcogenide-based copolymers have a refractive index of about 1.7-2.6 at a wavelength in a range of about 5000 nm-8μιτι. The sulfur copolymer can be a thermoplastic or a thermoset for use in elastomers, resins, lubricants, coatings, antioxidants, cathode materials for electrochemical cells, dental adhesives/restorations, and polymeric articles such as polymeric films and free-standing substrates. Optical substrates are constructed from the chalcogenide copolymer and are substantially transparent in the visible and infrared spectrum.

First claim

What is claimed is:

1. An optical sulfur copolymer comprising:
a. sulfur monomers comprising sulfur chains derived from S 8 , at a level of about 50-95 wt % of the optical sulfur copolymer;
b. one or more comonomers each selected from a group consisting of amine monomers, thiol monomers, sulfide monomers, alkynylly unsaturated monomers, epoxide monomers, nitrone monomers, aldehyde monomers, ketone monomers, thiirane monomers, and ethylenically unsaturated monomers at a level in the range of about 1-49 wt % of the optical sulfur copolymer; and
c. one or more selenium comonomers at a level of about 1-49 wt % of the optical sulfur copolymer;

wherein the one or more selenium comonomers copolymerize with the sulfur chains derived from S 8 ;
wherein the optical sulfur copolymer is transparent in an infrared spectrum.

2. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer has a refractive index of about 1.78-2.6 at a wavelength in a range of about 500 nm to about 10 μm.

3. The optical sulfur copolymer of claim 1 , wherein the one or more selenium comonomers have the formula Se n S (8-n) , where n is an integer that can range from 1-7; or
wherein the selenium comonomers have the formula Se n S m , where n is an integer that can range from 1-7 and m is an integer that can range from 1-7.

4. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is transparent in an electromagnetic spectrum having a wavelength range of about 1000-1500 nm.

5. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is transparent in an electromagnetic spectrum having a wavelength range of about 3000-5000 nm.

6. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is transparent in an electromagnetic spectrum having a wavelength range of about 3-20 microns.

7. The optical sulfur copolymer of claim 1 , wherein at least one functional sulfur moiety of the sulfur monomers is bonded to at least one functional moiety of the one or more monomers.

8. The optical sulfur copolymer of claim 1 , wherein in addition to the sulfur monomers, the one or more comonomers, and the one or more selenium monomers, the sulfur copolymer further comprises one or more epoxide monomers at a level in the range of about 10 wt % to about 50 wt % of the optical sulfur copolymer.

9. The optical sulfur copolymer of claim 1 , wherein in addition to the sulfur monomers, the one or more comonomers, and the one or more selenium monomers, the sulfur copolymer further comprises one or more of a fourth monomer selected from a group consisting of amine monomers, thiol monomers, sulfide monomers, alkynylly unsaturated monomers, epoxide monomers, nitrone monomers, aldehyde monomers, ketone monomers, thiirane monomers, and ethylenically unsaturated monomers at a level in the range of about 10 wt % to about 50 wt % of the optical sulfur copolymer.

10. The optical sulfur copolymer of claim 1 , wherein in addition to the sulfur monomers, the one or more comonomers, and the one or more selenium monomers, the sulfur copolymer further comprises one or more polyfunctional monomers selected from a group consisting of a polyvinyl monomer, a polyisopropenyl monomer, a polyacryl monomer, a polymethacryl monomer, a polyunsaturated hydrocarbon monomer, a polyepoxide monomer, a polythiirane monomer, a polyalkynyl monomer, a polydiene monomer, a polybutadiene monomer, a polyisoprene monomer, a polynorbornene monomer, a polyamine monomer, a polythiol monomer, a polysulfide monomer, a polyalkynylly unsaturated monomers, a polynitrone monomers, a polyaldehyde monomers, a polyketone monomers, and a polyethylenically unsaturated monomers, wherein the polyfunctional monomer has moieties that are the same or different.

11. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is processable in a solution.

12. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is melt processable.

13. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is self-healing upon reprocessing.

14. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is formed into a transparent substrate.

15. The optical sulfur copolymer of claim 14 , wherein the transparent substrate is a film, a lens, a window, or a free-standing object.

16. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is coated on a substrate and cured as a thin film.

17. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is shaped and cured using a mold.

18. The optical sulfur copolymer of claim 1 , wherein the optical sulfur copolymer is fabricated into an optical device component for use as a transmitting material in an infrared imaging device.

Assignees

• Univ Arizona

Inventors

• Pyun Dong-Chul
• Glass Richard S
• Norwood Robert A
• Griebel Jared J
• Namnabat Soha

Classifications

• C08F212/08

  Styrene · CPC title

• C08G75/00

  Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule · CPC title

• C08F12/30 Primary

  Sulfur · CPC title

• C08F228/04

  Thioethers · CPC title

• C08G79/00

  Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon {with or without the latter elements in the main chain of the macromolecule} · CPC title