Method and an apparatus for forming a lignin fraction, a lignin composition and its use

Patent metadata

Field	Value
Publication number	US-11078225-B2
Application number	US-201615577624-A
Country	US
Kind code	B2
Filing date	May 26, 2016
Priority date	May 29, 2015
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

The invention relates to a method and an apparatus for forming a lignin fraction from crude lignin which has been processed by means of a treatment step selected from enzymatic treatment, treatment with ionic liquid and their combinations. The method comprises treating the crude lignin ( 1 ) by a lignin liberation in at least one lignin liberation step ( 3 ), and separating a lignin fraction ( 6 ) in at least one separation step ( 5 ). Further, the invention relates to a lignin composition and its use.

First claim

The invention claimed is:

1. A method for forming a lignin fraction from crude lignin wherein the method comprises:
forming crude lignin using enzymatic treatment, treatment with ionic liquid, or the combination thereof;
treating the crude lignin by a lignin liberation at a temperature of at least 170° C. in at least one lignin liberation step, wherein the lignin is liberated using a dilute acid hydrolysis and a steam explosion and wherein two solid phases are formed; and
separating a lignin fraction and a lignocellulose fraction in at least one solid-solid separation step after the lignin liberation.

2. The method of claim 1 , wherein the cellulose content of the crude lignin is between about 10-60% by weight.

3. The method according to claim 1 , wherein below 70% of glucan is dissolved during the lignin liberation.

4. The method according to claim 1 , wherein the crude lignin is treated by dewatering, washing, filtrating, centrifuging, or a combination thereof in at least one washing and separation step before the lignin liberation.

5. The method according to claim 1 , wherein the separating the lignin fraction and the lignocellulose is carried out in more than one separation step.

6. The method according to claim 1 , wherein a stabilizing chemical is added into the treated crude lignin in connection with the act of separating the lignin fraction and the lignocellulose fraction.

7. The method according to claim 6 , wherein the stabilizing chemical includes carboxymethyl cellulose (CMC) or guar gum.

8. The method according to claim 1 , wherein at least a part of the lignocellulose fraction is recirculated to the enzymatic treatment, the treatment with ionic liquid, or the combination thereof.

9. The method of claim 1 , further comprising forming a lignin composition including the lignin fraction.

10. The method of claim 9 , wherein the lignin composition is configured to be used as a component in a product selected from the group consisting of activated carbon, carbon fiber, lignin composite, binder material, polymers, resins, phenolic component, dispersion agent, feed, food or their combination.

11. The method of claim 9 , wherein the lignin composition is configured to be used as an adsorbent for oil, hydrocarbon composition, or heavy metals.

12. The method of claim 1 , further comprising forming a lignocellulose composition including the lignocellulose fraction.

13. The method of claim 12 , wherein the lignocellulose composition is configured to be used as a component in a product selected from the group consisting of composites, wood composites, lignin-wood composites, wood-plastic composites, resins, wood based materials, wood based fillers, construction materials, building boards, glue boards and/or other wood based hoards, or as combustible matter, or as raw material in a production of microcrystalline cellulose, nanocrystalline cellulose or nanofibrillated cellulose.

Assignees

• Upm Kymmene Corp

Inventors

• Miettinen Mauno

Classifications

• C07G1/00 Primary

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• B01J31/003

  containing enzymes · CPC title

• B01J8/00

  Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes · CPC title

• B01J31/0277 Primary

  comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature · CPC title

• C08H8/00

  Macromolecular compounds derived from lignocellulosic materials {(pretreatment thereof B27N)} · CPC title